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Hydroxyl-bearing bortolanite from the Lovozero alkaline massif, Kola Peninsula, Russia

Published online by Cambridge University Press:  23 May 2024

Ekaterina A. Selivanova Open the ORCID record for Ekaterina A. Selivanova [Opens in a new window] ,
Yakov A. Pakhomovsky ,
Lyudmila M. Lyalina Open the ORCID record for Lyudmila M. Lyalina [Opens in a new window] ,
Alena A. Kompanchenko Open the ORCID record for Alena A. Kompanchenko [Opens in a new window] ,
Julia A. Mikhailova Open the ORCID record for Julia A. Mikhailova [Opens in a new window]  and
Andrey A. Zolotarev
Ekaterina A. Selivanova*
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia
Yakov A. Pakhomovsky
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia
Lyudmila M. Lyalina
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia
Alena A. Kompanchenko
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia
Julia A. Mikhailova
Affiliation:
Geological Institute, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia Nanomaterials Research Centre, Kola Science Centre of the Russian Academy of Sciences, 14 Fersman Street Apatity 184209 Murmansk Region, Russia
Andrey A. Zolotarev
Affiliation:
St. Petersburg State University, Department of Crystallography, 7/9 Universitetskaya Emb. St. Petersburg 199034, Russia
*
Corresponding author: Ekaterina A. Selivanova; Email: [email protected]
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Abstract

Bortolanite, a rare mineral of the rinkite group, seidozerite supergroup occurs in two different associations in the Lovozero massif in the Kola Peninsula, Russia: (1) together with ferri-katophorite and phlogopite, it forms porous or mesh aggregates (symplectitic accretions) with euhedral contours in the contact zone of a volcano–sedimentary xenolith and eudialyte lujavrite at Kuamdespakhk Mt and (2) in intergrowths with titanite and fluorcaphite in the poikilitic feldspathoid syenites at Sengischorr Mt. In both cases, bortolanite was found in association with rosenbuschite that is close to it in chemical composition, but unlike bortolanite, it contains no REEs. The mineral is triclinic, space group P$\bar{1}$, a = 9.5807(5), b = 5.6943(4), c = 7.2813(4) Å, α = 89.891(5)°, β = 100.959(4)°, γ = 101.241(5)°, V = 382.25(4) Å3 and Z = 1.

The Lovozero bortolanite differs from the Brazilian holotype sample from de Caldas alkaline massif, Minas Gerais, due to the presence of (OH)-groups in its composition, which is indicated by Raman data. A combination of single-crystal X-ray diffraction data and electron microprobe data provides the following crystal-chemical formula: (Ca1.97Ce0.01Nd0.01Th0.01)Σ2(Ca1.39Zr0.61)Σ2(Na0.72Ca0.28)Σ1(Na1.36Ca0.56Mn0.03Zn0.01)Σ1.96(Ti0.78Zr0.08Nb0.05Mg0.05Fe0.04)Σ1Si4O14((OH)0.92O0.87F0.21)Σ2F2.

Keywords

bortolanitetitanosilicaterinkite groupalkaline rockscrystal structureLovozeroKola PeninsulaArctic
Type
Article
Information
Mineralogical Magazine , Volume 88 , Issue 4 , August 2024 , pp. 380 - 391
Copyright
Copyright © The Author(s), 2024. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland

