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Phosphatian coffinite with rare earth elements and Ce-rich françoisite-(Nd) from sandstone beneath a natural fission reactor at Bangombé, Gabon

Published online by Cambridge University Press:  05 July 2018

Janusz Janeczek
Affiliation:
Department of Earth Sciences, University of Silesia, ul. Bedzinska 60, PL-41-200 Sosnowiec, Poland
Rodney Ewing
Affiliation:
Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, NM 87131-1116, USA

Extract

Spontaneous fission reactions occurred in several uranium deposits in SE Gabon approximately two billion years ago. The reactor zones, between 10 to 50 cm thick, are found in Proterozoic sandstones and consist of high-grade uranium ore mantled by illite and/or chlorite (Gauthier-Lafaye et al., 1989). During a mineralogical study of sandstones (quartz arenites) underlying a natural fission reactor at Bangombé (20 km south of the Oklo uranium deposit), we have found several grains of a uranous silicate, coffinite, with unusually high concentrations of phosphorous and enriched in light rare earth elements (LREE).

Type
Short Communications
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1996

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References

Belova, L.N., Gorshkov, A,J., Ivanova, O.A. and Sivtsov, A.V. (1980) Nature of the so-called phosphorus-bearing coffinite. Doklady Earth Science Sections, 255, 156—8 (translated from DokL Akad. Nauk SSSR, 255, 428-30).Google Scholar
Gauthier-Lafaye, F., Weber, E. and Ohmoto, H. (1989) Natural fission reactors of Oklo. Econ Geol, 84, 2286-95.CrossRefGoogle Scholar
Hansley, P.L. and Fitzpatrick, J.J. (1989) Compositional and crystallographic data on REE-bearing coffinite from the Grants Uranium region, northwestern New Mexico. Amer. Mineral.t, 74, 263–70.Google Scholar
Hemingway, B.S. (1982) Thermodynamic properties of selected uranium compounds and aqueous species at 298.15 K and 1 bar and at higher temperatures. Preliminary models for the origin of coffinite deposits. U.S. Geol. Survey Open-File Report, 82-619, 60 pp.Google Scholar
Hidaka, H., Takahashi, K. and Holliger, P. (1994) Migration of fission products into micro-minerals of the Oklo natural reactors. Radiochim. Acta, 66/67, 463—8.Google Scholar
Janeczek, J. (1991) Composition and origin of coffinite from Jachymov, Czechoslovakia. N. Jb. Miner. Mh., 9, 385–95.Google Scholar
Janeczek, J. and Ewing, R.C. (1992) Coffinitization - a mechanism for the alteration of UO2 under reducing conditions. Mat. Res. Soc. Symp. Proc., 257, 497-503.Google Scholar
Piret, P., Deliens, M., and Piret-Meunier, J. (1988) La françOisite-(Nd), nouveau phosphate d'uranyle et de terres rares; propriétés et structure cristalline. Bull. Minéral. 111, 443—9.CrossRefGoogle Scholar
Smits, G. (1989) (U,Th)-bearing silicates in Reefs of the Witwatersrand, South Africa. Canad. Mineral., 27, 643-55.Google Scholar
Speer, J.A. (1982) Zircon. In: Orthosilicates. Reviews in Mineralogy(Ribbe, P.H., ed.), MSA, pp. 67—112.Google Scholar
Stieff, L.R., Stem, T.W. and Sherwood, A.M. (1956) Coffinite, a uranous silicate with hydroxyl substitution -a new mineral. Amer. Minerals 41, 675—88.Google Scholar