Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-20T00:29:58.508Z Has data issue: false hasContentIssue false
  • English
  • Français

Chevkinite-group minerals from granulite-facies metamorphic rocks and associated pegmatites of East Antarctica and South India

Published online by Cambridge University Press:  05 July 2018

H. E. Belkin ,
R. Macdonald  and
E. S. Grew
H. E. Belkin*
Affiliation:
U.S. Geological Survey, 956 National Center, Reston, VA 20192, USA
R. Macdonald
Affiliation:
IGMiP Faculty of Geology, University of Warsaw, Al. Żwirki i Wigury 93, 02-089 Warsaw, Poland Environment Centre, Lancaster University, Lancaster LA1 4YQ, UK
E. S. Grew
Affiliation:
Department of Earth Sciences, University of Maine, 5790 Bryand Center, Orono, ME 04469, USA
*
* E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Electron microprobe data are presented for chevkinite-group minerals from granulite-facies rocks and associated pegmatites of the Napier Complex and Mawson Station charnockite in East Antarctica and from the Eastern Ghats, South India. Their compositions conform to the general formula for this group, viz. A4BC2D2Si4O22 where, in the analysed specimens A = (rare-earth elements (REE), Ca, Y, Th), B = Fe2+, Mg, C = (Al, Mg, Ti, Fe2+, Fe3+, Zr) and D = Ti and plot within the perrierite field of the total Fe (as FeO) (wt.%) vs. CaO (wt.%) discriminator diagram of Macdonald and Belkin (2002). In contrast to most chevkinite-group minerals, the A site shows unusual enrichment in the MREE and HREE relative to the LREE and Ca. In one sample from the Napier Complex, Y is the dominant cation among the total REE + Y in the A site, the first reported case of Y-dominance in the chevkinite group. The minerals include the most Al-rich yet reported in the chevkinite group (≤9.15 wt.% Al2O3), sufficient to fill the C site in two samples. Conversely, the amount of Ti in these samples does not fill the D site, and, thus, some of the Al could be making up the deficiency at D, a situation not previously reported in the chevkinite group. Fe abundances are low, requiring Mg to occupy up to 45% of the B site. The chevkinite-group minerals analysed originated from three distinct parageneses: (1) pegmatites containing hornblende and orthopyroxene or garnet; (2) orthopyroxene-bearing gneiss and granulite; (3) highly aluminous paragneisses in which the associated minerals are relatively magnesian or aluminous. Chevkinite-group minerals from the first two parageneses have relatively high FeO content and low MgO and Al2O3 contents; their compositions plot in the field for mafic and intermediate igneous rocks. In contrast, chevkinite-group minerals from the third paragenesis are notably more aluminous and have greater Mg/Fe ratios.

