Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-27T01:21:11.783Z Has data issue: false hasContentIssue false
  • English
  • Français

A Comparison of Mechanical and Electrical Properties in Hierarchical Composites Prepared using Electrophoretic or Chemical Vapor Deposition of Carbon Nanotubes

Published online by Cambridge University Press:  06 January 2016

Andrew N. Rider ,
Qi An ,
Narelle Brack  and
Erik T. Thostenson
Andrew N. Rider*
Affiliation:
Defence Science and Technology Group, Fisherman’s Bend, Victoria 3207, Australia
Qi An
Affiliation:
Department of Mechanical Engineering, Department of Materials Science and Engineering, and Center for Composite Materials, University of Delaware, Newark, DE 19716, USA
Narelle Brack
Affiliation:
Department of Chemistry and Physics, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, 3086, Australia
Erik T. Thostenson
Affiliation:
Department of Mechanical Engineering, Department of Materials Science and Engineering, and Center for Composite Materials, University of Delaware, Newark, DE 19716, USA
*
*(Email: [email protected])
Get access

Abstract

Two approaches have been employed in the preparation of hierarchical composite laminates with a carbon nanotube (CNT) phase. Glass fibers were coated with CNTs using electrophoretic deposition (EPD) prior to infusion with epoxy resin. The CNTs were functionalized using an ultrasonicated-ozone process followed by reaction with polyethyleneimine (PEI) to enhance CNT to fiber and matrix adhesion. Chemical vapor deposition (CVD) was also used to grow CNTs onto quartz fibers, prior to infusion with an epoxy resin modified with a thermoplastic nanophase. The mechanical performance of the two CNT laminates types were similar, however, the fracture surfaces indicated distinct differences. The EPD laminates showed fracture in the CNT-rich interphase region, whereas, the CVD laminates showed that strength was limited by adhesion failure at the CNT-fiber interface. The electrical conductivity of CVD laminates was 100 times higher than EPD laminates. For the EPD laminates the PEI functionalization increases the CNT-CNT distance resulting in reduced conductivity, while the high CNT packing density and residual iron catalyst on the fiber surface in the CVD laminates creates conducting pathways resulting in higher conductivities.

Keywords

compositenanostructurenanoscale
Type
Articles
Information
MRS Advances , Volume 1 , Issue 12: Mechanical Behavior and Failure of Materials , 2016 , pp. 785 - 790
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Pandey, G., Thostenson, E. T., Polym. Rev. 52, 355–416 (2012).CrossRefGoogle Scholar
Thostenson, E. T., Li, W., Wang, D., Ren, Z., and Chou, T., J. Appl. Phys. 91, 6034–6037 (2002).CrossRefGoogle Scholar
Qian, H., Bismarck, A., Greenhalgh, E. S., and Shaffer, M. S. P., Compos. Sci. Technol. 70 (2), 393-399 (2010).Google Scholar
Garcia, E. J., Wardle, B. L., John Hart, A., and Yamamoto, N., Compos. Sci. Technol. 68 (9), 2034–2041 (2008).Google Scholar
Rider, A. N., Yeo, E., Gopalakrishna, J., Thostenson, E. T., and Brack, N., Carbon 94, 971–981 (2015).CrossRefGoogle Scholar
An, Q., Rider, A. N., and Thostenson, E. T., ACS Applied Materials and Interfaces 5 (6), 2022-2032 (2013).CrossRefGoogle Scholar
An, Q., Rider, A. N., and Thostenson, E. T., Carbon 50 (11), 4130-4143 (2012).CrossRefGoogle Scholar
Zhang, H., Liu, Y., Kuwata, M., Bilotti, E., Peijs, T., Compos Part A Appl Sci Manuf. 70, 102–110 (2015).Google Scholar
Zhang, Q., Liu, J., Sager, R., Dai, L., and Baur, J, Compos. Sci. Technol. 69, 594–601 (2009).Google Scholar
Kappen, P., Halstead, B., Rider, A. N., Pigram, P. J., and Brack, N., Journal of Physical Chemistry C 113 (11), 4307-4314 (2009).Google Scholar
Rider, A. N., An, Q., Thostenson, E. T., and Brack, N., Nanotechnology 25 (49), 495607 (2014).Google Scholar
Rider, A. N., An, Q., Brack, N., and Thostenson, E. T., Chemical Engineering Journal 269, 121–134 (2015).CrossRefGoogle Scholar