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Footnotes

Associate Editor: Elena Zhitova

References

Agakhanov, A.A., Day, M.C., Sokolova, E., Karpenko, V.Yu., Hawthorne, F.C., Pautov, L.A., Pekov, I.V., Kasatkin, A.V., Agakhanova, V.A. (2023) Two Rinkite-Group (Seidozerite-Supergroup) Minerals: nacareniobsite-(Y), a new mineral from the Darai-Pioz Alkaline Massif, Tajikistan, and crystal-structure refinement of nacareniobsite-(Ce). The Canadian Journal of Mineralogy and Petrology, 61, 1123–1136. http://doi.org/10.3749/2300029CrossRefGoogle Scholar
Aksenov, S.M., Ryanskaya, A.D., Shchapova, Yu.V., Chukanov, N.V., Vladykin, N.V., Votyakov, S.L. and Rastsvetaeva, R.K. (2021) Crystal chemistry of lamprophyllite-group minerals from the Murun alkaline complex (Russia) and pegmatites of Rocky Boy and Gordon Butte (USA): single crystal X-ray diffraction and Raman spectroscopy study. Acta Crystallographica, B77, 287–298.Google Scholar
Andrade, M.B., Yang, H., Downs, R.T., Färber, G., Filho, R.R.C., Evans, S.H., Loehn, C.W. and Schumer, B.N. (2018) Fluorlamprophyllite, Na3(SrNa)Ti3(Si2O7)2O2F2, a new mineral from Poços de Caldas alkaline massif, Morro do Serrote, Minas Gerais, Brazil. Mineralogical Magazine, 82, 121–131.CrossRefGoogle Scholar
Bussen, I. V. and Sakharov, A. S. (1972) Petrology of the Lovozero Alkaline Massif. Nedra, Leningrad, Russia, 296 pp. [in Russian].Google Scholar
Chukanov, N. V. and Vigasina, M. F. (2020) Some aspects of the use of Raman spectroscopy in mineralogical studies. Pp. 721–739 in: Vibrational (Infrared and Raman) Spectra of Minerals and Related Compounds. Springer International Publishing.CrossRefGoogle Scholar
CRYSALISPRO (2015) Crysalispro Software System, version 1.171.39.44. Rigaku Oxford Diffraction, Oxford, UK.Google Scholar
Day, M.C., Sokolova, E., Hawthorne, F.C., Horváth, L. and Pfenninger-Horváth, E. (2022) Bortolanite, Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(FO)F2, a new rinkite-group (Seidozerite Supergroup) TS-block mineral from the Bortolan Quarry, Poços de Caldas Massif, Minas Gerais, Brazil. The Canadian Mineralogist, 60, 699–712.CrossRefGoogle Scholar
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K. and Puschmann, H. (2009) OLEX2: A complete structure solution, refinement and analysis program. Journal of Applied Crystallography, 42, 339–341.CrossRefGoogle Scholar
Emsley, J. (1980) Very strong hydrogen bonding. Chemical Society Reviews, 9, 91. http://doi.org/10.1039/cs9800900091CrossRefGoogle Scholar
Ferraris, G. (2008) Modular structures – the paradigmatic case of heterophyllosilicates. Zeitschrift für Kristallographie – Crystalline Materials, 223, 76–84.CrossRefGoogle Scholar
Ferraris, G. and Gula, A. (2005) Polysomatic Aspects of microporous minerals – heterophyllosilicates, palysepioles and rhodesite-related structures. Reviews in Mineral Geochemistry, 57, 69–104.CrossRefGoogle Scholar
Frezzotti, M.L., Tecce, F. and Casagli, A. (2012) Raman spectroscopy for fluid inclusion analysis. Journal of Geochemical Exploration, 112, 1–20.CrossRefGoogle Scholar
Gerasimovsky, V.I., Volkov, V.P., Kogarko, L.N., Polyakov, A.I., Saprykina, T.V. and Balashov, Y.A. (1966) Geochemistry of the Lovozero alkaline massif. Nauka, Moscow, 396 pp. [in Russian].Google Scholar
Ilinca, G. (2022) Charge distribution and bond valence sum analysis of sulfosalts – The ECoN21 Computer Program. Minerals, 12, 924.CrossRefGoogle Scholar
Korchak, Y.A., Men'shikov, Y.P., Pakhomovsky, Y.A., Yakovenchuk, V.N. and Ivanyuk, G.Y. (2011) Trap Formation of the Kola Peninsula. Petrology, 19, 1, 87–101 [In Russian].CrossRefGoogle Scholar
