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Sylvite and fluorite microcrysts, and fluorite-nyerereite intergrowths from natrocarbonatite, Oldoinyo Lengai, Tanzania

Published online by Cambridge University Press:  05 July 2018

R. H. Mitchell*
Affiliation:
Department of Geology, Lakehead University, 955 Oliver Road, Thunder Bay, Ontario, Canada P7B 5E1

Abstract

Natrocarbonatite lavas erupted from hornitos T37B and T49B at Oldoinyo Lengai (Tanzania) during 23–30 July, 2000 are unusual in containing sylvite and fluorite microcrysts together with fluorite-nyerereite intergrowths. The latter are relatively coarse grained and exhibit granular textures indicative of slow crystallization rates relative to those of their host subaerial lavas. Fluorite microcrysts are considered to be derived by the fragmentation of the fluorite-nyerereite clasts. Sylvite microcrysts contain inclusions of ferroan alabandite [(Mn0.67-0.71Fe0.33-0.29)S] and are poor in Na (1.9–7.7 wt.% Na; 6.1–23.4 mol.% NaCl). Intergrowth and microcrystal fluorite contains 1–3.5 wt.% Sr. Intergrowth nyerereite has a composition similar to that occurring as bona fide phenocrysts. The groundmass of lava erupted from hornito T37B contains nyerereite microphenocrysts (4–8 wt.% BaO) that are epitaxially mantled by barian nyerereite (12–20 wt.% BaO). The latter are compositionally and texturally distinct from the groundmass phase X, which is considered to be a burbankite-group mineral. The fluorite-nyerereite clasts are considered to be derived from the magma chamber underlying hornitos T37B and T49B, and thus representative of some of the products of crystallization of natrocarbonatite magma under hypabyssal conditions. The origins of the sylvite microcrysts cannot, as yet, be determined.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2006

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References

Church, A.A. and Jones, A.P. (1995) Silicate-carbonatite immiscibility at Oldoinyo Lengai. Journal of Petrology, 36, 869889.CrossRefGoogle Scholar
Dawson, J.B. (1989) Sodium carbonatite extrusions from Oldoinyo Lengai, Tanzania: Implications for carbonatite genesis. Pp. 255277 in Carbonatites: Genesis and Evolutio. (Bell, K., editor). Unwin Hyman, London.Google Scholar
Dawson, J.B., Pinkerton, H., Norton, G.E., Pyle, D.M., Browning, P., Jackson, D. and Fallick, A.E. (1995) Petrology and geochemistry of Oldoinyo Lengai lavas extruded in November 1988: magma source, ascent and crystallization. Pp. 4769 in: Carbonatite Volcanis. (Bell, K. and Keller, J., editors). Springer-Verlag, Berlin.CrossRefGoogle Scholar
Dawson, J.B., Pyle, D.M. and Pinkerton, H. (1996) Evolution of natrocarbonatite from a wollastonite nephelinite parent: evidence from the June 1993 eruption of Oldoinyo Lengai, Tanzania. Journal of Geology, 104, 4154.CrossRefGoogle Scholar
Eremenko, G.K. and Belko, V.A. (1982) Khannesite, (Na,Ca)3(Ba,Sr,REE,Ca)3(CO3)5: a new mineral of the burbankite group. Zapiskii Vsesoyuznovo Mineralogischeskovo Obshschestva, 111, 321324 (in Russian).Google Scholar
Jago, B.C. (1991) The role of fluorine in the evolution of alkali-bearing carbonatite magma and the formation of carbonatite-hosted apatite and pyrochlore depos¬its. PhD thesis, University of Toronto, Ontario, Canada 374 pp.Google Scholar
Jago, B.C. and Gittins, J. (1999) Mn and F-bearing rasvumite in natrocarbonatite at Oldoinyo Lengai Volcano, Tanzania. Mineralogical Magazine, 63, 5355.CrossRefGoogle Scholar
Keller, J. and Krafft, M. (1990) Effusive natrocarbonatite activity at Oldoinyo Lengai, June 1988. Bulletin Volcanologie, 52, 629645.CrossRefGoogle Scholar
Mitchell, R.H. (1997) Carbonate-carbonate immiscibility, neighborite and potassium iron sulphide in Oldoinyo Lengai natrocarbonatite. Mineralogical Magazine, 61, 779789.CrossRefGoogle Scholar
Mitchell, R.H. and Belton, F. (2004) Niocalite-cuspidine solid solution and manganoan monticellite from natrocarbonatite, Oldoinyo Lengai, Tanzania. Mineralogical Magazine, 68, 787799.CrossRefGoogle Scholar
Peterson, T.D. (1990) Petrology and genesis of natrocarbonatite. Contributions to Mineralogy and Petrology, 105, 143155.CrossRefGoogle Scholar
Waldbaum, D.R. (1969) Thermodynamic mixing properties of NaCl-KCl liquids. Geochimica et Cosmochimica Acta, 52, 28712875.Google Scholar