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Subaerial sulfate mineral formation related to acid aerosols at the Zhenzhu Spring, Tengchong, China

Published online by Cambridge University Press:  14 January 2019

Lianchao Luo
Affiliation:
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology), Chengdu 610059, China Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
Huaguo Wen*
Affiliation:
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology), Chengdu 610059, China Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
Rongcai Zheng
Affiliation:
State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology), Chengdu 610059, China Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
Ran Liu
Affiliation:
Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
Yi Li
Affiliation:
Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
Xiaotong Luo
Affiliation:
Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
Yaxian You
Affiliation:
Institute of Sedimentary Geology, Chengdu University of Technology, Chengdu 610059, China
*
*Author for correspondence: Huaguo Wen, Email: [email protected]

Abstract

The Zhenzhu Spring, located in the Tengchong volcanic field, Yunnan, China, is an acid hot spring with high SO42− concentrations and intense acid aerosol generation. In order to understand the formation mechanism of sulfate minerals at the Zhenzhu Spring and provide a better insight into the sulfur isotope geochemistry of the associated Rehai hydrothermal system, we investigated the spring water hydrochemistry, mineralogy and major-element geochemistry of sulfate minerals at the Zhenzhu Spring together with the sulfur-oxygen isotope geochemistry of sulfur-containing materials at the Rehai geothermal field and compared the isotope results with those in other steam-heated environments. Subaerial minerals include a wide variety of sulfate minerals (gypsum, alunogen, pickeringite, tamarugite, magnesiovoltaite and a minor Mg–S–O phase) and amorphous SiO2. The δ34S values of the subaerial sulfate minerals at the Zhenzhu Spring varied subtly from –0.33 to 1.88‰ and were almost consistent with the δ34S values of local H2S (–2.6 to 0.6‰) and dissolved SO42− (–0.2 to 5.8‰), while the δ18O values (–8.94 to 20.1‰) were between that of the spring waters (–10.19 to –6.7‰) and atmospheric O2 (~23.88‰). The results suggest that most of the sulfate minerals are derived from the oxidation of H2S, similar to many sulfate minerals from modern steam-heated environments. However, the rapid environmental change (different ratio of atmospheric and water oxygen) at the Zhenzhu Spring accounts for the large variation of δ18O. The formation of subaerial sulfate minerals around the Zhenzhu Spring is related to acid aerosols (vapour and acid water droplets). The intense activity of spring water around vents supply the aerosol with H2SO4 (H2S oxidation and acid water droplets formed by bubble bursting) and few cations. Deposition of the acid sulfate aerosol forms the acid condensate, which attacks the underlying rocks and releases many cations and anions to form subaerial sulfate minerals at the Zhenzhu Spring.

Type
Article
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

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Footnotes

Associate Editor: G. Diego Gatta

References

Adams, P.M., Lynch, D.K., Buckland, K.N., Johnson, P.D. and Tratt, D.M. (2017) Sulfate mineralogy of fumaroles in the Salton Sea Geothermal Field, Imperial County, California. Journal of Volcanology and Geothermal Research, 347, 1543.Google Scholar
