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Parisite-(La), ideally CaLa2(CO3)3F2, a new mineral from Novo Horizonte, Bahia, Brazil

Published online by Cambridge University Press:  28 February 2018

Luiz A. D. Menezes Filho ,
Mario L. S. C. Chaves ,
Nikita V. Chukanov ,
Daniel Atencio ,
Ricardo Scholz ,
Igor Pekov ,
Geraldo Magela da Costa ,
Shaunna M. Morrison ,
Marcelo B. Andrade  and
Erico T. F. Freitas
...Show all authors
Luiz A. D. Menezes Filho
Affiliation:
Universidade Federal de Minas Gerais (UFMG), Instituto de Geociências, Departamento de Geologia, Avenida Antônio Carlos, 6627, 31270-901, Belo Horizonte, MG, Brazil
Mario L. S. C. Chaves
Affiliation:
Universidade Federal de Minas Gerais (UFMG), Instituto de Geociências, Departamento de Geologia, Avenida Antônio Carlos, 6627, 31270-901, Belo Horizonte, MG, Brazil
Nikita V. Chukanov
Affiliation:
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432Russia
Daniel Atencio*
Affiliation:
Universidade de São Paulo, Instituto de Geociências, Rua do Lago 562, 05508-080, São Paulo, Brazil
Ricardo Scholz
Affiliation:
Universidade Federal de Ouro Preto (UFOP), Escola de Minas, Departamento de Geologia, Campus Morro do Cruzeiro, 35400-000, Ouro Preto, MG, Brazil
Igor Pekov
Affiliation:
Faculty of Geology, Moscow State University, Vorobievy Gory, Moscow, 119991Russia
Geraldo Magela da Costa
Affiliation:
Universidade Federal de Ouro Preto (UFOP), Instituto de Ciências Exatas e Biológicas, Departamento de Química, Campus Morro do Cruzeiro, 35400-000, Ouro Preto, MG, Brazil
Shaunna M. Morrison
Affiliation:
Department of Geosciences, University of Arizona, 1040 E. 4th Street, Tucson, Arizona 85721, USA.
Marcelo B. Andrade
Affiliation:
University of São Paulo, São Carlos Institute of Physics, PO Box 369, 13560-970, São Carlos, SP, Brazil
Erico T. F. Freitas
Affiliation:
Universidade Federal de Minas Gerais (UFMG), Centro de Microscopia, Avenida Antônio Carlos, 6627, 31270-901, Belo Horizonte, MG, Brazil
Robert T. Downs
Affiliation:
Department of Geosciences, University of Arizona, 1040 E. 4th Street, Tucson, Arizona 85721, USA.
Dmitriy I. Belakovskiy
Affiliation:
Fersman Mineralogical Museum of Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow, 119071Russia
*
*E-mail: [email protected]
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Abstract

Parisite-(La) (IMA2016-031), ideally CaLa2(CO3)3F2, occurs in a hydrothermal vein crosscutting a metarhyolite of the Rio dos Remédios Group, at the Mula mine, Tapera village, Novo Horizonte county, Bahia, Brazil, associated with hematite, rutile, almeidaite, fluocerite-(Ce), brockite, monazite-(La), rhabdophane-(La) and bastnäsite-(La). Parisite-(La) occurs as residual nuclei (up to 5 mm) in steep doubly-terminated pseudo-hexagonal pyramidal crystals (up to 8.2 cm). Parisite-(La) is transparent, yellow-green to white, with a white streak and displays a vitreous (when yellow-green) to dull (when white) lustre. Cleavage is distinct on pseudo-{001}; fracture is laminated, conchoidal, or uneven. The Mohs hardness is 4 to 5, and it is brittle. Calculated density is 4.273 g cm−3. Parisite-(La) is pseudo-uniaxial (+), ω = 1.670(2) and ε = 1.782(5) (589 nm). The empirical formula normalized on the basis of 11 (O + F) atoms per formula unit (apfu) is Ca0.98(La0.83Nd0.51Ce0.37Pr0.16Sm0.04Y0.03)Σ1.94C3.03O8.91F2.09. The IR spectrum confirms the absence of OH groups. Single-crystal X-ray studies gave the following results: monoclinic (pseudo-trigonal), space group: C2, Cm, or C2/m, a = 12.356(1) Å, b = 7.1368(7) Å, c = 28.299(3) Å, β = 98.342(4)°, V = 2469.1(4) Å3 and Z = 12. Parisite-(La) is the La-dominant analogue of parisite-(Ce).

