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Mitrofanovite, Pt3Te4, a new mineral from the East Chuarvy deposit, Fedorovo–Pana intrusion, Kola Peninsula, Russia

Published online by Cambridge University Press:  03 October 2018

Victor V. Subbotin ,
Anna Vymazalová ,
František Laufek ,
Yevgeny E. Savchenko ,
Chris J. Stanley ,
Dmitry A. Gabov  and
Jakub Plášil
Victor V. Subbotin
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 184209 Apatity, Russia
Anna Vymazalová*
Affiliation:
Czech Geological Survey, Geologická 6, 152 00 Prague 5, Czech Republic
František Laufek
Affiliation:
Czech Geological Survey, Geologická 6, 152 00 Prague 5, Czech Republic
Yevgeny E. Savchenko
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 184209 Apatity, Russia
Chris J. Stanley
Affiliation:
Department of Earth Sciences, Natural History Museum, London SW7 5BD, UK
Dmitry A. Gabov
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 184209 Apatity, Russia
Jakub Plášil
Affiliation:
Institute of Physics, AS CR v.v.i. Na Slovance 2, 182 21, Prague 8, Czech Republic
*
*Author for correspondence: Anna Vymazalova, Email: [email protected]
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Abstract

Mitrofanovite, Pt3Te4, is a new telluride discovered in low-sulfide disseminated ore in the East Chuarvy deposit, Fedorovo–Pana intrusion, Kola Peninsula, Russia. It forms anhedral grains (up to ~20 μm × 50 μm) commonly in intergrowths with moncheite in aggregates with lukkulaisvaaraite, kotulskite, vysotskite, braggite, keithconnite, rustenburgite and Pt–Fe alloys hosted by a chalcopyrite–pentlandite–pyrrhotite matrix. Associated silicates are: orthopyroxene, augite, olivine, amphiboles and plagioclase. Mitrofanovite is brittle; it has a metallic lustre and a grey streak. Mitrofanovite has a good cleavage, along {001}. In plane-polarised light, mitrofanovite is bright white with medium to strong bireflectance, slight pleochroism, and strong anisotropy on non-basal sections with greyish brown rotation tints; it exhibits no internal reflections. Reflectance values for the synthetic analogue of mitrofanovite in air (Ro, Re’ in %) are: 58.4, 54.6 at 470 nm; 62.7, 58.0 at 546 nm; 63.4, 59.1 at 589 nm; and 63.6, 59.5 at 650 nm. Fifteen electron-microprobe analyses of mitrofanovite gave an average composition: Pt 52.08, Pd 0.19, Te 47.08 and Bi 0.91, total 100.27 wt.%, corresponding to the formula (Pt2.91Pd0.02)Σ2.93(Te4.02Bi0.05)Σ4.07 based on 7 atoms; the average of eleven analyses on synthetic analogue is: Pt 52.57 and Te 47.45, total 100.02 wt.%, corresponding to Pt2.94Te4.06. The density, calculated on the basis of the formula, is 11.18 g/cm3. The mineral is trigonal, space group R$\overline 3 $m, with a = 3.9874(1), c = 35.361(1) Å, V = 486.91(2) Å3 and Z = 3. The crystal structure was solved and refined from the powder X-ray-diffraction data of synthetic Pt3Te4. Mitrofanovite is structurally and chemically related to moncheite (PtTe2). The strongest lines in the powder X-ray diffraction pattern of synthetic mitrofanovite [d in Å (I) (hkl)] are: 11.790(23)(003), 5.891(100)(006), 2.851(26)(107), 2.137(16)(1013), 2.039(18)(0114), 1.574(24)(0120), 1.3098(21)(0027). The structural identity of natural mitrofanovite with synthetic Pt3Te4 was confirmed by electron backscatter diffraction measurements on the natural sample. The mineral name is chosen to honour Felix P. Mitrofanov, a Russian geologist who was among the first to discover platinum-group element mineralisation in the Fedorova–Pana complex.

Keywords

mitrofanoviteplatinum tellurideplatinum-group mineralPt3Te4 phasereflectance dataX-ray-diffraction datacrystal structureEast Chuarvy depositFedorovo–Pana intrusionKola PeninsulaRussia
Type
Article
Information
Mineralogical Magazine , Volume 83 , Issue 4 , August 2019 , pp. 523 - 530
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Associate Editor: Brian O'Driscoll

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