Africano, F. and Bernard, A. (2000) Acid alteration in the fumarolic environment of Usu volcano, Hokkaido, Japan. Journal of Volcanology and Geothermal Research, 97, 475495.Google Scholar
Aguilera, F., Layana, S., Rodríguezdíaz, A., González, C., Cortés, J. and Inostroza, M. (2016) Hydrothermal alteration, fumarolic deposits and fluids from Lastarria Volcanic Complex: A multidisciplinary study. Andean Geology, 43, 166196.Google Scholar
Alcicek, H., Bulbul, A. and Alcicek, M.C. (2016) Hydrogeochemistry of the thermal waters from the Yenice Geothermal Field (Denizli Basin, Southwestern Anatolia, Turkey). Journal of Volcanology and Geothermal Research, 309, 118138.Google Scholar
Allard, P., Maiorani, A., Tedesco, D., Cortecci, G. and Turi, B. (1991) Isotopic study of the origin of sulfur and carbon in Solfatara fumaroles, Campi Flegrei caldera. Journal of Volcanology & Geothermal Research, 48, 139159.Google Scholar
Bai, D.H., Liao, Z.J., Zhao, G.Z. and Wang, X.B. (1994) The inference of magmatic heat source beneath the Rehai (Hot Sea) field of Tengchong from the result of magnetotelluric sounding. Chinese Science Bulletin, 39, 572577.Google Scholar
Bai, D.H., Meju, M.A. and Liao, Z.J. (2001) Magnetotelluric images of deep crustal structure of the Rehai geothermal field near Tengchong, southern China. Geophysical Journal International, 147, 677687.Google Scholar
Balci, N., Iii, W.C.S., Mayer, B. and Mandernack, K.W. (2007) Oxygen and sulfur isotope systematics of sulfate produced by bacterial and abiotic oxidation of pyrite. Geochimica et Cosmochimica Acta, 71, 37963811.Google Scholar
Barkan, E. and Luz, B. (2005) High precision measurements of 17O/16O and 18O/16O ratios in H2O. Rapid Communications in Mass Spectrometry, 19, 37373742.Google Scholar
Bonny, S. and Jones, B. (2003) Microbes and mineral precipitation, Miette Hot Springs, Jasper National Park, Alberta, Canada. Canadian Journal of Earth Sciences, 40, 14831500.Google Scholar
Briggs, B.R., Brodie, E.L., Tom, L.M., Dong, H.L., Jiang, H.C., Huang, Q.Y., Wang, S., Hou, W.G., Wu, G., Huang, L.Q., Hedlund, B.P., Zhang, C.L., Dijkstra, P. and Hungate, B.A. (2014) Seasonal patterns in microbial communities inhabiting the hot springs of Tengchong, Yunnan Province, China. Environmental Microbiology, 16, 15791591.Google Scholar
Chiba, H. and Sakai, H. (1985) Oxygen isotope exchange rate between dissolved sulfate and water at hydrothermal temperatures. Geochimica et Cosmochimica Acta, 49, 9931000.Google Scholar
Ciesielczuk, J., Zaba, J., Bzowska, G., Gaidzik, K. and Glogowska, M. (2013) Sulphate efflorescences at the geyser near Pinchollo, southern Peru. Journal of South American Earth Sciences, 42, 186193.Google Scholar
Cortecci, G., Noto, P. and Panichi, C. (1978) Environmental isotopic study of the Campi Flegrei (Naples, Italy) geothermal field. Journal of Hydrology, 36, 143159.Google Scholar
Cunningham, C.G. (1984) Origins and exploration significance of replacement and vein-type alunite deposits in the Marysvale volcanic field, west central Utah. Economic Geology, 79, 5071.Google Scholar
Delines, M. (1975) Volcanic sublimates of Rugarama, Kiva region, Republic of Zaire. Bulletin du Survice Géologique de la Republique du Rwanda, 8, 111.Google Scholar
Du, J.G., Liu, C.Q., Fu, B.H., Ninomiya, Y., Zhang, Y.L., Wang, C.Y., Wang, H.L. and Sun, Z.G. (2005) Variations of geothermometry and chemical-isotopic compositions of hot spring fluids in the Rehai geothermal field, southwestern China. Journal of Volcanology and Geothermal Research, 142, 243261.Google Scholar
