Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-23T04:34:26.314Z Has data issue: false hasContentIssue false

Quantitative determination of analcime in pumice samples by X-ray diffraction

Published online by Cambridge University Press:  05 July 2018

R. J. Parker*
Affiliation:
Department of Geology, Imperial College, London

Summary

A quantitative X-ray diffraction method has been successfully applied to the determination of analcime in pumice rock samples. A calibration line was constructed from spiked pumice standards (range: 0 to 42%) and the mean relative error of the standards on the calibration line was < 0·6%. The major-element compositions of the samples and standards were available, and this allowed the total mass absorption coefficients to be calculated. The latter were then used to correct the sample and standard intensities for absorption effects resulting from compositional variations. When compositional data already exist, the calculation of the total absorption coefficient provides a rapid and accurate alternative to direct measurement, or to the use of an internal standard.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1978

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Gupta, (A. K.) and Fyfe, (W. S.), 1975. Can. Mineral. 13, 361.Google Scholar
Harvey, (P. K.), Taylor, (D. M.), Hendry, (R. D.), and Bancroft, (F.), 1973. X-Ray Spectrom. 2, 33.Google Scholar
Heinrich, (K. F. J.), 1966. In The Electron Microprobe, p. 1035; eds. Mckinly, T. D., Heinrich, K. F. J., and Wittry, D. B.. Wiley. New York.Google Scholar
Klug, (H. P.) and Alexander, (L. E.), 1973. X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials, 2nd edn., p. 966. Wiley. New York.Google Scholar
Leroux, (J.), Lennox, (D. H.), and Kay, (K.), 1953. Anal. Chem. 25, 740.CrossRefGoogle Scholar
Niskanen, (E.), 1964. Ibid. 36, 12-68.Google Scholar
Norrish, (K.) and Hutton (J. T.), 1969. Geochim. Cosmochim. Ada, 33, 431.CrossRefGoogle Scholar
Norrish, (K.) and Taylor, (R. M.), 1962. Clay Minerals Bull. 5, 98.CrossRefGoogle Scholar
Parker, (R. J.), 1978. X-Ray Spectrom. 7, 38.CrossRefGoogle Scholar
Parker, (R. J.) and Willis, (J. P.), 1977. Computers and Geosciences, 3, 115.CrossRefGoogle Scholar
Williams, (P. P.), 1959. Anal. Chem. 31, 1842.CrossRefGoogle Scholar