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New IR and XRD data for leadhillite of ideal composition

Published online by Cambridge University Press:  05 July 2018

J. D. Russell ,
A. E. Milodowski ,
A. R. Fraser  and
D. R. Clark
J. D. Russell
Affiliation:
Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen AB9 2QJ
A. E. Milodowski
Affiliation:
Department of Geology, King’s College, Strand, London WC2R 2L
A. R. Fraser
Affiliation:
Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen AB9 2QJ
D. R. Clark
Affiliation:
Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen AB9 2QJ
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Abstract

The infra-red spectrum and X-ray powder pattern of a chemically analysed specimen of leadhillite, a lead carbonate sulphate hydroxide mineral from Leadhills, Scotland, are shown to be different from those in the literature. The IR spectra of several specimens suggest that mutual replacement of SO4, CO3, and OH may occur in this mineral, and it is thought that this might be responsible for the observed variation in X-ray spacings.

Type
Research Article
Information
Mineralogical Magazine , Volume 47 , Issue 344 , September 1983 , pp. 371 - 375
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1984

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Footnotes

*

Present address: IGS Environmental Protection Unit, Bldg 151, Harwell Laboratory, Oxfordshire OXll 0RA.

†

The principal specimen of leadhillite studied here (L1) was kindly supplied by Mr E. A. Jobbins, Mineral Curator, Geological Museum, IGS, London.

References

Angino, E. E. (1967) Am. Mineral. 52, 137–48.Google Scholar
Erd, R. C Lyon, R. J. P., and Madsen, B. M. (1965) Geol. Soc. Am. Bull. 76, 271–82.CrossRefGoogle Scholar
Hezel, A., and Ross, S. D. (1966) Spectrochim. Ada. 22, 1949–61.CrossRefGoogle Scholar
Miller, F. A., Carlson, G. L., Bentley, F. F., and Jones, W. H. (1960) Ibid. 16, 135–235.Google Scholar
Milodowski, A. E. Thermal decomposition reactions of selected carbonate minerals and their detection, identification and quantitative determination by evolved gas analysis. Unpubl. Ph.D. thesis, University of London (in prep.).Google Scholar
Moenke, H. (1962) Mineralspektren. 1, Akademie-Verlag, Berlin.Google Scholar
Mrose, M. E., and Christian, R. P. (1969) Can. Mineral. 10, 141 (Abstract only).Google Scholar
Omori, K., and Kerr, P. F. (1963) Geol. Soc. Am. Bull. 74, 709–34.CrossRefGoogle Scholar
Palache, G, Berman, H., and Frondel, C. (1951) Dana's system of mineralogy. 7th edn., 2, John Wiley & Sons, New York.Google Scholar
Ross, S. D. (1974) In The Infrared Spectra of Minerals (Farmer, V. C., ed.), Mineralogical Society, London, 427.Google Scholar
Rundle, L. M. (1974) Analyst. 99, 163–5.CrossRefGoogle Scholar
Temple, B. K. (1957) Royal Soc. Edin. Trans. 63, (part 1, 1955–6), 85–113. CrossRefGoogle Scholar
Vandeberg, J. T. (1980) An Infrared Spectroscopy Atlas for the Coatings Industry. Federation of Societies for Coatings Technology, Philadelphia, USA, 896.Google Scholar
van der Marel, H. W., and Beutelspacher, H. (1976) Atlas of Infrared Spectroscopy Of Clay Minerals and their Admixtures. Elsevier Scientific Publishing Company, New York, 332.Google Scholar
White, W. B. (1974) In The Infrared Spectra of Minerals (Farmer, V. C., ed.) Mineralogical Society, London, 227.CrossRefGoogle Scholar
Yosimura, T. (1939) J. Fac. Sc. Hokkaido Univ. 4. 453–63.Google Scholar