Ebert, S.W. and Rye, R.O. (1997) Secondary precious metal enrichment by steam-heated fluids in the Crofoot-Lewis hot spring gold-silver deposit and relation to paleoclimate. Economic Geology, 92, 578600.Google Scholar
Fernández-Remolar, D.C., Morris, R.V., Gruener, J.E., Amils, R. and Knoll, A.H. (2005) The Río Tinto Basin, Spain: mineralogy, sedimentary geobiology, and implications for interpretation of outcrop rocks at Meridiani Planum, Mars. Earth and Planetary Science Letters, 240, 149167.Google Scholar
Fry, B., Ruf, W., Gest, H. and Hayes, J. (1988) Sulfur isotope effects associated with oxidation of sulfide by O2 in aqueous solution. Chemical Geology: Isotope Geoscience Section, 73, 205.Google Scholar
Guo, Q.H. (2012) Hydrogeochemistry of high-temperature geothermal systems in China: A review. Applied Geochemistry, 27, 18871898.Google Scholar
Guo, Q.H. and Wang, Y.X. (2012) Geochemistry of hot springs in the Tengchong hydrothermal areas, Southwestern China. Journal of Volcanology & Geothermal Research, 215–216, 6173.Google Scholar
Guo, Q.H., Liu, M.L., Li, J.X., Zhang, X.B. and Wang, Y.X. (2014) Acid hot springs discharged from the Rehai hydrothermal system of the Tengchong volcanic area (China): formed via magmatic fluid absorption or geothermal steam heating? Bulletin of Volcanology, 76, 868879.Google Scholar
Holt, B.D. and Kumar, R. (1991) Oxygen isotope fractionation for understanding the sulphur cycle. Pp. 2741 in: Stable Isotopes: Natural and Anthropogenic Sulphur in the Environment (Krouse, H.R. and Grinenko, V.A., editors). Wiley & Sons, New York.Google Scholar
Hong, L., Zhang, G.P., Jin, Z.S., Liu, C.Q., Han, G.L. and Ling, L.I. (2009) Geochemical characteristics of geothermal fluid in Tengchong Area,Yunnan Province,China. Acta Mineralogica Sinica, 29, 496501 [in Chinese with English Abstract].Google Scholar
Hou, W.G., Wang, S., Dong, H.L., Jiang, H.C., Briggs, B.R., Peacock, J.P., Huang, Q.Y., Huang, L.Q., Wu, G., Zhi, X.Y., Li, W.J., Dodsworth, J.A., Hedlund, B.P., Zhang, C.L., Hartnett, H.E., Dijkstra, P. and Hungate, B.A. (2013) A comprehensive census of microbial diversity in hot springs of Tengchong, Yunnan Province China using 16S rRNA gene pyrosequencing. PLoS One, 8, e53350.Google Scholar
Huang, X.W., Zhou, M.F., Wang, C.Y., Robinson, P.T., Zhao, J.H. and Qi, L. (2013) Chalcophile element constraints on magma differentiation of Quaternary volcanoes in Tengchong, SW China. Journal of Asian Earth Sciences, 76, 111.Google Scholar
Hynek, B.M., McCollom, T.M., Marcucci, E.C., Brugman, K. and Rogers, K.L. (2013) Assessment of environmental controls on acid-sulfate alteration at active volcanoes in Nicaragua: Applications to relic hydrothermal systems on Mars. Journal of Geophysical Research: Planets, 118, 20832104.Google Scholar
Ikehata, K. and Maruoka, T. (2016) Sulfur isotopic characteristics of volcanic products from the September 2014 Mount Ontake eruption, Japan. Earth Planets and Space, 68, 17.Google Scholar
Jiang, C.S. (1998) Period division of volcano activities in the Cenozoic era of Tengchong. Journal of Seismological Research, 21, 320329 [in Chinese with English Abstract].Google Scholar
Jiang, M., Tan, H.D., Zhang, J.W., Peng, M., Li, Q.Q., Zhang, L.H., Xu, L.H. and Wang, W. (2012) Geophysical mode of Mazhan-Gudong magma chamber in Tengchong volcano-tectonic area. Acta Geoscientica Sinica, 33, 731739 [in Chinese with English Abstract].Google Scholar
