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The crystal structure of Ga-rich plumbogummite from Tsumeb, Namibia

Published online by Cambridge University Press:  05 July 2018

S. J. Mills ,
A. R. Kampf ,
M. Raudsepp  and
A. G. Christy
S. J. Mills*
Affiliation:
Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
A. R. Kampf
Affiliation:
Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, California 90007, USA
M. Raudsepp
Affiliation:
Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, British Columbia V6T 1Z4, Canada
A. G. Christy
Affiliation:
Research School of Earth Sciences, The Australian National University, Canberra ACT 0200, Australia
*
* E-mail: [email protected]
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Abstract

Ga-rich plumbogummite, (Pb0.87,Ca0.13)Σ1.00H(Al1.95,Ga1.05)Σ3.00(PO4)2(OH)6, from Tsumeb, Namibia, has rhombohedral symmetry, space group Rm, with the cell parameters a = 7.0752(19) Å, c = 16.818(4) Å and V = 729.1(3) Å3. The crystal structure has been refined to R1 = 2.05%. Ga-rich plumbogummite has an alunite-type structure comprised of a rhombohedral stacking of (001) composite layers of corner-shared (Al,Ga)O6 octahedra and PO4 tetrahedra, with Pb atoms occupying icosahedrally coordinated sites between the layers. The Pb and H positions are discussed. Ga-rich plumbogummite is nonpleochroic, uniaxial (+), with indices of refraction, ε = 1.742(3) and ω = 1.722(3), determined in white light. The five strongest powder-diffraction lines [d in Å, (I/I°), (hkl)] are: 2.995, (100), (113); 5.766, (95), (101); 2.236, (43), (107, 122); 3.539, (38), (110); 1.919 (32), (303, 033).

Keywords

plumbogummiteTsumebNamibiagalliumcrystal structurekintoreitebond valence.
Type
Research Article
Information
Mineralogical Magazine , Volume 73 , Issue 5 , October 2009 , pp. 837 - 845
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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