Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-25T06:04:40.045Z Has data issue: false hasContentIssue false

Chrysoberyl, beryl and zincian spinel mineralization in granulite-facies Archaean rocks at Dowerin, Western Australia

Published online by Cambridge University Press:  05 July 2018

P. J. Downes*
Affiliation:
Department of Earth and Planetary Sciences, Western Australian Museum, Francis Street, Perth, Western Australia 6000
A. W. R. Bevan
Affiliation:
Department of Earth and Planetary Sciences, Western Australian Museum, Francis Street, Perth, Western Australia 6000
*

Abstract

A deposit of chrysoberyl (BeAl2O4), including the variety alexandrite, occurs near Dowerin, in the southwestern region of the Archaean Yilgarn Craton, Western Australia. The deposit is situated in the northern part of the Lake Grace Terrain, a crustal component of the southwestern Yilgarn Craton, in granulite-facies gneisses (2640–2649 Ma; T = 700°C, P <6 kbar) adjacent to the margin of the Kellerberrin Batholith (2587±25 Ma). Beryllium mineralization at Dowerin occurs in plagioclase-quartz-biotite-garnet gneiss and cross-cutting tourmaline-plagioclase veins situated adjacent to lenses of actinolite-cummingtonite-phlogopite schist. Crystals of chrysoberyl (0.15–1.74 wt.% Cr2O3; 2.25–3.23 wt.% FeO; trace–0.13 wt.% ZnO; SiO2 <0.05 wt.%) are found embedded in almandine or plagioclase, and closely intergrown with biotite and/or zincian hercynite in the host-rock gneiss. Minor Cr and Fe in the alexandrite variety of chrysoberyl were possibly derived from associated zincian hercynite and/or almandine. Trace beryl (0.04–0.20 wt.% Cr2O3; 0.54–0.71 wt.% FeO; trace– 0.22 wt.% Na2O; 0.1–0.71 wt.% MgO) occurs as anhedral interstital grains between crystals of chrysoberyl, plagioclase and biotite, and as rare inclusions in chrysoberyl. Textural and mineral chemical evidence suggests that chrysoberyl and zincian spinels (chromite to hercynite containing from 2–8 wt.% ZnO) formed during granulite-facies regional metamorphism and probably pre-dated the formation of metamorphic tourmaline-plagioclase veins during the same metamorphic episode. The Be, B and Zn required to form chrysoberyl, beryl, tourmaline and zincian spinels may have been released by metamorphic reactions in host-rock metapelites during prograde granulite-facies metamorphism.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Anders, E. and Ebihara, M. (1982) Solar-system abundances of the elements. Geochimica et Cosmochimica Acta, 46, 23632380.CrossRefGoogle Scholar
Baba, S., Grew, E.S., Shearer, C.K. and Sheraton, J.W. (2000) Surinamite: A high-temperature metamorphic beryllosilicate from Lewisian sapphirine-bearing kyanite-orthopyroxene-quartz-potassium feldspar gneiss at South Harris, N.W. Scotland. American Mineralogist, 85, 14741484.CrossRefGoogle Scholar
Barnes, S.J. (2000) Chromite in Komatiites, II. Modification during greenschist to mid-amphibolite facies metamorphism. Journal of Petrology, 41, 387409.CrossRefGoogle Scholar
Barton, M.D. (1986) Phase equilibria and thermodynamic properties of minerals in the BeO-Al2O3-SiO2-H2O (BASH) system, with petrologic applications. American Mineralogist, 71, 277300.Google Scholar
Beus, A.A. (1966) Geochemistry of Beryllium and Genetic Types of Beryllium Deposits. Freeman, San Francisco.Google Scholar
Bevan, J.C. and Mallinson, L.G. (1980) Zinc- and manganese-bearing chromites and associated grossular from Zimbabwe. Mineralogical Magazine, 43, 811814.CrossRefGoogle Scholar