Keywords

parisite-(La)new mineralrare-earth fluorocarbonateMula mineNovo HorizonteBahiaBrazil
Type
Article
Information
Mineralogical Magazine , Volume 82 , Issue 1 , February 2018 , pp. 133 - 144
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

†

Deceased July 2014

Associate Editor: Stuart Mills

References

Adler, H.H and Kerr, P.F. (1963) lnfrared spectra, symmetry and structure relations of some carbonate minerals. American Mineralogist, 48, 839–853.Google Scholar
Betancourtt, V.M.R. (2003) Raman Spectroscopic Study of High Temperature Rare Earth Metal – Rare Earth Halide Solutions: Ln–LnX3– and LnX2–LnX3–(LiX–KX)eu Systems (Ln: Nd, Ce; X: Cl, I). Dr. Sci. thesis. Faculty of Chemistry and Biosciences, Karlsruhe University, Germany.Google Scholar
Cheang, K. (1977) Structure and Polytypism in Synchysite and Parisite from Mont St. Hilaire, Quebec. M.S. thesis, Carleton University, Ottawa, Canada.Google Scholar
Enrich, G.E.R., Gomes, C.B. and Ruberti, E. (2010) Química mineral de carbonatos de elementos terras raras em nefelina sienitos e fonólitos agpaíticos do maciço de Cerro Boggiani, Província Alto Paraguay, Paraguai. X Congresso de Geoquímica dos Países de Língua Portuguesa, 2010, Porto. Actas, 2010. v. CD-rom, pp. 223– 227.Google Scholar
Flink, G. (1901) Part I. On the minerals from Narsarsuk on the Firth of Tunugdliarfik in Southern Greenland. Parisite. Meddelelser om Grønland, 24, 29–42.Google Scholar
Frost, R.L. and Dickfos, M.J. (2007) Raman spectroscopy of halogen-containing carbonates. Journal of Raman Spectroscopy, 38, 1516–1522.Google Scholar
Frost, R.L., López, A., Scholz, R., Xi, Y. and Belotti, F.M. (2013) Infrared and Raman spectroscopic characterization of the carbonate mineral huanghoite – And in comparison with selected rare earth carbonates. Journal of Molecular Structure, 1051, 221–225.CrossRefGoogle Scholar
Guastoni, A., Kondo, D. and Nestola, F. (2010) Bastnäsite-(Ce) and parisite-(Ce) from Mt. Malosa, Malawi. Gems & Gemology, 46, 42–46.Google Scholar
Hirtopanu, P. (2006) One hundred minerals for one hundred years (dedicated to the Centennial of the Geological Institute of Romania), 3rd Conference on Mineral Sciences in the Carpathians, Miskolc Hungary. Acta Mineralogica–Petrographica, Abstract series, 5, 86.Google Scholar
Hirtopanu, P., Fairhurst, R.J. and Jakab, G. (2015) Niobian rutile and its associations at Jolotca, Ditrau Alkaline Intrusive Massif, East Carpathians, Romania. Proceedings of the Romanian Academy, Series B, 17, 39–55.Google Scholar
Jacob, D., Ji, G. and Morniroli, J.P. (2012) A systematic method to identify the space group from PED and CBED patterns part II – practical examples. Ultramicroscopy, 121, 61–71.Google Scholar
Jambor, J.L., Burke, E.A., Ercit, T.S and Grice, J.D. (1988) New mineral names. American Mineralogist, 73, 1496–1497.Google Scholar
Mandarino, J.A. (1981) The Gladstone-Dale relationship: Part IV. The compatibility concept and its application. Canadian Mineralogist, 19, 441–450.Google Scholar
Martins, A.A.M., Andrade Filho, E.L.A, Loureiro, H.S.C., Arcanjo, J.B.A. and Guimarães, R.V.B. (2008) Geologia da Chapada Diamantina Oriental (Projeto Ibitiara – Rio de Contas). Série Arquivos Abertos 31 – CPRM (Serviço Geológico do Brasil) and CBPM (Companhia Baiana de Pesquisa Mineral), Salvador, 64 pp.Google Scholar
