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Phase relations in the system PbS-PbSe-PbTe

Published online by Cambridge University Press:  05 July 2018

H. Liu  and
L. L. Y. Chang
H. Liu
Affiliation:
Department of Geology, University of Maryland, College Park, Maryland 20742, U.S.A.
L. L. Y. Chang
Affiliation:
Department of Geology, University of Maryland, College Park, Maryland 20742, U.S.A.
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Abstract

Phase relations in the system PbS-PbSe-PbTe were investigated in the temperature range between 1150 and 300°C. There is a complete solid solution series along the join PbS-PbSe, whereas miscibility gaps exist below ∼ 350°C and 805°C along joins PbSe-PbTe and PbS-PbTe, respectively. Both gaps extend into the ternary system, and the range of the gap between PbS and PbTe reduces in size with temperature as well as Se-content.

By using the subregular model of mixing (Ganguly and Saxena, 1987), mixing energetics and activity composition relations of PbX were derived. The temperature-dependence of the interaction parameters was calculated to be 5057.6 − 1.7T, 9605.2 − 4.4T, 3933.2 − 3.1T (T < 500°C), 6410.3 − 6.35T (T < 500°C) 1649 − 0.26T, 1594.6 − 0.2T, and 12906.3 − 17.3T for WWSte, WTeS, WSeTe, WTeSe, WSSe, WSeS, and WSSeTe, respectively. A critical temperature along the join PbS-PbSe at ∼ 100°C was obtained from interaction parameter calculation, which suggests the separation of the PbS-PbSe series.

Correlation of solid-solution ranges established in this study with natural occurrences was made.

Keywords

lead chalcogenidesphase relationsthermodynamicsPbS-PbSe-PbTe system
Type
Petrology and Geochemistry
Information
Mineralogical Magazine , Volume 58 , Issue 393 , December 1994 , pp. 567 - 578
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