Jiang, Z., Li, P., Tu, J., Wei, D.Z., Zhang, R., Wang, Y.H. and Dai, X.Y. (2018) Arsenic in geothermal systems of Tengchong, China: Potential contamination on freshwater resources. International Biodeterioration & Biodegradation, 128, 2835.Google Scholar
Jones, B. and Peng, X.T. (2015) Laminae development in opal-A precipitates associated with seasonal growth of the form-genus Calothrix (Cyanobacteria), Rehai geothermal area, Tengchong, Yunnan Province, China. Sedimentary Geology, 319, 5268.Google Scholar
Kodosky, L. and Keskinen, M. (1990) Fumarole distribution, morphology, and encrustation mineralogy associated with the 1986 eruptive deposits of mount St. Augustine, Alaska. Bulletin of Volcanology, 52, 175185.Google Scholar
Liao, Z.J., Shen, M.Z. and Guo, G.Y. (1991) Characteristics of the Reservoir of the Rehai Geothermal Field in Tengchong, Yunnan Province, China. Acta Geologica Sinica (English Edition), 4, 307320.Google Scholar
Lin, M.S., Peng, S.B., Qiao, W.T. and Li, H. (2014) Petro-geochemistry and geochronology of late Cretaceous-Eocene granites in high geothermal anomaly areas in the Tengchong block, Yunnan Province, China and their tectonic implications. Acta Petrologica Sinica, 30, 527546 [in Chinese with English Abstract].Google Scholar
Liu, L., Salam, N., Jiao, J.Y., Jiang, H.C., Zhou, E.M., Yin, Y.R., Ming, H. and Li, W.J. (2016) Diversity of culturable thermophilic actinobacteria in hot springs in Tengchong, China and studies of their biosynthetic gene profiles. Microbial Ecology, 72, 150162.Google Scholar
Martin, R., Rodgers, K. and Browne, P. (1999) The nature and significance of sulphate-rich, aluminous efflorescences from the Te Kopia geothermal field, Taupo Volcanic Zone, New Zealand. Mineralogical Magazine, 63, 413413.Google Scholar
Masalehdani, M.N.-N., Mees, F., Dubois, M., Coquinot, Y., Potdevin, J.-L., Fialin, M. and Blanc-Valleron, M.-M. (2009) Condensate minerals from a burning coal-waste heap in Avion, Northern France. The Canadian Mineralogist, 47, 573591.Google Scholar
McCollom, T.M., Hynek, B.M., Rogers, K., Moskowitz, B. and Berquo, T.S. (2013) Chemical and mineralogical trends during acid-sulfate alteration of pyroclastic basalt at Cerro Negro volcano and implications for early Mars. Journal of Geophysical Research-Planets, 118, 17191751.Google Scholar
McHenry, L.J., Carson, G.L., Dixon, D.T. and Vickery, C.L. (2017) Secondary minerals associated with Lassen fumaroles and hot springs: Implications for Martian hydrothermal deposits. American Mineralogist, 102, 14181434.Google Scholar
Mckenzie, W.F. and Truesdell, A.H. (1977) Geothermal reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes. Geothermics, 5, 5161.Google Scholar
Mizutani, Y. and Sugiura, T. (1966) The chemical equilibrium of the 2H2S + SO2 = 3S + 2H2O reaction in solfataras of the Nasudake Volcano. Bulletin of the Chemical Society of Japan, 39, 24112414.Google Scholar
Mormone, A., Troise, C., Piochi, M., Balassone, G., Joachimski, M. and Natale, G.D. (2015) Mineralogical, geochemical and isotopic features of tuffs from the CFDDP drill hole: Hydrothermal activity in the eastern side of the Campi Flegrei volcano (southern Italy). Journal of Volcanology & Geothermal Research, 290, 3952.Google Scholar
Naughton, J.J., Greenberg, V.A. and Goguel, R. (1976) Incrustations and fumarolic condensates at Kilauea volcano, Hawaii: field, drill-hole and laboratory observations. Journal of Volcanology and Geothermal Research, 1, 149165.Google Scholar
Onac, B.P., Wynn, J.G. and Sumrall, J.B. (2011) Tracing the sources of cave sulfates: a unique case from Cerna Valley, Romania. Chemical Geology, 288, 105114.Google Scholar
