Hostname: page-component-cd9895bd7-hc48f Total loading time: 0 Render date: 2024-12-28T11:48:59.592Z Has data issue: false hasContentIssue false
  • English
  • Français

Fluoronyböite from Jianchang (Su-Lu, China) and nyböite from Nybö (Nordfjord, Norway): a petrological and crystal-chemical comparison of these two high-pressure amphiboles

Published online by Cambridge University Press:  05 July 2018

R. Oberti ,
M. Boiocchi  and
D. C. Smith
R. Oberti*
Affiliation:
CNR-Istituto di Geoscienze e Georisorse, sezione di Pavia, I-27100 Pavia, Italy
M. Boiocchi
Affiliation:
Centro Grandi Strumenti, Università degli Studi di Pavia, I-27100 Pavia, Italy
D. C. Smith
Affiliation:
Muséum National d’Histoire Naturelle, Bâtiment Minéralogie, F-75005 Paris, France
*
* E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Fluoronyböite, ideally NaNa2(Al2Mg3)(Si7Al)O22F2, has been found in the Jianchang eclogite pod, Su-Lu coesite-eclogite province, China. It has been approved as a new mineral by the IMA. Single-crystal structure refinement and electron microprobe analysis were used for characterization: C2/m, with a = 9.666(4), b = 17.799(6), c = 5.311(2) Å, β = 104.10(3)º, V = 886.2(8) Å3, Z = 2, formula: A(Na0.78K0.06)Σ0.84B(Na1.53Ca0.47)Σ2.00C(Fe2+0.89Mg2.55Mn0.01Zn0.01Fe3+0.32Al1.21Ti0.01)Σ5.00T(Si7.14Al0.86)Σ8.00O22X(OH0.84F1.16)Σ2.00.

Fluoronyböite formed during UHPM conditions, and is preserved in the retrograded kyanite-bearing eclogite sample DJ102 together with clinopyroxene (Jd70Ae20Di10), garnet (Alm60Prp21Grs17Sps02), and rutile. Lower-pressure minerals are also present (fluoro-alumino-magnesiotaramite, apatite, paragonite), and symplectitic rims were also developed around clinopyroxene crystals. Cation ordering and the structural and physical properties of fluoronyböite are reported and discussed with reference to those of F-free nyböite from the type locality at Nyböin Norway, for which some as yet unpublished mineral data are also reported. Relations between composition and petrogenetic conditions of these rare high-pressure amphiboles are discussed.

