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A record of anthropogenic Pb deposition in a Mediterranean karst catchment (Lake Vrana, Cres Island, Croatia)

Published online by Cambridge University Press:  05 July 2018

S. Miko*
Affiliation:
Croatian Geological Survey, Sachsova 2, HR-10000, Zagreb, Croatia
S. Mesić
Affiliation:
Croatian Geological Survey, Sachsova 2, HR-10000, Zagreb, Croatia
M. Šparica Miko
Affiliation:
Croatian Geological Survey, Sachsova 2, HR-10000, Zagreb, Croatia
O. Hasan
Affiliation:
Croatian Geological Survey, Sachsova 2, HR-10000, Zagreb, Croatia
*

Abstract

To trace the historyof anthropogenic, atmospheric Pb pollution, analyses of soils from the region and of cores from the karst Lake Vrana (Croat: Vransko jezero) on the island of Cres were performed. The area affected byPb pollution in Croatia covers most of the high-mountain karst region. Since lake sediments can act as archives of atmospheric deposition of metals (and other pollutants) a multi-element analysis as well as Pb isotopes of dated sediment core samples and palaeosoil from the catchment enabled the evaluation of Pb-pollution history. The Pb/Sc ratios and the 206Pb/207Pb ratios allowed the calculation of enrichment factors and the anthropogenic contributions of Pb during the past 4000 y. The sediments of Lake Vrana were found to be a consistent record of Pb pollution in this part of the Mediterranean region, despite the fact that the catchment lost most of its soil cover between 1404 and 1650 AD due to deforestation which caused a major change in sediment composition.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2008

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References

Brännvall, M.-L., Bindler, R., Emteryd, O. and Renberg, I. (2001) Four thousand years of atmospheric lead pollution in northern Europe: a summary from Swedish lake sediments. Journal of Paleolimnology, 25, 421–435.CrossRefGoogle Scholar
Camuffo, D., Secco, C. Brimblecombe, P. and Martin-Vide, J. (2000) Sea Storms in the Adriatic Sea and the Western Mediterranean during the Last Millennium. Climatic Change, 46, 209–223.CrossRefGoogle Scholar
Fortis, A. (1771) Saggio d'osservazioni sopra I'Isola di Cherso ed Ossero. Venezia, 1971, 54 pp.Google Scholar
Martínez Cortizas, A., Garcia-Rodeja, E., Pontevedra Pombal, X., Novoa, Munoz, J.C., Weiss, D. and Cheburkin, A. (2002) Atmospheric Pb deposition in Spain during the last 4600 years recorded by two ombrotrophic peat bogs and implications for the use of peat as archive. Science of the Total Environment, 292, 33.CrossRefGoogle Scholar
Oldfield, F., Asioli, A., Accorsi, C.A., Mercuri, A M., Juggins, S., Langone, L. et al. (2003) A high resolution late-Holocene palaeo environmental record from the central Adriatic Sea. Quaternary Science Reviews, 22, 319–342.CrossRefGoogle Scholar
Ožanić, N., Rubinić, J. and Vrkljan, I. (2003) The regime of inflow and runoff from Vrana lake and the risk of permanent water pollution. ICGGE Bled 2003.Google Scholar
Schmidt, R., Miiller, J., Drescher-Schneider, R., Krisai, R., Szeroczynska, K. and Baric, A. (2000) Changes in lake level and trophy at Lake Vrana, a large karstic lake on the Island of Cres (Croatia), with respect to palaeoclimate and anthropogenic impacts during the last approx. 16,000 years. Journal of Limnology, 59, 113–130.CrossRefGoogle Scholar
Shotyk, W., Weiss, D., Appleby, P.G., Cheburkin, A.K., Frei, R., Gloor, M., Kramers, J.D., Reese, S. and van der Knaap, W.O. (1998) History of atmospheric lead deposition since 12,370 14C yr BP recorded in a peat bog profile, Jura Mountains, Switzerland. Science, 281, 1635–1640.CrossRefGoogle Scholar
Shotyk, W., Weiss, D.J., Kramers, J.D., Frei, R., Cheburkin, A.K., Gloor, M. and Reese, S. (2001) Geochemistry of the peat bog at Etang de la Gruere, jura Mountains, Switzerland, and its record of atmopheric Pb and lithogenic trace elements (Sc, Ti, Y, Zr, and REE) since 12,370 14C yr BP. Geochimica et Cosmochimica Acta, 65, 2337–2360.CrossRefGoogle Scholar
Surić, M., Juračić, M., Horvatincic, H. and Krajcar Bronic, I. (2005) Late Pleistocene-Holocene sea-level rise and the pattern of coastal karst inundation: records from submerged speleothems along the Eastern Adriatic Coast (Croatia). Marine Geology, 214, 163–175.CrossRefGoogle Scholar
Yang, H., Linge, K. and Rose, N. (2007) The Pb pollution fingerprint at Lochnagar: The historical record and current status of Pb isotopes. Environmental Pollution, 145, 723–729.CrossRefGoogle ScholarPubMed