Pierre, D. and Alain, B. (1994) Geochemistry, mineralogy, and chemical modeling of the acid crater lake of Kawah Ijen Volcano, Indonesia. Geochimica et Cosmochimica Acta, 58, 24452460.Google Scholar
Piochi, M., Mormone, A., Balassone, G., Strauss, H., Troise, C. and De Natale, G. (2015) Native sulfur, sulfates and sulfides from the active Campi Flegrei volcano (southern Italy): Genetic environments and degassing dynamics revealed by mineralogy and isotope geochemistry. Journal of Volcanology and Geothermal Research, 304, 180193.Google Scholar
Raab, M. and Spiro, B. (1991) Sulfur isotopic variations during seawater evaporation with fractional crystallization. Chemical Geology Isotope Geoscience, 86, 323333.Google Scholar
Rodgers, K.A., Hamlin, K.A., Browne, P.R.L., Campbell, K.A. and Martin, R. (2000) The steam condensate alteration mineralogy of Ruatapu cave, Orakei Korako geothermal field, Taupo Volcanic Zone, New Zealand. Mineralogical Magazine, 64, 125142.Google Scholar
Rodríguez, A. and van Bergen, M.J. (2016) Volcanic hydrothermal systems as potential analogues of Martian sulphate-rich terrains. Netherlands Journal of Geosciences, 95, 153169.Google Scholar
Rodríguez, A. and van Bergen, M.J. (2017) Superficial alteration mineralogy in active volcanic systems: An example of Poás volcano, Costa Rica. Journal of Volcanology and Geothermal Research, 346, 5480.Google Scholar
Rye, R.O. (2005) A review of the stable-isotope geochemistry of sulfate minerals in selected igneous environments and related hydrothermal systems. Chemical Geology, 215, 536.Google Scholar
Rye, R.O., Bethke, P.M. and Wasserman, M.D. (1992) The stable isotope geochemistry of acid sulfate alteration. Economic Geology, 87, 225262.Google Scholar
Sakae, T., Okada, S., Okamura, K. and Nakano, K. (2011) Unique form hot spring sinter composed of gypsum with special reference to the relation between microorganisms and mineralization. Journal of Hard Tissue Biology, 20, 339343 [in Japanese with English Abstract].Google Scholar
Schiffman, P., Zierenberg, R., Marks, N., Bishop, J.L. and Dyar, M.D. (2006) Acid-fog deposition at Kilauea volcano: A possible mechanism for the formation of siliceous-sulfate rock coatings on Mars. Geology, 34, 921924.Google Scholar
Schoen, R. and Rye, R.O. (1970) Sulfur isotope distribution in Solfataras, Yellowstone National Park. Science, 170, 10821084.Google Scholar
Shangguan, Z.G. (2000) Structure of geothermal reservoirs and the temperature of mantle-derived magma hot source in the Rehai area, Tengchong. Acta Petrologica Sinica, 16, 8390 [in Chinese with English Abstract].Google Scholar
Shangguan, Z.G. and Huo, W.G. (2002) delta D values of escaped H2 from hot springs at the Tengchong Rehai geothermal area and its origin. Chinese Science Bulletin, 47, 146149.Google Scholar
Shangguan, Z.G., Bai, C.H. and Sun, M.L. (2000) Mantle-derived magmatic gas releasing features at the Rehai area, Tengchong county, Yunnan Province, China. Science in China Series D-Earth Sciences, 43, 132140.Google Scholar
Simmons, S.F., Stewart, M.K., Robinson, B.W. and Glover, R.B. (1994) The chemical and isotopic compositions of thermal waters at Waimangu, New Zealand. Geothermics, 23, 539553.Google Scholar
Steiner, A. and Rafter, T.A. (1966) Sulfur isotopes in pyrite, pyrrhotite, alunite and anhydrite from steam wells in the Taupo Volcanic Zone, New Zealand. Economic Geology, 61, 11151129.Google Scholar
