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Post-crystallisation modification of the igneous layering in the Nunarssuit and West Kûngnât syenites, South Greenland1

Published online by Cambridge University Press:  05 July 2018

Mark Hodson*
Affiliation:
Department of Geology and Geophysics, Kings Buildings, West Mains Road, Edinburgh, EH9 3JW, Scotland

Abstract

The chemistry and textures of the minerals in the layered syenites of Nunarssuit and West Kûngnât record a complex post-crystallisation history. The initial cumulus phases were alkali feldspar, pyroxene and olivine, apatite and opaque oxides. Grain size distributions of the pyroxenes and olivines have been modified since crystallisation, possibly during transport of these grains in a density current, prior to deposition in layers. Olivines and pyroxenes re-equilibrated with intercumulus melt. The lower ratio of mafic phases to intercumulus fluid in leucocratic layers has resulted in pyroxene and olivine in these layers undergoing more re-equilibration that in melanocratic layers, consequently pyroxenes and olivines in leucocratic layers are more ferroan. Pyroxenes reacted with either intercumulus or deuteric fluid to form amphibole. In West Kûngnât pyroxene and amphibole re-equilibrated via a later fluid. Olivines reacted with deuteric fluid to produce biotites, probably at temperatures < 550°C. After crystallisation alkali feldspars exsolved, the exsolution textures coarsened in the presence of deuteric fluids with a magmatic origin, possibly at temperatures as low as 450°C. Zoning patterns of apatites and zircons were modified during interactions with either, or both intercumulus or deuteric fluids. Leucocratic layers underwent more modification than melanocratic ones, probably due to the higher concentration of intercumulus melt in the former leading to a higher concentration of deuteric fluids as water exsolved from the magma during cooling. The syenites underwent little compaction during solidification.

Type
Intraplate Alkaline Magmatism
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1997

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Footnotes

*

Present address: Macanlay Land Use Research Institute, Craigiebuckler, Aberdeen, AB15 8QH, Scotland

1

The first seven papers in this issue were presented at the Conference on Intraplate Alkaline Magmatism held at the University of Birmingham on 11-12 April 1996. The contributions were edited by Dr Adrian Finch.