Bjerg, E.A., De Brodtkorb, M.K. and Stumpfl, E.F. (1993) Compositional zoning in Zn-chromites from the Cordillera Frontal Range, Argentina. Mineralogical Magazine, 57, 131139.CrossRefGoogle Scholar
Bodinier, J.-L., Dupuy, C., Dostal, J. and Merlet, C. (1987) Distribution of trace transition elements in olivine and pyroxenes from ultramafic xenoliths: application of microprobe analysis. American Mineralogist, 72, 902913.Google Scholar
Černý, P. (1991) Fertile granites of Precambrian rare-element pegmatite fields: is geochemistry controlled by tectonic setting or source lithologies? Precambrian Research, 51, 429468.CrossRefGoogle Scholar
Challis, A., Grapes, R. and Palmer, K. (1995) Chromian muscovite, uvarovite, and zincian chromite: products of regional metasomatism in northwest Nelson, New Zealand. The Canadian Mineralogist, 33, 12631284.Google Scholar
Chin, R.J. (1986) 1:250000 Geologic al Series- Explanatory notes. Kellerberrin, Western Australia (Sheet SH 50-15 international index). Geological Survey of Western Australia, Perth.Google Scholar
Davidson, L.R. (1968) Variations in ferrous ironmagnesium distribution coefficients of metamorphic pyroxenes from Quairading, Western Australia. Contributions to Mineralogy and Petrology, 19, 239259.CrossRefGoogle Scholar
Dissanayake, C.B. and Vincent, E.A. (1972) Zinc in rocks from the Skaergaard intrusion, East Greenland. Chemical Geology, 9, 285297.CrossRefGoogle Scholar
Evans, B.W. and Frost, B.R. (1975) Chrome-spinel in progressive metamorphism – a preliminary analysis. Geochimica et Cosmochimica Acta, 39, 959972.CrossRefGoogle Scholar
Ferry, J.M. and Spear, F.S. (1978) Experimental calibration of the partitioning of Fe and Mg between biotite and garnet. Contributions to Mineralogy and Petrology, 66, 113117.CrossRefGoogle Scholar
Franz, G. and Morteani, G. (1981) The system BeO-Al2O3-SiO2-H2O: hydrothermal investigation of the stability of beryl and euclase in the range from 1 to 6 kb and 400 to 800°C. Neues Jahrbuch für Mineralogie Abhandlungen, 140, 273299.Google Scholar
Franz, G. and Morteani, G. (1984) The formation of chrysoberyl in metamorphosed pegmatites. Journal of Petrology, 25, 2752.CrossRefGoogle Scholar
Fraser, G., Ellis, D. and Eggins, S. (1997) Zirconium abundance in granulite-facies minerals, with implications for zircon geochronology in high-grade rocks. Geology, 25, 607610.2.3.CO;2>CrossRefGoogle Scholar
Frost, B.R. (1973) Ferroan gahnite from quartz-biotitealmandine schist, Wind River Mountains, Wyoming. American Mineralogist, 58, 831834.Google Scholar
Frost, B.R. (1991) Stability of oxide minerals in metamorphic rocks. Pp. 469487 in: Oxide Minerals: Petrologic and Magnetic Significance (Lindsley, D.H., editor). Reviews in Mineralogy, 25. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Gee, R.D., Baxter, J.L., Wilde, S.A. and Williams, I.R. (1981) Crustal development in the Archaean Yilgarn Block, Western Australia. Geological Society of Australia Special Publication, 7, 4356.Google Scholar
Grew, E.S. (1981) Surinamite, taaffeite, and beryllian sapphirine from pegmatites in granulite-facies rocks of Casey Bay, Enderby Land, Antarctica. American Mineralogist, 66, 10221033.Google Scholar
Grew, E.S. (1988) Kornerupine at the Sar-e-Sang, Afghanistan, whiteschist locality: Implications for tourmaline-kornerupine distribution in metamorphic rocks. American Mineralogist, 73, 345357.Google Scholar