Kramm, U. and Kogarko, L.N. (1994) Nd and Sr Isotope Signatures of the Khibina and Lovozero Agpaitic Centres, Kola Alkaline Province, Russia. Lithos, 32, 225–242.CrossRefGoogle Scholar
Lafuente, B., Downs, R.T., Yang, H. and Stone, N. (2015) The power of databases: the RRUFF project. Pp. 1–30 in: Highlights in Mineralogical Crystallography (Armbruster, T and Danisi, RM, editors). De Gruyter, W., Berlin, Germany.Google Scholar
Larkin, P.J. (2011) Infrared and Raman Spectroscopy: Principles and Spectral Interpretation. Elsevier, 230 pp.Google Scholar
Libowitzky, E. (1999) Correlation of O–H stretching frequencies and O–H‧‧‧O hydrogen bond lengths in minerals. Monatshefte Für Chemie / Chemical Monthly, 130, 1047–1059. http://doi.org/10.1007/bf03354882CrossRefGoogle Scholar
Lyalina, L.M., Zolotarev, A.A. Jr., Selivanova, E.A., Savchenko, Ye.E., Krivovichev, S.V., Mikhailova, Yu.A., Kadyrova, G.I. and Zozulya, D.R. (2016) Batievaite-(Y), Y2Ca2Ti[Si2O7]2(OH)2(H2O)4, a new mineral from nepheline syenite pegmatite in the Sakharjok massif, Kola Peninsula, Russia. Mineralogy and Petrology, 110, 895–904.CrossRefGoogle Scholar
Mitchell, R.H., Wu, F.Y. and Yang, Y.H. (2011) In situ U-Pb, Sr and Nd isotopic analysis of loparite by LA-(MC)-ICP-MS. Chemical Geology, 280, 191–199.CrossRefGoogle Scholar
Momma, K. and Izumi, F. (2011) VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data. Journal of Applied Crystallography, 44, 1272–1276.CrossRefGoogle Scholar
Pautov, L.A., Agakhanov, A.A., Karpenko, V.Y., Uvarova, Y.A., Sokolova, E. and Hawthorne, F.C. (2019) Rinkite-(Y), Na2Ca4YTi(Si2O7)2OF3, a seidozerite-supergroup TS-block mineral from the Darai-Pioz alkaline massif, Tien-Shan mountains, Tajikistan: Description and crystal structure. Mineralogical Magazine, 83, 373–380.CrossRefGoogle Scholar
Pekov, I.V. (2000) Lovozero Massif: History, Pegmatites, Minerals. Ocean Pictures Ltd, Moscow, 484 pp.Google Scholar
Saprykina, L.G., Zhadritskii, V.L., Panteleimonov, V.M. and Tereshkov, V.G. (1977) Report on Prospecting for Apatite within the Lovozero Alkaline Massif in 1974–76 and on the search for apatite ores in the rocks of the eudialyte complex of the northeastern part of the Lovozero Massif in 1975–77 (Murmansk Region). Revda, Russia [in Russian].Google Scholar
Semenov, E.I. (1972) Mineralogy of the Lovozero Alkaline Massif. Nauka Publishing, Moscow, 308 pp. [in Russian].Google Scholar
Sharygin, V.V., Stoppa, F. and Kolesov, B.A. (1996) Zr-Ti disilicates from the Pian di Celle volcano, Umbria, Italy. European Journal of Mineralogy, 8, 1199–1212.CrossRefGoogle Scholar
Sheldrick, G.M. (2015) Crystal structure refinement with SHELXL. Acta Crystallographica, C71, 3–8.Google Scholar
Sokolova, E. (2006) From structure topology to chemical composition. I. Structural hierarchy and stereochemistry in titanium disilicate minerals. The Canadian Mineralogist, 44, 1273–1330.Google Scholar
Sokolova, E. and Cámara, F. (2017) The seidozerite supergroup of TS-block minerals: nomenclature and classification, with change of the following names: rinkite to rinkite-(Ce), mosandrite to mosandrite-(Ce), hainite to hainite-(Y) and innelite-1T to innelite-1A. Mineralogical Magazine, 81, 1457–1484.CrossRefGoogle Scholar
Vlasov, K.A., Kuzmenko, M.V. and Eskova, E.M. (1966) The Lovozero Alkali Massif. Hafner Publishing, New York, 627 pp.Google Scholar
Wu, F.Y., Yang, Y.H., Marks, M.A.W., Liu, Z.C., Zhou, Q., Ge, W.C., Yang, J.S., Zhao, Z.F., Mitchell, R.H. and Markl, G. (2010) In situ U-Pb, Sr, Nd and Hf isotopic analysis of eudialyte by LA-(MC)-ICP-MS. Chemical Geology, 273, 8–34.CrossRefGoogle Scholar
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