Stoiber, R.E. and Rose, W.I. (1974) Fumarole incrustations at active Central American volcanoes. Geochimica et Cosmochimica Acta, 38, 495516.Google Scholar
Stracher, G.B., Prakash, A., Schroeder, P., McCormack, J., Zhang, X.M., Van Dijk, P. and Blake, D. (2005) New mineral occurrences and mineralization processes: Wuda coal-fire gas vents of Inner Mongolia. American Mineralogist, 90, 17291739.Google Scholar
Süer, S. (2004) Monitoring of Chemical and Isotopic Compositions of Geothermal Waters along the North Anatolian Fault Zone. Master Thesis. Middle East Technical University, Turkey.Google Scholar
Szynkiewicz, A., Modelska, M., Buczyński, S., Borrok, D.M. and Merrison, J.P. (2013) The polar sulfur cycle in the Werenskioldbreen, Spitsbergen: Possible implications for understanding the deposition of sulfate minerals in the North Polar Region of Mars. Geochimica et Cosmochimica Acta, 106, 326343.Google Scholar
Tang, M., Ehreiser, A. and Li, Y.L. (2014) Gypsum in modern Kamchatka volcanic hot springs and the Lower Cambrian black shale: Applied to the microbial-mediated precipitation of sulfates on Mars. American Mineralogist, 99, 21262137.Google Scholar
Tong, W. and Zhang, M.Z. (1989) Geothermics in Tengchong. Science Press, Beijing [in Chinese].Google Scholar
Toran, L. and Harris, R.F. (1989) Interpretation of sulfur and oxygen isotopes in biological and abiological sulfide oxidation. Geochimica et Cosmochimica Acta, 53, 23412348.Google Scholar
Valente, T.M. and Gomes, C.L. (2009) Occurrence, properties and pollution potential of environmental minerals in acid mine drainage. Science of the Total Environment, 407, 11351152.Google Scholar
Wang, C. and Gang, H. (2004) Crustal structure in Tengchong Volcano-Geothennal Area, western Yunnan, China. Tectonophysics, 380, 6987.Google Scholar
White, W.B. (2010) Secondary minerals in volcanic caves: Data from Hawai'i. Journal of Cave and Karst Studies, 72, 7585.Google Scholar
Xu, Y., Yang, X.T., Li, Z.W. and Liu, J.H. (2012) Seismic structure of the Tengchong volcanic area southwest China from local earthquake tomography. Journal of Volcanology and Geothermal Research, 239–240, 8391.Google Scholar
Yang, H.Y., Hu, J.F., Hu, Y.L., Duan, Y.Z. and Li, G.Q. (2013) Crustal structure in the Tengchong volcanic area and position of the magma chambers. Journal of Asian Earth Sciences, 73, 4856.Google Scholar
Zhang, G.P., Liu, C.Q., Liu, H., Jin, Z.S. and Han, G.L. (2008) Geochemistry of the Rehai and Ruidian geothermal waters, Yunnan Province, China. Geothermics, 37, 7383.Google Scholar
Zhang, Y.F., Tan, H.B., Zhang, W.J., Wei, H.Z. and Dong, T. (2016) Geochemical constraint on origin and evolution of solutes in geothermal springs in western Yunnan, China. Chemie der Erde – Geochemistry, 76, 6375.Google Scholar
Zhao, C.P., Ran, H. and Chen, K.H. (2011) Present-day temperatures of magma chambers in the crust beneath Tengchong volcanic field, southwestern China: Estimation from carbon isotopic fractionation between CO2 and CH4 of free gases escaped from thermal springs. Acta Petrologica Sinica, 27, 28832897 [in Chinese with English Abstract].Google Scholar
Zhu, M.X., Tong, W. and You, M.Z. (1980) Efflorescence in geothermal areas of Xizang (Tibet) and its geological significance. Acta Scientiarum Naturalum Universitis Pekinensis, 110117 [in Chinese with English Abstract].Google Scholar
Zou, H.B., Fan, Q.C., Schmitt, A.K. and Sui, J.L. (2010) U-Th dating of zircons from Holocene potassic andesites (Maanshan volcano, Tengchong, SE Tibetan Plateau) by depth profiling: Time scales and nature of magma storage. Lithos, 118, 202210.Google Scholar