Grew, E.S. (1996) Borosilicates (exclusive of tourmaline) and boron in rock-forming minerals in metamorphic environments. Pp. 387502 in: Boron: Mineralogy, Petrology and Geochemistry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Grew, E.S. (1998) Boron and beryllium minerals in granulite-facies pegmatites and implications of beryllium pegmatites for the origin and evolution of the Archaean Napier Complex of East Antarctica. Memoirs of the National Institute of Polar Research, Special Issue, 53, 7492.Google Scholar
Grew, E.S., Yates, M.G., Barbier, J., Shearer, C.K., Sheraton, J.W., Shiraishi, K. and Motoyoshi, Y. (2000) Granulite-facies beryllium pegmatites in the Napier Complex in Khmara and Amundsen Bays, western Enderby Land, East Antarctica. Polar Geoscience, 13, 140.Google Scholar
Grundmann, G. and Morteani, G. (1989) Emerald mineralization during regional metamorphism: the Habachtal (Austria) and Leydsdorp (Transvaal, South Africa) Deposits. Economic Geology, 84, 18351849.CrossRefGoogle Scholar
Heinrich, E.Wm. and Buchi, S.H. (1969) Beryl-chrysoberyl- sillimanite paragenesis in pegmatites. Indian Mineralogist, 10, 17.Google Scholar
Henry, D.J. and Dutrow, B.L. (1996) Metamorphic tourmaline and its petrologic applications. Pp. 503557 in: Boron: Mineralogy, Petrology and Geochemistry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Henry, D.J. and Guidotti, C.V. (1985) Tourmaline as a petrogenetic indicator mineral: an example from the staurolite-grade metapelites of NW Maine. American Mineralogist, 70, 115.Google Scholar
Hudson, D.R., Wilson, A.F. and Threadgold, I.M. (1967) A new polytype of taaffeite – a rare beryllium mineral from the granulites of central Australia. Mineralogical Magazine, 36, 305310.CrossRefGoogle Scholar
Johnson, C.A. (1994) Partitioning of zinc among common ferromagnesian minerals and implications for hydrothermal mobilization. The Canadian Mineralogist, 32, 121132.Google Scholar
Leeman, W.P. and Sisson, V.B. (1996) Geochemistry of boron and its implications for crustal and mantle processes. Pp. 645708 in: Boron: Mineralogy, Petrology and Geochemistry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Lindsley, D.H. (1983) Pyroxene thermometry. American Mineralogist, 68, 477493.Google Scholar
London, D. (1999) Stability of tourmaline in peraluminous granite systems: the boron cycle from anatexis to hydrothermal aureoles. European Journal of Mineralogy, 11, 253262.CrossRefGoogle Scholar
Martin-Izard, A., Paniagua, A., Moreiras, D., Acevedo, R.D. and Marcos-Pascual, C. (1995) Metasomatism at a granitic pegmatite-dunite contact in Galicia: the Franquiera occurrence of chrysoberyl (alexandrite), emerald, and phenakite. The Canadian Mineralogist, 33, 775792.Google Scholar
Morteani, G. and Franz, G. (2002) Synthesis and stability experiments on Be-minerals and the occurrence of Be-minerals in metamorphic-(hydrothermal- metasomatic) rocks. In: Beryllium: Mineralogy, Petrology and Geochemistry (Grew, E.S., editor ). Reviews in Mineralogy and Geochemistry. Mineralogical Society of America, Washington, D.C. (in press).Google Scholar
O'Reilly, S.Y., Griffin, W.L. and Ryan, C.G. (1991) Residence of trace elements in metasomatized spinel lherzolite xenoliths: a proton-microprobe study. Contributions to Mineralogy and Petrology, 109, 98113.CrossRefGoogle Scholar