Keywords

fluoronyböite, nyböite, amphibole, structure refinement, UHPM metamorphism.
Type
Research Article
Information
Mineralogical Magazine , Volume 67 , Issue 4 , August 2003 , pp. 769 - 782
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Carman, J.H. and Gilbert, M.C. (1983 Experimental studies of glaucophane stability. American Journal of Science , 283A, 414—437.Google Scholar
Deer, W., Howie, R.A. and Zussman, J. (1992 An Introduction to the Rock-forming Minerals , 2nd edition. Longman, Harlow, Essex, UK.Google Scholar
Della Ventura, G., Robert, J.-L. Sergent, J., Hawthorne, F.C. and Delbove, F. (2001 Constraints for the FOH substitution in synthetic [6] Al-bearing monoclinic amphiboles. European Journal of Mineralogy, 13, 841—847.CrossRefGoogle Scholar
Hawthorne, F.C., Ungaretti, L. and Oberti, R. (1995 Site populations in minerals: terminology and presentation of results. The Canadian Mineralogist, 33, 907—911.Google Scholar
Hawthorne, F.C., Oberti, R. and Sardone, N. (1996 Sodium at the A site in clinoamphiboles: the effects of composition on patterns of order. The Canadian Mineralogist, 34, 577—593.Google Scholar
Hirajima, T. and Compagnoni, R. (1993 Petrology of a jadeite-quartz/ coesite-almandine-phengite fels with retrograde ferro-nyböite from the Dora-Maira Massif, Western Alps. European Journal of Mineralogy, 5, 943—955.CrossRefGoogle Scholar
Hirajima, T., Ishiwatari, A., Cong, B., Zhang, R. Banno, S., and Nozaka, T. (1990 Coesite from Mengzhong eclogite at Donghai county, northeastern Jiangsu province, China. Mineralogical Magazine, 54, 579—583.CrossRefGoogle Scholar
Hirajima, T., Zhang, R., Li, J. and Cong, B. (1992 Petrology of the nyböite-bearing eclogite in the Donghai area, Jiangsu province, eastern China. Mineralogical Magazine, 56, 37—46.CrossRefGoogle Scholar
Kechid, S.-A. (1984 Etude pétrologique et minéralogique des éclogites de Liset, Stadlandet, Norvège. Doctoral thesis, Muséum National d’Histoire Naturelle, Paris.Google Scholar
Kechid, S.-A. and Smith, D.C. (1982 Nyböitekataphorite et taramite-pargasite dans la lentille d’éclogite de Liset, Région du Gneiss de l’Ouest, Norvège. 9 ème Réunion Annuelle Sciences Terre, Paris, Societé Géologique, France, abstracts vol., p. 333.Google Scholar
Kechid, S.-A. and Smith, D.C. (1985 The petrological evolution of the Liset eclogite pod, Norway. (Second International Eclogite Conference). Terra Cognita , 5, 422.Google Scholar
Koons, P.O. (1982 An experimental investigation of the behaviour of amphibole in the system Na2O-MgOAl2O3- SiO2-H2O at high pressures. Contributions to Mineralogy and Petrology, 79, 258—267.CrossRefGoogle Scholar
Lappin, M.A. and Smith, D.C. (1978 Mantle-equilibrated orthopyroxene eclogite pods from the Basal Gneisses in the Selje District, Western Norway. Journal of Petrology, 19, 530—584.CrossRefGoogle Scholar
Lappin, M.A. and Smith, D.C. (1981 Carbonate, silicate and fluid relationships in eclogites, Selje District and environs, SW Norway. Transactions of the Royal Society of Edinburgh, 72, 171—193.CrossRefGoogle Scholar
Leake, B.E. (1978 Nomenclature of amphiboles. Mineralogical Magazine, 42, 533—563.CrossRefGoogle Scholar
Leake, B.E., Woolley, A.R., Arps, C.C.E., Birch, W.D., Gilbert, M.C., Grice, J.D., Hawthorne, F.C., Kato, A., Kisch, H.J., Krivovichev, V.G., Linthout, K., Laird, J., Mandarino, J., Maresch, W.V., Nickel, E.H., Rock, N.N.M., Schumacher, J.C., Smith, D.C., Stephenson, N.N.C., Ungaretti, L.,Whittaker, E.E.J. and Youzhi, G. (1997 Nomenc lature of Amphiboles: Report of the Subcommittee on Amphiboles of the International Mineralogical Association Commission on New Minerals and Mineral Names. Mineralogica l Magazine, 61, 295—321.CrossRefGoogle Scholar
Oberti, R., Previde-Massara, E., Ungaretti, L., Kechid, S.-A. and Smith, D.C. (1989 Nyböite-taramitesadanagaite trend in amphibole from the Liset eclogite pod, Norway: crystal-chemical and petrogenetical implications. (Third International Eclogite Conference), Terra Abstracts , 1, 17.Google Scholar
Oberti, R., Ungaretti, L., Cannillo, E. and Hawthorne, F.C. (1992 The behaviour of Ti in amphiboles. I. Four- and six-coordinated Ti in richterite. European Journal of Mineralogy, 7, 1049—1063.CrossRefGoogle Scholar
Oberti, R., Hawthorne, F.C., Ungaretti, L. and Cannillo, E. (1993 The behaviour of Mn in amphiboles: Mn in richterite. European Journal of Mineralogy, 5, 43—51.CrossRefGoogle Scholar
Oberti, R., Ungaretti, L., Cannillo, E., Hawthorne, F.C. and Memmi, I. (1995 Temperature-dependent Al order-disorder in the tetrahedral double-chain o. C2/m amphiboles. European Journal of Mineralogy, 7, 1049—1063.CrossRefGoogle Scholar
Pawley, A. (1992 Experimental study of the compositions and stabilities of synthetic nyböite-glaucophane amphiboles. European Journal of Mineralogy, 4, 171—192.CrossRefGoogle Scholar