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References

Benoit, P. H. (1987) Adaption to microcomputer of the Appleman-Evans program for indexing and least-squares refinement of powder-diffraction data for unit cell dimensions. Amer. Mineral., 11, 1018-9.Google Scholar
Bethke, P. and Barton, P. B. (1961) Unit cell dimension versus composition in the systems: PbS-CdS, PbS-PbSe, ZnS-ZnSe and CuFeSigo-CuFeSeLso. U.S.G.S. Professional Paper 424B, B266-70.Google Scholar
Coleman, R. G. (1959) The natural occurrence of galena-clausthalite solid solution series. Amer. Mineral, 44, 166–75.Google Scholar
Darrow, M. S., White, W. B. and Roy, R. (1966) Phase relations in the system PbS-PbTe. Trans. Metal. Soc. AIME, 236, 654–8.Google Scholar
Dombrugov, M. R. and Zhovnir, G. L. (1986) Calculation of the phase equilibria in the system Pb-PbTe-PbSe. Izv. Akad. Nauk SSSR, Neor-gan. Mater., 24, 334–6.Google Scholar
Earley, J. W. (1950) Description and synthesis of selenide minerals. Amer. Mineral., 35, 337–64.Google Scholar
Elagina, E. I. and Abrikosov, N. Kh. (1956) Investigation of the PbTe-PbSe system. Dokl. Akad. Nauk SSSR, 111, 353–4.Google Scholar
Filimonova, C. E., Levin, V. L., Abulgazina, S. D., Eremeeva, E. Ya and Mitina, V. F. (1986) Tellurium minerals in ores of the Aiderly copper porphyry ore deposit. Zap. Vses. Min. Obshch., 115, 459–66 (in Russian).Google Scholar
Ganguly, J.I and Saxena, S. K. (1987) Mixtures and Mineral Reactions. Springer-Verlag, Berlin, New York, London, Paris and Tokyo, 291pp.CrossRefGoogle Scholar
Gavrilenko, B. V. (1987) First occurrence of selenides in the Kola Peninsula. Dokl. Akad. Nauk SSSR, 296, 1213–6.Google Scholar
Grimes, D. E. (1965) The Pb-PbTe-PbSe subtern-ary system. Trans. Metal. Soc, AIME, 233, 1442–4.Google Scholar
Gromakov, S. D., Zoroatskaya, I. V., Latypov, Z. M., Chvala, M. A., Eidel'sman, E. A., Badygina, L. I. and Zari'pora, L. G. (1964) Method of studying the equilibrium diagram of semiconducting systems. Russ. Jour. Inorg. Chem., 9, 1340.Google Scholar
Guilbert, J. W. and Park, C. F. (1986) The Geology of Ore Deposits, W. H. Freeman Company, San Francisco, 985pp.Google Scholar
Healy, R. E. and Petruk, W. (1992) Graphic galena—clausthalite solid solution in low Fesphalerite from the Trout Lake massive sulfide ores, Flin Flon, Manitoba. Econ. Geol., 87, 1906–10.CrossRefGoogle Scholar
Izawa, E., Urashima, Y., Ibaraki, K., Suzuki, R., Yokoyama, T., Kawasaki, K., Koga, A. and Taguchi, S. (1990) The Hishikari gold deposit: high-grade epithermal veins in quaternary volca-nics of southern Kyushu, Japan. J. Geochem. Explor., 36, 1–56.CrossRefGoogle Scholar
Johan, Z., Picot, P. and Ruhtmann, F. (1987) The ore mineralogy of the Otish Mountains uranium deposit, Quebec: Skippenite, Bi2Se2Te and wat-kinsonite, Cu2PbBi4(Se,S)g, two new mineral species. Can. Mineral., 25, 625–38.Google Scholar
Kovalenker, V. A., Laputina, I. P. and Vyal'sov, L. N. (1971) First find of minerals of galena—claustha-lite series in copper-nickel sulfide ores. Geol. Rud. Mestorozhd., 13, 98–101.Google Scholar
Kullerud, G. and Yoder, H. S. (1959) Pyrite stability relations in the Fe—S system. Econ. Geol., 54, 533–72.CrossRefGoogle Scholar
Malevskii, A. Yu. (1963) Effect of selenium as an isomorphous replacement of sulfide sulfur with tellurium. Dokl. Akad. Nauk SSSR, 152, 191–3.Google Scholar
Romanenko, V. N. and Sidorov, A. F. (1975) Use of a diffusion couple to determine solid-phase solubility in the system PbTe-PbS. Izv. Akad. Nauk SSSR, Neorgan. Mater., 11, 432–7.Google Scholar
Saxena, S. K. (1973) Thermodynamics of Rock-forming Crystalline Solutions. Springer-Verlag, Berlin, Heidelberg and New York, 189pp.CrossRefGoogle Scholar
Simpson, D. R. (1961) The binary system PbS-PbSe. Amer. Mineral., 46, 150–3.Google Scholar
Sindeyeva, N. D. and Godovikov, A. A. (1959) Isomorphism of S and Te in galena. Dokl. Akad. Nauk SSSR, 127, 431–4.Google Scholar
Spiridonov, E. M., Sokolova, H. F., Gapeyev, A. K., Daskevskaya, D. M., Yevstigneyeva, T. L., Chvileva, T. N., Demidov, V. G., Balaskov, Ye. P., and Shul'ga, V. I. (1986) New mineral— argentotennantite. Dokl. Akad. Nauk SSSR, 290, 206–10.Google Scholar
Steininger, J. (1970) Phase diagrams of the PbTe—PbSe pseudo-binary system. Metal. Trans., 1, 2939–41.Google Scholar
Threadgold, I. M. (1960) Mineral composition of some uranium ores from the South Alligator river area, Northern Territory. CSIRO Austral. Mineragraphic Invest. Tech. Paper, 2, 53pp.Google Scholar
Vikre, P. G. (1985) Precious metal vein system in the National District, Humboldt County, Nevada. Econ. Geol, 80, 360–93.CrossRefGoogle Scholar
Wright, H. D., Barnard, W. M. and Halbig, J. B. (1965) Solid solutions in the systems ZnS-ZnSe and PbS-PbSe at 300°C and above. Amer. Mineral, 50, 1802–15.Google Scholar
Yamamoto, S. (1956) Solid solutions of lead sulfide, selenide, and telluride. Scient. Rept., Tohoku Univ., First Series, 40, 11–6.Google Scholar
Yushkin, N. P. and Parlov, L. G. (1983) Isomorphic galena-clausthalite series: First occurrence of intermediate members at Novaya Zemlya. Akad. Nauk SSSR, Komi. Fil Inst. Geol, 40, 38–44.Google Scholar