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Pressure buffering in a diamond anvil cell

Published online by Cambridge University Press:  05 July 2018

T. Arlt*
Affiliation:
Bayerisches Geoinstitut, Universität Bayreuth, D 95440 Bayreuth, Germany
R. J. Angel
Affiliation:
Bayerisches Geoinstitut, Universität Bayreuth, D 95440 Bayreuth, Germany
*

Abstract

The clinopyroxenes kanoite and spodumene were studied by single-crystal X-ray diffraction in a diamond anvil cell (DAC) at room temperature. At the displacive phase transitions between the C2/c and P21/c polymorphs both phases coexist within the same crystal. In this two-phase region the pressure in the DAC remains constant. The experimental results demonstrate that pressure buffering at first-order phase transitions can occur in the DAC.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2000

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References

Allan, D.R., Miletich, R. and Angel, R.J. (1996) A diamond-anvil cell for single-crystal X-ray diffraction studies to pressures in excess of 10 GPa. Rev. Scienti. c Instruments, 67, 840–2.CrossRefGoogle Scholar
Angel, R.J., Chopelas, A. and Ross, N.L. (1992) Stability of high-density clinoenstatite at uppermantle pressures. Nature, 358, 322–4.CrossRefGoogle Scholar
Angel, R.J., Allan, D.R., Miletich, R. and Finger, L.W. (1997) The use of quartz as an internal pressure standard in high-pressure crystallography. J. Appl. Crystallogr., 30, 461–6.CrossRefGoogle Scholar
Angel, R.J., Downs, R.T. and Finger, L.W. (2000) High-pressure, high-temperature diffractometry. In: Comparative Crystal Chemistry (Hazen, R.M., editor). Reviews in Mineralogy, 39. Mineralogical Society of America, Washington, D.C. (in prep.)Google Scholar
Arlt, T. and Angel, R.J. (1999) High-pressure phase transition in spodumene LiAlSi2O6. XVIIIth IUCr Congress & General Assembly (Glasgow), Abstract volume, 461.Google Scholar
Arlt, T., Kunz, M., Stolz, J., Armbruster, T. and Angel, R. (2000) P-T-X data on P21/c clinopyroxenes and their displacive phase transitions. Contrib. Mineral. Petrol., 138, 3545.CrossRefGoogle Scholar
Arlt, T., Angel, R.J., Miletich, R., Armbruster, T. and Peters, T. (1998) High pressure P21/c-C2/c phase transitions in clinopyroxenes: Influence of cation size and electronic structure. Amer. Mineral., 83, 1176–81.CrossRefGoogle Scholar
Bean, V.E., Akimoto, S., Bell, P.M., Block, S., Holzapfel, W.B., Manghnani, M.H., Nicol, M.F. and Stishov, S.M. (1986) Another step toward an international practical pressure scale. Physica, 139 & 140B, 52–4.Google Scholar
Getting, I.C. (1998) The practical pressure scale: fixing fixed points and future prospects. Eos, Transactions (suppl.) AGU, 79(45), F830.Google Scholar
Getting, I.C. and Burnley, P.C. (1994) Absolute pressure and temperature calibration to 6 GPa and 1700 K using a gas piston cylinder apparatus. Eos, Transactions (suppl.) AGU, 75(44), 722.Google Scholar
Hugh-Jones, D., Woodland, A. and Angel, R.J. (1994) The structure of high-pressure C2/c ferrosilite and crystal chemistry of high-pressure C2/c pyroxenes. Amer. Mineral., 79, 1032–41.Google Scholar
Ito, E. and Presnall, D.C. (1998) Report on the First International Pressure Calibration Workshop. Rev. High Pressure Sci. Technol., 7, 151–3.CrossRefGoogle Scholar
King, H. and Finger, L.W. (1979) Diffracted beam crystal centring and its application to high-pressure crystallography. J. Appl. Crystallogr., 12, 374–8.CrossRefGoogle Scholar
Mao, H.K., Xu, J. and Bell, P.M. (1986) Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic condition. J. Geophys. Res., 91, 4673–6.CrossRefGoogle Scholar
Merrill, L. and Bassett, W.A. (1975) The crystal structure of CaCO3(II), a high-pressure metastable phase of calcium carbonate. Acta Crystallogr., B31, 343–9.CrossRefGoogle Scholar
Rubie, D.C. (1999) Characterising the sample environment in multianvil high-pressure experiments. Phase Transitions, 68, 431–51.CrossRefGoogle Scholar