Raudsepp, M., Turnock, A.C. and Hawthorne, F.C. (1991 Amphibole synthesis at low pressure: what grows and what doesn’t. European Journal of Mineralogy, 3, 983—1004.CrossRefGoogle Scholar
Robert, J.-L., Della Ventura, G., Welch, M. and Hawthorne, F.C. (2000 OH-F substitution in synthetic pargasite at 1.5 kbar, 850ºC. American Mineralogist, 85, 926—931.CrossRefGoogle Scholar
Rossi, G., Smith, D.C., Ungaretti, L. and Domeneghetti, C. (1983 Crystal-chemistry and cation ordering in the system diopside-jadeite: a detailed study by crystal structure refinement. Contributions to Mineralogy and Petrology, 83, 247—258.CrossRefGoogle Scholar
Rossi, G., Oberti, R. and Smith, D.C. (1986 The crystal structure of lisetite. American Mineralogist, 71, 1378—1383.Google Scholar
Smith, D.C. (1976 The geology of the Vartdal Area, Sunnmöre, Norway, and the petrochemistry of the Sunnmöre Eclogite Suite. PhD thesis, University of Aberdeen, UK, 750 pp.Google Scholar
Smith, D.C. (1977 Aluminiumholdig titanit i eklogitter fra Sunnmöre. Geolognytt, 10, 32—33.Google Scholar
Smith, D.C. (1981 The pressure and temperature dependence of Al-solubility in sphene in the system Ti-Al-Ca-Si-O-F. Progress Report Experimental Petrology , 5, NERC Publications Series D18, 193—197.Google Scholar
Smith, D.C. (1982 The essence of an eclogite: Alvi, as exemplified by the crystal-chemistry and petrology of high-pressure minerals in Norwegian eclogites. (First International Eclogite Conference), Terra Cognita , 2, 300.Google Scholar
Smith, D.C. (1984 Coesite in clinopyroxene in the Caledonides. Nature, 310, 641—644.CrossRefGoogle Scholar
Smith, D.C. (1988 A review of the peculiar mineralogy of the “Norwegian coesite-eclogite province”, with crystal-chemical, petrological, geochemical and geodynamical notes and an extensive bibliography. Pp. 1—206 in: Eclogites and Eclogite-Facies Rocks (Smith, D.C., editor). Developments in Petrology 12, Elsevier, Amsterdam.Google Scholar
Smith, D.C. (1995 Microcoesites and microdiamonds in Norway: an overview. Pp. 299—355 in: Ultra-High Pressure Metamorphism (UHPM) (Coleman, R.G. and Wang, X., editors). Cambridge University Press, Cambridge, UK 528 pp.CrossRefGoogle Scholar
Smith, D.C., Kechid, S.-A. and Rossi, R. (1986 Occurrence and properties of lisetite, CaNa2Al4Si4O16, a new tektosilicate in the system Ca-Na-Al-Si-O. American Mineral ogist, 71, 1372—1377.Google Scholar
Smith, D.C., Mottana, A. and Rossi, G. (1980 Crystalchemistry of a unique jadeite-rich acmite-poor omphacite from the Nyböeclogite pod, Sörpollen, Nordfjord, Norway. Lithos, 13, 227—236.CrossRefGoogle Scholar
Smith, D.C., Yang, J., Oberti, R. and Previde-Massara, E. (1990 A new locality of nyböite and taramite, the Jianchang eclogite pod in the “Chinese Su-Lu coesite-eclogi te province”, compared with the nyböite- and taramite-bearing Liset eclogite pod in the “Norwegian coesite-eclogite province”. 15th Meeting of the IMA, Beijing, Abstracts , vol. 2, pp. 889—890.Google Scholar
Ungaretti, L., Mazzi, F., Rossi, G. and Dal Negro, A. (1978 Crystal-chemical characterization of blue amphibo les. Proceedin gs of the XI General Meeting of the IMA, Rock-forming minerals , pp. 82—110.Google Scholar
Ungaretti, L., Rossi, G. and Smith, D.C. (1981 Crystal chemistry by X-ray structure refinement and electron microprobe analysis of a series of sodic-calcic to alkali amphiboles from the Nyböeclogite pod, Norway. Bulletin Societè Francaise de Minéralogie et Cristallographie, 104, 400—412.Google Scholar
Welch, M. and Graham, C.M. (1992 An experimental study of glaucophanic amphiboles in the system Na2O-MgO-Al2O3-SiO2-SiF4 (NMASF): some implications for glaucophane stability in natural and synthetic systems at high temperatures and pressures. Contributions to Mineralogy and Petrology, 111, 248—259.CrossRefGoogle Scholar
Winchell, H. (1963 Clinoamphibole regression studies. I. Regressions of optical properties and density on composition. Mineralogical Society of America Special Paper, 1, 267—277.Google Scholar
Yang, J. (1991 Eclogites, garnet pyroxenites and related ultrabasics in Shandong and North Jiangsu of East China [in Chinese with a brief summary in English]. Geological Society of China, Geological Publishing House, 99 pp.Google Scholar
Yang, J. and Smith, D.C. (1989 Evidence for a former sanidine-coesite eclogite at Lanshantou, Eastern China, and the recognition of the Chinese “Su-Lu coesite-ecl ogite province”. Third International Eclogite Conference, Terra Abstracts , 1, 26.Google Scholar
Zhang, R.-Y., Hirajima, T., Banno, S., Cong, B. and Liou, J.G. (1995 Petrology of ultrahigh-pressure rocks from the southern Su-Lu region, eastern China. Journal of Metamorphic Petrology, 13, 659—675.CrossRefGoogle Scholar
Supplementary material: PDF

Oberti et al. supplementary material

Structure factor data

Download Oberti et al. supplementary material(PDF)
PDF 105.1 KB