Hostname: page-component-cd9895bd7-fscjk Total loading time: 0 Render date: 2024-12-23T04:16:54.810Z Has data issue: false hasContentIssue false
  • English
  • Français

Non-isodiametric growth and confinement effect in the mineralisation of witherite

Published online by Cambridge University Press:  01 July 2020

Kangxin Li ,
Xun Liu Open the ORCID record for Xun Liu [Opens in a new window] ,
Rong Guo ,
Chao Wu ,
Bihui Peng ,
Zhaoqian Li ,
Xiaohui Duan ,
Yong Zhou  and
Chonghua Pei
Kangxin Li
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Xun Liu*
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Rong Guo
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Chao Wu
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Bihui Peng
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Zhaoqian Li
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Xiaohui Duan
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
Yong Zhou
Affiliation:
Department of Materials Science and Engineering, National Lab of Solid State Microstructure, ERERC, Nanjing University, Nanjing 210093, China.
Chonghua Pei*
Affiliation:
State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, China
*
*Author for correspondence: Xun Liu, Email: [email protected] Chonghua Pei, Email: [email protected]
*Author for correspondence: Xun Liu, Email: [email protected] Chonghua Pei, Email: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Witherite originates from the biochemical sedimentation of barium in sea water. Due to the complexity of the metallogenic environment, witherite appears in many morphologies. However, the relationship between its diverse morphologies and its mineralisation environment is not well understood. In this paper, Ca2+, a common substitute for Ba2+, and mixed protein (egg white) were used to simulate the inorganic and organic environments of witherite mineralisation, respectively. Comparison of samples prepared under different conditions showed that Ca2+ and egg white have relatively independent regulatory effects on the mineralisation of witherite particles. Egg white primarily limits the growth of the nanocrystals, while Ca2+ directs their non-isodiametric growth. Results shows that Ca2+ is distributed along a gradient in nanocrystalline witherite particles, with the Ca2+ content being proportional to the diameter of the nanocrystals. The results of this study shed light on the different roles of organic matter and inorganic ions in the formation of witherite and offer insight into the genesis of its various morphologies.

Keywords

witheritemineralisationnon-isodiametric growthconfinement effectegg whitecalcium ion
Type
Article
Information
Mineralogical Magazine , Volume 84 , Issue 4 , August 2020 , pp. 524 - 532
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2020