Menezes Filho, L.A.D., Chukanov, N.V., Rastsvetaeva, R.K., Aksenov, S.M., Pekov, I.V., Chaves, M.L.S.C., Richards, R.P., Atencio, D., Brandão, P.R.G., Scholz, R., Krambrock, K., Moreira, R.L., Guimarães, F.S., Romano, A.W., Persiano, A.C., Oliveira, L.C.A. and Ardisson, J.D. (2015) Almeidaite, Pb(Mn,Y)Zn2(Ti,Fe3+)18O36(O,OH)2, a new crichtonite-group mineral, from Novo Horizonte, Bahia, Brazil. Mineralogical Magazine, 79, 269–283.Google Scholar
Moore, M., Chakhmouradian, A.R., Mariano, A.N. and Sidhu, R. (2015) Evolution of rare-earth mineralization in the Bear Lodge carbonatite, Wyoming: Mineralogical and isotopic evidence. Ore Geology Reviews, 64, 499–521.Google Scholar
Morniroli, J.P. (2013) Atlas of Electron Diffraction Zone Axis Patterns, p. 314. Available at: http://www.electron-diffraction.fr.Google Scholar
Morniroli, J.P. and Steeds, J.W. (1992) Microdiffraction as a tool for crystal structure identification and determination. Ultramicroscopy, 45, 219–239.CrossRefGoogle Scholar
Nakamoto, K. (1997) Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part A: Theory and Applications in Inorganic Chemistry. John Wiley and Sons, New York.Google Scholar
Nakamoto, K. (2009) Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part A: Theory and Applications in Inorganic Chemistry. (Sixth edition). John Wiley and Sons, New Jersey.Google Scholar
Ni, Y, Post, J.E. and Hughes, J.M. (2000) The crystal structure of parisite-(Ce), Ce2CaF2(CO3)3. American Mineralogist, 85, 251–258.Google Scholar
Pedrosa-Soares, A.C., Campos, C., Noce, C.M., Silva, L.C., Novo, T., Roncato, J., Medeiros, S., Castañeda, C., Queiroga, G., Dantas, E., Dussin, I. and Alkmim, F. (2011) Late Neoproterozoic–Cambrian granitic magmatism in the Araçuaí orogen (Brazil), the Eastern Brazilian Pegmatite Province and related deposits. Pp. 25–51 in: Granite-Related Ore Deposits (Sial, A.N., Bettencourt, J.S., De Campos, C.P., Ferreira, V.P., editors). Geological Society of London Special Publications, 350.Google Scholar
Ranieri, I.M., Baldochi, S.L. and Klimm, D. (2008) The phase diagram GdF3–LuF3. Journal of Solid State Chemistry, 181(5), 1070–1074.Google Scholar
Redjaïmia, A. and Morniroli, J.P. (1994) Application of microdiffraction to crystal structure identification. Ultramicroscopy, 53, 305–317.Google Scholar
Sulovský, P. (2001) Accessory minerals of the Třebíč durbachite massif (SW Moravia). Mineralia Slovaca, Košice: SGS, 33(5), 467–472.Google Scholar
Teixeira, L.R. (2005) Projeto Ibitiara – Rio de Contas, Estado da Bahia. Programa Recursos Minerais do Brasil, Litogeoquímica. CPRM (Serviço Geológico do Brasil) and CBPM (Companhia Baiana de Pesquisa Mineral), Salvador, 33 pp. + xv.Google Scholar
Theye, T., Ockenga, E. and Bertoldi, C. (2003) Davidite(-La), bastnaesite(-La), parisite(-La), monazite(-La): REE minerals at a metabauxite/marble interface in eastern Samos (Greece). Berichte der Deutschen Mineralogischen Gesellschaft, Beihefte zum European Journal of Mineralogy, Vol. 15 (1). ftp://ftp.gmg.rub.de/pub/geo2003/17%20Quantification%20and%20dating%20of%20metamorphic%20processes%20WILLNER/Theye.PDF.Google Scholar
White, W.B. (1974) The carbonate minerals. Pp. 227–284 in: Infrared Spectra of Minerals (Farmer, V.C., editor). Mineralogical Society Monograph, 4. London.Google Scholar