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Directly grown TiO2 nanotubes on carbon nanofibers for photoelectrochemical water splitting

Published online by Cambridge University Press:  24 May 2016

Hyungkyu Han ,
Stepan Kment ,
Anandarup Goswami ,
Ondrej Haderka  and
Radek Zboril
Hyungkyu Han
Affiliation:
Regional Centre of Advanced Technologies and Materials, Joint Laboratory of Optics and Department of Physical Chemistry, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic
Stepan Kment
Affiliation:
Regional Centre of Advanced Technologies and Materials, Joint Laboratory of Optics and Department of Physical Chemistry, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic
Anandarup Goswami
Affiliation:
Regional Centre of Advanced Technologies and Materials, Joint Laboratory of Optics and Department of Physical Chemistry, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic
Ondrej Haderka
Affiliation:
Regional Centre of Advanced Technologies and Materials, Joint Laboratory of Optics and Department of Physical Chemistry, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic
Radek Zboril*
Affiliation:
Regional Centre of Advanced Technologies and Materials, Joint Laboratory of Optics and Department of Physical Chemistry, Faculty of Science, Palacky University, Slechtitelu 11, 783 71 Olomouc, Czech Republic
*
*(Email: [email protected])
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Abstract

A variety of Titanium dioxide (TiO2) phases and nanostructures have been explored for their applications in photoelectrochemical cells (PECs) for solar-driven water splitting. In this case, anatase phase and TiO2 nanotubes offer significant advantages especially for PEC-based applications. Though, significant efforts have already been engaged to combine the advantages from both the fields, poor activation and the high electron-hole pair recombination rate of TiO2 electrodes, originating from intrinsic physicochemical properties, limits its practical use. As an alternative, we report directly grown TiO2 nanotubes (synthesized on Fluorine doped Tin Oxide (FTO) via facile electrospinning technique) on carbon nanofibers, using hydrothermal method. The hierarchical branch type configuration has an intimate contact between the TiO2 nanotube and carbon nanofiber backbone and offers higher photocatalytic activity than their respective individual components (namely TiO2 nanotubes and carbon nanostructures).

Keywords

hydrothermalnanostructurephotochemical
Type
Articles
Information
MRS Advances , Volume 1 , Issue 46: Energy and Environment , 2016 , pp. 3145 - 3150
Copyright
Copyright © Materials Research Society 2016 

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References

REFERENCES

Khaselev, O. and Turner, J. A., "A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting," Science, vol. 280, pp. 425–427, Apr 17 1998.CrossRefGoogle Scholar
Navarro, R. M., Pena, M. A., and Fierro, J. L. G., "Hydrogen production reactions from carbon feedstocks: Fossils fuels and biomass," Chemical Reviews, vol. 107, pp. 3952–3991, Oct 2007.CrossRefGoogle Scholar
Fujishima, A. and Honda, K., "Electrochemical Photolysis of Water at a Semiconductor Electrode," Nature, vol. 238, pp. 37-+, 1972.CrossRefGoogle Scholar
Han, H., Song, T., Bae, J. Y., Nazar, L. F., Kim, H., and Paik, U., "Nitridated TiO2 hollow nanofibers as an anode material for high power lithium ion batteries," Energy & Environmental Science, vol. 4, pp. 4532–4536, Nov 2011.CrossRefGoogle Scholar
Han, H., Song, T., Lee, E. K., Devadoss, A., Jeon, Y., Ha, J., et al. , "Dominant Factors Governing the Rate Capability of a TiO2 Nanotube Anode for High Power Lithium Ion Batteries," Acs Nano, vol. 6, pp. 8308–8315, Sep 2012.CrossRefGoogle Scholar
Zhang, Z. H., Zhang, L. B., Hedhili, M. N., Zhang, H. N., and Wang, P., "Plasmonic Gold Nanocrystals Coupled with Photonic Crystal Seamlessly on TiO2 Nanotube Photoelectrodes for Efficient Visible Light Photoelectrochemical Water Splitting," Nano Letters, vol. 13, pp. 14–20, Jan 2013.CrossRefGoogle Scholar
Park, J. H., Kim, S., and Bard, A. J., "Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting," Nano Letters, vol. 6, pp. 24–28, Jan 2006.CrossRefGoogle Scholar
Zhao, L., Chen, X. F., Wang, X. C., Zhang, Y. J., Wei, W., Sun, Y. H., et al. , "One-Step Solvothermal Synthesis of a Carbon@TiO2 Dyade Structure Effectively Promoting Visible-Light Photocatalysis," Advanced Materials, vol. 22, pp. 3317-+, Aug 10 2010.CrossRefGoogle Scholar
Chen, Y. J., Tian, G. H., Ren, Z. Y., Pan, K., Shi, Y. H., Wang, J. Q., et al. , "Hierarchical Core-Shell Carbon Nanofiber@ZnIn2S4 Composites for Enhanced Hydrogen Evolution Performance," Acs Applied Materials & Interfaces, vol. 6, pp. 13841–13849, Aug 27 2014.CrossRefGoogle Scholar