References

Adams, H.G., Cohen, L.H. and Rosenfeld, J.L. (1975) Solid inclusion piezothermometry lI: Geometric basis, calibration for the association quartz-garnet and application to some pelitic schists. Amer. Mineral., 60, 584-98.Google Scholar
Barnes, S.J. (1986) The effect of trapped liquid crystallisation on cumulus mineral composition in layered intrusions. Contrib. Mineral. Petrol., 93, 524-31.CrossRefGoogle Scholar
Blaxland, A.B., O. van, Breemen, Emeleus, C.H. and Anderson, J.G. (1978) Age and origin of the major syenite centres of the Gardar: Rb—Sr studies. Geol. Soc. Amer. Bull. 78, 231–44.2.0.CO;2>CrossRefGoogle Scholar
Bouch, J.E., Hole, M.J., Trewin, N.H. and Morton, A.C. (1996) Low-temperature mobility of the rare-earth elements during sandstone diagenesis. Geol. Soc. 152, 895-8.CrossRefGoogle Scholar
Boudreau, A.E. (1987) Pattern formation during crystallisation and the formation of line-scale layering. In Origins qf lgneous Layering (Parsons, I., ed.). NATO ASI Series C196, D. Reidel Publishing Company, Dordrecht, 453-71.CrossRefGoogle Scholar
Brown, W.L. and Parsons, I. (1994) Feldspars in igneous rocks. In Fehlspars and their reaction (Parsons, I., ed.). NATO ASI Series C421, D. Kulwer Academic publishers 449-99.CrossRefGoogle ScholarPubMed
Buddington, A.F. and Lindsley, D.H. (1964) Iron-titanium oxide minerals and synthetic equivalents. J. Petrol., 5, 310-57.CrossRefGoogle Scholar
Butterfield, A.W. (1980) Geology of the Western part of the Nunarssuit alkaline complex of south Greenland. Unpubl PhD thesis, University of Aberdeen.Google Scholar
Cashman, K.V. and Ferry, J.M. (1988) Crystal size distribution in rocks and the kinetics and dynamics of crystallisation III. Metamorphic crystallisation. Contrib. Mineral. Petrol., 99, 401-15.CrossRefGoogle Scholar
Cashman, K.V. and Marsh, B.D. (1988) Crystal size distribution in rocks and the kinetics and dynamics of crystallisation II. Igneous crystallisation. Contrib. Mineral. Petrol., 99, 292-305.CrossRefGoogle Scholar
Dachs, E. (1994) Annite stability revised. 1. Hydrogen-sensor data for the reaction annite = sanidine + magnetite + H2 . Contrib. Mineral. Petrol., 117, 229-40.CrossRefGoogle Scholar
Deer, W.A., Howie, R.A. and Zussman, J. (1978) Rock-forming minerals volume 2A. Single-chain silicates. Longman, 2nd ed. pp 668.Google Scholar
Deer, W.A., Howie, R.A. and Zussman, J. (1982) Rock-forming minerals volume 1A. Orthosilicates. Longman, 2nd ed. pp 918.Google Scholar
Droop, G.T.R. (1987) A general equation for estimating Fe concentrations in ferromagnesian silicates and oxides from microprobe analyses, using stoichio-metric criteria. Mineral. Mag., 45, 201—9.Google Scholar
Emeleus, C.H. and Upton, B.G.J. (1976) The Gardar Period in southern Greenland. In The Geology of Greenland (Escher, A. and Watt, W.S., eds.). Greinl. Geol. Unders., Copenhagen 153—81.Google Scholar
Ferguson, J. and Pulvertaft, T.C.R. (1963) Contrasted styles of igneous layering in the Gardar province of South Greenland. Spec. Pap. Mineral. Soc. Amer:, 1, 10-21.Google Scholar
Finch, A.A. (1990) The chemical and isotopic nature of fluids associated with alkaline magmatism, South Greenland. Unpubl PhD thesis, University of Edinburgh.Google Scholar
Finch, A.A. and Walker, F.D.L. (1991) Cathodoluminescence and microporosity in alkali feldspars from the Blue Moon Perthosite, S Greenland. Mineral. Mag., 55, 585-9.CrossRefGoogle Scholar
Finch, A.A., Parsons, I. and Mingard, S.C (1995) Biotites as indicators of fluorine fugacities on late-stage magmatic fluids: the Gardar Province, south Greenland. J. Petrol., 36, 1701-28.Google Scholar
Gilbert, M.C., Heltz, R.T., Popp, R.K. and Spear, F.S. (1982) Experimental studies of amphibole stability. In Amphiboles: Petrography and phase relationships (Veblen, D.R., and Ribbe, P.H., eds), Amer. Min. Soc. Reviews in Mineralogy 9B, 229346.CrossRefGoogle Scholar
Hewitt, A.D. and Wones, D.R. (1984) Experimental relations in the micas. In Micas (Bailey, S.W., ed.). Amer. Min. Soc. Reviews in Mineralogy, 13 201—47.Google Scholar
Higgins, M.D. (1991) The origin of laminated and massive anorthosites, Sept Iles layered intrusion, Quebec, Canada. Contrib. Mineral. Petrol., 106, 340-54.CrossRefGoogle Scholar
Hodson, M.E. (1994) Igneous layering in the syenites of Nunarssuit and West Kûingnât, South Greenland. Unpubl PhD thesis, University of Edinburgh.Google Scholar
Hodson, M.E. and Finch, A.A. (1997) Trough layering in the Western Syenite of Kûingnât, S Greenland: Mineralogy and mechanisms of formation. Contrib. Mineral. Petrol., 127, 4656.CrossRefGoogle Scholar
Hole, M.J., Trewin, N.H. and Still, J. (1992) Mobility of the high field strength, rare earth elements and yttrium during late stage diagenesis. J. Geol. Soc. Lond., 149, 689-92.CrossRefGoogle Scholar
Hunter, R.H. (1987) Textural equilibrium in layered igneous rocks. In Origins of Igneous Layering (Parsons, I., ed). NATO AS1 Series C196, D. Reidel Publishing Company, Dordrecht 453—71.Google Scholar
