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The thermal expansion behaviour of the framework silicates

Published online by Cambridge University Press:  05 July 2018

D. Taylor
D. Taylor*
Affiliation:
Doulton Research Limited, Basil Green Laboratories, Hanworth Lane, Chertsey, Surrey
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Summary

This paper gives a revision and expansion of an earlier interpretation of the thermal expansion behaviour of the framework silicates. The partially-collapsed and ideal fully-expanded structures of quartz, cristobalite, and sodalite are characterized by the geometric relationship between the angle of rotation of their tetrahedra from the ideal fully-expanded state, their cell parameters, and the length of the tetrahedron edge. Their thermal expansion behaviour is interpreted as due mainly to the effect of the rotation of the tetrahedra towards the fully-expanded state modified by anisotropic thermal motion of the framework oxygens and distortion of the tetrahedra from a regular form. With the leucite and sodalite groups the significance of the interframework cations is discussed.

Type
Research Article
Information
Mineralogical Magazine , Volume 38 , Issue 297 , March 1972 , pp. 593 - 604
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1972

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