Percival, J.A. (1994) Archaean high-grade metamorphism. Pp. 357410 in: Developments in Precambrian Geology 11: Archaean Crustal Evolution (Condie, K.C., editor). Elsevier, Amsterdam.Google Scholar
Robinson, P., Spear, F.S., Schumacher, J.C., Laird, J., Klein, C., Evans, B.W. and Doolan, B.L. (1982) Phase relations of metamorphic amphiboles: natural occurrence and theory. Pp. 1227 in: Amphiboles: Petrology and Experimental Phase Relations (Veblen, D.R. and Ribbe, P.H., editors). Reviews in Mineralogy, 9B. Mineralogical Society of America, Washington, D.C.Google Scholar
Schaltegger, U., Fanning, C.M., Gunther, D., Maurin, J.C., Schulmann, K. and Gebauer, D. (1999) Growth, annealing and recrystalliz ation of zircon and preservation of monazite in high-grade metamorphism: conventional and in-situ U-Pb isotope, cathodoluminescence and microchemical evidence. Contributions to Mineralogy and Petrology, 134, 186201.CrossRefGoogle Scholar
Simpson, E.S. (1932) Contributions to the Mineralogy of Western Australia Series VII. Journal of the Royal Society of Western Australia, 18, 6165.Google Scholar
Snee, L.W. and Kazmi, A.H. (1989) Origin and Classification of Pakistani and world emerald deposits. Pp. 229236 in: Emeralds of Pakistan, Geology, Gemology and Genesis (Kazmi, A.H. and Snee, L.W., editors). Van Nostrand Reinhold Co., New York.CrossRefGoogle Scholar
Spry, P.G. and Scott, S.D. (1986) Zincian spinel and staurolite as guides to ore in the Appalachians and Scandinavian Caledonides. The Canadian Mineralogist, 24, 147163.Google Scholar
Ustinov, V.I. and Chizhik, O.Ye. (1994) Sequential nature of the formation of emerald and alexandrite in Micaite-Type deposits. Geochemistry International, 31, 115118.Google Scholar
Vavra, G., Schmid, R. and Gebauer, D. (1999) Internal morphology, habit and U-Th-Pb microanalysis of amphibolite-to-granulite facies zircons: geochronology of the Ivrea Zone (Southern Alps). Contributions to Mineralogy and Petrology, 134, 380404.CrossRefGoogle Scholar
Wagner, C. and Velde, D. (1985) Mineralogy of two peralkaline, arfvedsonite-bearing minettes. A new occurren ce of Zn-rich chromite. Bulletin de Minéralogie, 108, 173187.CrossRefGoogle Scholar
Ware, N.G., Robinson, B.W. and Walker, R.K. (1988) Programming for Microprocessor Operated Instrumentation. Proceedings of the Australian X-ray Analytical Association Conference, AXAA-88, University of Western Australia, Perth, pp. 509513.Google Scholar
Wilde, S.A. and Pidgeon, R.T. (1987) Western Australian Minerals and Petroleum Research Institution, Project 30, Final Report, 171 pp.Google Scholar
Wilde, S.A., Middleton, M.F. and Evans, B.J. (1996) Terrane accretion in the southwestern Yilgarn Craton: evidence from a deep seismic crustal profile. Precambrian Research, IGCP 280 Special Volume, 78, 179196.CrossRefGoogle Scholar
Williams, I.S. (2001) Response of detrital zircon and monazite, and their U-Pb isotopic systems, to regional metamorphism and host-rock partial melting, Cooma Complex, southeastern Australia. Australian Journal of Earth Sciences, 48, 557580.CrossRefGoogle Scholar
Wilson, A.F. and Green, D.C. (1971) The use of oxygen isotopes for geothermometry of Proterozoic and Archaean granulites. Geological Society of Australia Special Publication, 3, 389400.Google Scholar
Wylie, A.G., Candela, P.A. and Burke, T.M. (1987) Compositional zoning in unusual Zn-rich chromite from the Sykesville district of Maryland and its bearing on the origin of “ferritchromit”. American Mineralogist, 72, 413422.Google Scholar