Hunter, R.H. (1993) Cumulate texture and physical process. Conference abstract, Symposium on layering in igneous complexes, Johannesburg, South Africa.Google Scholar
lrvine, T.N. (1982) Terminology for layered cumulates. J. Petrol., 23, 127-62.Google Scholar
lrvine, T.N. (1987a) Processes involved in the formation and development of layered igneous rocks. Appendix II. In Origins of Igneous Layering (Parsons, I., ed). NATO ASI Series C196, D. Reidel Publishing Company, Dordrecht, 649—56.Google Scholar
lrvine, T.N. (1987b) Layering and related structures in the Duke Island and Skaergaard intrusion: simila-rities, differences and origins. In Origins of lgneous Layering (Parsons, I., ed). NATO ASI Series C196, D. Reidel Publishing Company, Dordrecht 185245.Google Scholar
Marsh, B.D. (1988) Crystal size distribution in rocks and the kinetics and dynamics of crystallisation I : Theory. Contrib. Mineral. Petrol., 99, 277-91.CrossRefGoogle Scholar
McBirney, A.R. and Noyes, R.M. (1979) Crystallisation and layering of the Skaergaard Intrusion. J. Petrol., 20, 487554.CrossRefGoogle Scholar
Mitchell, R.H. (1990) A review of the compositional variation of amphiboles in alkaline plutonic com-plexes. Lithos, 26, 135-56.CrossRefGoogle Scholar
Munoz, J.L. (1984) F-OH and CI-OH exchange in micas with application to hydrothermal ore deposits. In Micas (Bailey, S.W., ed. Amer. Min. Soc. Reviews in Mineralogy, 13, 469-94.Google Scholar
Parsons, I. (1979) The Klokken gabbro-syenite complex, S Greenland. Cryptic variation and origin of inversely graded layering. J. Petrol., 20, 653—94.CrossRefGoogle Scholar
Parsons, I. (1981) The Klokken gabbro-syenite complex, South Greenland: quantitative interpretation of mineral chemistry. J. Petrol., 22, 233—60.CrossRefGoogle Scholar
Parsons, I. (1987) Origins of Igneous Layering. NATO AS1 Series C196, D. Reidel Publishing Company, Dordrecht.CrossRefGoogle Scholar
Parsons, I. and Brown, W.L. (1984) Feldspars and the thermal history of igneous rocks. In Feldspars and Feldspathoids: (Brown, W.L., ed). NATO ASI Series C137, D. Reidel Publishing Company, Dordrecht 317-71.CrossRefGoogle Scholar
Parsons, I. and Brown, W.L. (1988) Sidewall crystal-lisation in the Klokken intrusion: zoned ternary feldspars and co-existing minerals. Contrib. Mineral. Petrol., 98, 431-43.CrossRefGoogle Scholar
Parsons, I., Mason, R.A., Becker, S.M. and Finch, A.A. (1991) Biotite equilibria and fluid circulation in the Klokken stock, South Greenland. J. Petrol., 32, 1299-333.CrossRefGoogle Scholar
Powell, M. (1978) The crystallisation history of the Igdlerfigssalik nepheline syenite intrusion, Greenland. Lithos, 11, 99-120.CrossRefGoogle Scholar
Rae, D.A. and Chambers, A.D. (1988) Metasomatism in the North Qôroq centre, South Greenland: cathodo-luminescence and mineral chemistry of alkali feldspars. Trans. Roy. Soc. Edin.: Earth Sci., 79, 112.CrossRefGoogle Scholar
Rae, D.A., Coulson, I.M. and Chambers, A.D. (1996) Metasomatism in the North Qôroq centre, South Greenland: apatite chemistry and rare-earth element transport. Mineral. Mag., 60, 207-20.CrossRefGoogle Scholar
Rubin, J.N., Henry, C.D. and Price, J.G. (1989) Hydrothermal zircons and zircon overgrowths, Sierra Blanca Peaks, Texas. Amer. Mineral., 74, 865-9.Google Scholar
Smith, J.V. and Brown, W.L. (1988) Feldspar minerals vol. 1. Springer-Berlin Heidelberg NY 828 pp.CrossRefGoogle Scholar
Sparks, R.S.J., Huppert, H.E., Kerr, R.C., McKenzie, D.P. and Tait, S.R. (1985) Postcumulus processes in layered intrusions. Geol. Mag., 122, 558—68.CrossRefGoogle Scholar
Strong, D.E. and Taylor, R.P. (1984) Magmatic-subsolidus and oxidation trends in composition of amphiboles from silica-saturated peralkaline rocks. Tscherm. Mineral. Petrol. Mitt., 32, 211-22.CrossRefGoogle Scholar
Thompson, P. (1996) The role of K-feldspar hydrate in mantle petrogenesis. Unpubl PhD thesis, University of Edinburgh.Google Scholar
Upton, B.G.J. (1960) The alkaline igneous complex of Kûingnât Fjeld, South Greenland. Grøn. Geol. Und. Rap., 123(4).Google Scholar
Upton, B.G.J. (1961) Textural features of some contrasted igneous cumulates from South Greenland. Grøn. Geol. Unders. Rap., 123(6).Google Scholar
Upton, B.G.J. (1974) The alkali province of SW Greenland. In The Alkaline Rocks (Scirensen, H., ed). Wiley, New York 221-38.Google Scholar
Upton, B.G.J. and Emeleus, C.H. (1987) Mid-Proterozoic alkaline magmatism in S Greenland: The Gardar Province. In Alkaline Igneous Rocks (Fitton, J.G. and Upton, B.G.J., eds.) Geol. Soc. Spec. Publ. 30, 449-71.Google Scholar
Upton, B.G.J., Emeleus, C.H., Parsons, I. and Hodson, M.E. (1996) Layered Alkali Igneous rocks of the Gardar Province, South Greenland. In Layered Intrusions (Cawthorn, R.G., ed.) Elsevier 331—64.CrossRefGoogle Scholar
Worden, R.H., Walker, F.D.L., Parsons, I. and Brown, W.L. (1990) Development of microporosity, diffusion channels and deuteric coarsening in perthitic alkali feldspar. Contrib. Mineral. Petrol., 104, 507-15.CrossRefGoogle Scholar
Zhu, C. and Sverjensky, D.A. (1992) F-CI-OH partitioning between biotite and apatite. Geochim. Cosmochim. Acta, 56, 3425—67.CrossRefGoogle Scholar