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Casey Bryce

References

Alavi, M.A. and Morsali, A. (2008) Syntheses of BaCO3 nanostructures by ultrasonic method. Ultrasonics Sonochemistry, 15, 833–838.CrossRefGoogle ScholarPubMed
Baldasari, A. and Speer, J.A. (1979) Witherite composition, physical properties, and genesis. American Mineralogist, 64, 742–747.Google Scholar
Chen, L., Shen, Y. and Xie, A. (2007) Nanosized barium carbonate particles stabilized by cetyltrimethylammonium bromide at the water/hexamethylene interface. Crystal Research Technology, 42, 886–889.CrossRefGoogle Scholar
Chen, G., Chang, X., Chen, J., Zhao, W. and Peng, J. (2015) Investigation of BaCO3 powders synthesized by microwave homogeneous precipitation. High Temperature Materials & Processes, 34, 757–764.CrossRefGoogle Scholar
Gao, H. (1998) The bio-chemical sedimentary metallogenic model of baritic and witherite deposits in Lower Cambrian in China. Journal of Mineralogy and Petrology, 18, 70–77.Google Scholar
Gutmann, B. and Chalup, A. (2000) Barium carbonate. American Ceramic Society Bulletin, 79, 63–65.Google Scholar
Holl, C.M., Smyth, J.R., Laustsen, H.M.S., Jacobsen, S.D. and Downs, R.T. (2000) Compression of witherite to 8 GPa and the crystal structure of BaCO3II. Physics & Chemistry of Minerals, 27, 467–473.CrossRefGoogle Scholar
Hu, W., Dong, F., Zhang, J., Liu, M., He, H., Wu, Y., Yang, D. and Deng, H. (2018) Differently ordered TiO2 nanoarrays regulated by solvent polarity, and their photocatalytic performances. Applied Surface Science, 442, 298–307.CrossRefGoogle Scholar
Lü, Z., Liu, C., Liu, J. and Wu, F. (2004) The bio-barite in witherite deposits from Southern Qinling and its significance. Progress in Natural Science, 14, 889–895CrossRefGoogle Scholar
Lv, S., Sheng, J., Zhang, S. and Sun, W. (2008) Effects of reaction time and citric acid contents on the morphologies of BaCO3 via PVP-assisted method. Materials Research Bulletin, 43, 1099–1105.CrossRefGoogle Scholar
Ma, X., Su, C., Yang, L., Li, L., Wang, K., Zhou, J., and Yuan, S. (2012) Size-and morphology-controlled biomimetic synthesis of hierarchical hollow BaCO3. Crystengcomm, 14, 8554–8561.CrossRefGoogle Scholar
Pi, D., Jiang, S., Luo, L., Yang, J. and Ling, H. (2014) Depositional environments for stratiform witherite deposits in the Lower Cambrian black shale sequence of the Yangtze Platform, southern Qinling region, SW China: Evidence from redox-sensitive trace element geochemistry. Palaeogeography, Palaeoclimatology, Palaeoecology, 398, 125–131.CrossRefGoogle Scholar
Qi, L., Ma, J., Cheng, H. and Zhao, Z. (1997) Reverse micelle based formation of BaCO3 nanowires. The Journal of Physical Chemistry B, 101, 3460–3463.CrossRefGoogle Scholar
Salvatori, F., Muhr, H., Plasari, E. and Bossoutrot, J. (2002) Determination of nucleation and crystal growth kinetics of barium carbonate. Powder Technology, 128, 114–123.CrossRefGoogle Scholar
Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751–767.CrossRefGoogle Scholar
Tang, J., Lin, W., Gao, D. and Mu, J. (1998) The genesis of the Miaozi witherite–barytocalcite–barytodolomite deposit in Wanyuan city, Sichuan Province. Mineral Deposits, 17, 264–276.Google Scholar
Tu, H.K. (1999) Metallogenic features of barite and witherite deposits in Qinlin–Dabashan region. Geology of Chemical Minerals, 21, 157–162.Google Scholar
Villiers, J.P.R.D. (1971) Crystal structures of aragonite, strontianite, and witherite. The American Mineralogist, 56, 758–767.Google Scholar
Wang, Z. and Li, G. (1991) Barite and witherite deposits in Lower Cambrian shales of South China: Stratigraphic distribution and geochemical characterization. Economic Geology, 86, 354–363.CrossRefGoogle Scholar
Wu, S., Cao, H., Yin, S., Zhang, X. and Chernow, V. (2009) Biomineralization and superhydrophobicity of BaCO3 complex nanostructures. Inorganic Chemistry, 48, 10326–10329.CrossRefGoogle ScholarPubMed
Yu, S., Cölfen, H., Xu, A. and Dong, W. (2004) Complex spherical BaCO3 superstructures self-assembled by a facile mineralization process under control of simple polyelectrolytes. Crystal Growth & Design, 4, 33–37.CrossRefGoogle Scholar
Yu, S., Cölfen, H., Tauer, K. and Antonietti, M. (2005) Tectonic arrangement of BaCO3 nanocrystals into helices induced by a racemic block copolymer. Nature Materials, 4, 51–55.CrossRefGoogle ScholarPubMed
Zeng, C., Li, P., Xu, H., Xu, Z., Li, H. and Zhang, Y. (2011) Chemical synthesis of nanosized BaCO3 with a pillar-like morphology. Ceramics International, 37, 1215–1218.CrossRefGoogle Scholar
Supplementary material: PDF

Li et al. supplementary material

Li et al. supplementary material

Download Li et al. supplementary material(PDF)
PDF 946.6 KB