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A re-examination of herzenbergite–teallite solid solution at temperatures between 300 and 700°C

Published online by Cambridge University Press:  05 July 2018

K. Hayashi ,
A. Kitakaze  and
A. Sugaki
K. Hayashi*
Affiliation:
Department of Mineralogy, Petrology and Economic Geology, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan
A. Kitakaze
Affiliation:
Department of Mineralogy, Petrology and Economic Geology, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan Center for Northeast Asian Studies, Tohoku University, Aoba-ku, Sendai 980-8576, Japan
A. Sugaki
Affiliation:
4-30-503 Kadan, Aoba-ku, Sendai 980-0815, Japan
*
*E-mail: [email protected]
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Abstract

In order to investigate the range of the solid solution series in herzenbergite-teallite minerals, samples of different composition were synthesized. Herzenbergite-teallite minerals were synthesized by an evacuated silica glass tube method at 700°C. A linear relationship between cell dimensions, a, b and c and composition is established. Extension of solid solution to the Pb-rich portion of the system PbS-SnS is limited; the solid solution area is between Pb1.060Sn0.940S2 and SnS at 700°C. Teallite coexisting with galena was also synthesized by hydrothermal recrystallization at 300, 400 and 450°C. The compositions of teallite are Pb1.140Sn0.860S2 at 300°C, Pb1.114Sn0.886S2 at 400°C, and Pb1.124Sn0.876S2 at 450°C, respectively. Their compositions shift towards the PbS end-member from stoichiometric teallite. The cell dimensions of teallite, which was synthesized hydrothermally, follow the linear relationship between cell dimensions and composition established at 700°C.

Keywords

herzenbergiteteallitesolid solution
Type
Research Article
Information
Mineralogical Magazine , Volume 65 , Issue 5 , October 2001 , pp. 645 - 651
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2001

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References

Barnes, H.L. (1971) Investigations in hydrothermal sulfide systems. Pp. 317–55 in: Research Techniques for High Pressure and High Temperature (Ulmer, G.C., editor). Springer-Verlag, New York.CrossRefGoogle Scholar
Bence, A.E. and Albee, A.L. (1968) Empirical factors for the electron microanalysis of silicates and oxides. J. Geol., 76, 382–403.CrossRefGoogle Scholar
Berndt, F. (1954) Über die Bleisulfostannate Boliviens. Neues Jahrb. Mineral. Monatsh., 200–4.Google Scholar
Chang, L.Y. and Brice, W.R. (1971) The herzenbergite– teallite series. Mineral. Mag., 38 186–9.CrossRefGoogle Scholar
Herzenberg, R. (1949) Novedades de la mineralogia Boliviana. Publ. Tecn. Inst. Boliviano Ingen. Minas y Geol. 4 pp.Google Scholar
Kitakaze, A. (1966) Cell parameters refinement using Guinier method. J. Mineral. Soc. Japan, 25, 69–76 (in Japanese with English abstract).Google Scholar
Moh, G.H. (1987) Mutual Pb2+/Sn2+ substitution in sulfosalts. Mineral. Petrol., 36, 191–204.CrossRefGoogle Scholar
Nekrasov, I.Ya., Kulakov, M.P. and Sokolovskaya, Zh.N. (1974) The subsolidus relations in the system PbS-SnS. Geochem. Int., 11, 63–70.Google Scholar
Ohta, E. (1991) Polymetallic mineralization at the Toyoha mine, Hokkaido, Japan. Mining Geol., 41, 279–95.Google Scholar
Ohta, E. (1995) Common features and genesis of tin-polymetallic veins. Resource Geol., Spec. Iss., 14, 187–95.Google Scholar
Ohtsuki, T., Kitakaze, A. and Sugaki, A. (1980) Synthetic minerals with quaternary compositions in the system Cu-Fe-Sn-S, Synthetic sul. de minerals (X). Sci. Rept. Tohoku Univ. Ser. 3, 14, 269–82.Google Scholar
Scott, S.D. (1976) Experimental methods in sulfide synthesis. Pp. S1–S38 in: Sulfide Mineralogy (Ribbe, P.H., editor). Mineralogical Society of America, Washington, D.C. Google Scholar
Seward, T.M. and Barnes, H.L. (1997) Metal transport by hydrothermal ore fluids. Pp. 435–86 in: Geochemistry of Hydrothermal Ore Deposits, 3rd edition (Barnes, H.L., editor). John Wiley & Sons, Inc., New York.Google Scholar
Smeds, S.-A. (1993) Herzenbergite (SnS) in Proterozoic granite pegmatites in north-central Sweden. Mineral. Mag., 57, 489–94.CrossRefGoogle Scholar
Sugaki, A. and Hayashi, K. (1986) Teallite from the Toyoha mine, Hokkaido, Japan. J. Japan. Assoc. Mineral. Petrol. Econ. Geol., 81, 393–8 (in Japanese with English abstract).CrossRefGoogle Scholar
Sugaki, A., Shima, H. and Kitakaze, A. (1972) Synthetic sulfide minerals (IV). Tech. Rept. Yamaguchi Univ., 1, 71–85.Google Scholar
Yajima, J., Ohta, E., Kamiki, T. and Takeyama, T. (1993) Formation model and exploration of the Toyoha mine, Hokkaido, Japan. Resource Geol. Spec. Iss., 15, 451–8.Google Scholar