Keywords

chevkinite-groupperrieriteAntarcticaEastern GhatsIndia.
Type
Research Article
Information
Mineralogical Magazine , Volume 73 , Issue 1 , February 2009 , pp. 149 - 164
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Asami, M., Suzuki, K., Grew, E.S. and Adachi, M. (1998) CHIME ages for granulites from the Napier complex, East Antarctica. Polar Geoscience, 11, 172—199.Google Scholar
Asami, M., Suzuki, K. and Grew, E.S. (2002) Chemical Th-U-total Pb dating by electron microprobe analysis of monazite, xenotime and zircon from the Archean Napier complex, East Antarctica: evidence for ultra- high-temperature metamorphism at 2400 Ma. Precambrian Research, 114, 249—275.CrossRefGoogle Scholar
Atrashenok, L.Ya., Avdzeyko, G.V., Klimov, A.V., Krylov, A.Ya. and Silin, Yu.I. (1967) Comparative data on absolute ages of Antarctic rocks (lead and argon methods). Akademiya Nauk SSSR Komissiya po Opredeleniyu Absolyutnogo Vozrasta Geologicheskikh Formatsii Trudy, 14, 227—229 (in Russian).Google Scholar
Bonatti, S. and Gottardi, G. (1966) Un caso di polimorfismo a strati in sorosilicati: perrierite chevkinite. Periodico di Mineralogia, 35, 69—91.Google Scholar
Bose, S., Fukuoka, M., Sengupta, P. and Dasgupta, S. (2000) Evolution of high-Mg-Al granulites from Sunkarametta, Eastern Ghats, India: evidence for a lower crustal heating-cooling trajectory. Journal of Metamorphic Geology, 18, 223—240.CrossRefGoogle Scholar
Carlier, G. and Lorand, J.P. (2008) Zr-rich accessory minerals (titanite, perrierite, zirconolite, baddeleyite) record strong oxidation associated with magma mixing in the south Peruvian potassic province. Lithos, 104, 54—70.CrossRefGoogle Scholar
Crisp, R.S. (1991) Wavelengths of emission lines in the M spectrum of 49In metal in the range of 12—265 AA. Journal of Physics: Condensed Matter, 3, 927—932.Google Scholar
DePaolo, D.J., Manton, W.I., Grew, E.S. and Halpern, M. (1982) Sm-Nd, Rb-Sr and U-Th-Pb systematics of granulite facies rocks from Fyfe Hills, Enderby Land, Antarctica. Nature, 298, 614—618.CrossRefGoogle Scholar
Grew, E.S. (1982) Sapphirine, kornerupine, and sillimanite + orthopyroxene in the charnockitic region of South India. Journal of the Geological Society of India, 23, 469—505.Google Scholar
Grew, E.S. (1998) Boron and beryllium minerals in granulite-facies pegmatites and implications of beryllium pegmatites for the origin and evolution of the Archean Napier Complex of East Antarctica. Memoirs of the National Institute of Polar Research, Special Issue, 53, 74—92.Google Scholar
Grew, E.S. and Manton, W.I. (1979a) Archean rocks in Antarctica: 2.5-billion-year uranium-lead ages of pegmatites in Enderby Land. Science, 206, 443—445.Google Scholar
Grew, E.S. and Manton, W.I. (1979b) Geochronologic studies in East Antarctica: Age of a pegmatite in Mawson charnockite. Antarctic Journal of the United States, 14 (5), 2—3.Google Scholar
Grew, E.S. and Manton, W.I. (1986) A new correlation of sapphirine granulites in the Indo-Antarctic metamorphic terrain: late Proterozoic dates from the Eastern Ghats Province of India. Precambrian Research, 33, 123—137.CrossRefGoogle Scholar
Grew, E.S., Yates, M.G., Barbier, J., Shearer, C.K., Sheraton, J.W., Shiraishi, K. and Motoyoshi, Y. (2000) Granulite-facies beryllium pegmatites in the Napier Complex in Khmara and Amundsen Bays, western Enderby Land, East Antarctica. Polar Geoscience, 13, 1—40.Google Scholar
Grew, E.S., Yates, M.G., Shearer, C.K., Hagerty, J.J., Sheraton, J.W. and Sandiford, M. (2006) Beryllium and other trace elements in paragneisses and anatectic veins of the ultrahigh-temperature Napier Complex, Enderby Land, East Antarctica: the role of sapphirine. Journal of Petrology, 47, 859—882.CrossRefGoogle Scholar
Grew, E.S., Halenius, U. Pasero, M. and Barbier, J. (2008) Recommended nomenclature for the sap- phirine and surinamite groups (sapphirine super- group). Mineralogical Magazine, 72, 839—876.CrossRefGoogle Scholar
Haggerty, S.E. and Mariano, A.N. (1983) Strontian- loparite and strontio-chevkinite: Two new minerals in rheomorphic fenites from the Parana Basin carbonatites, South America. Contributions to Mineralogy and Petrology, 84, 365—381.CrossRefGoogle Scholar
Halpin, J.A., Gerakiteys, C.L., Clarke, G.L., Belousova, E.A. and Griffin, W.L. (2005) In-situ U-Pb geochronology and Hf isotope analyses of the Rayner Complex, east Antarctica. Contributions to Mineralogy and Petrology, 148, 689—706.CrossRefGoogle Scholar
Harley, S.L. (1994) Mg-Al yttrian zirconolite in a partially melted sapphirine granulite, Vestfold Hills, East Antarctica. Mineralogical Magazine, 58, 259—269.CrossRefGoogle Scholar
Harley, S. (1998) On the occurrence and characterization of ultrahigh-temperature crustal metamorphism. Pp. 81—107 in: What Drives Metamorphism and Metamorphic Reactions?(P.J. Treloar and P.J. O’Brien, editors). Special Publications, 138, The Geological Society, London.Google Scholar
Harley, S. (2008) Refining the P-T records of UHT crustal metamorphism. Journal of Metamorphic Geology, 26, 125—154.CrossRefGoogle Scholar
Harley, S.L. and Christy, A.G. (1995) Titanium-bearing sapphirine in a partially melted aluminous granulite xenolith, Vestfold Hills, Antarctica: geological and mineralogical implications. European Journal of Mineralogy, 7, 637—653.CrossRefGoogle Scholar
Hawthorne, F.C. (2002) The use of end-member charge- arrangements in defining new mineral species and heterovalent substitutions in complex minerals. The Canadian Mineralogist, 40, 699—710.CrossRefGoogle Scholar
Hokada, T. (2007) Perrierite in sapphirine—quartz gneiss: geochemical and geochronological features and implications for accessory-phase paragenesis of UHT metamorphism. Journal of Mineralogical and Petrological Sciences, 102, 44—49.CrossRefGoogle Scholar
Johnson, G.G., Jr. and White, E.W. (1970) X-ray Emission Wavelengths and keV Tables for Nondestructive Analysis. American Society for Testing and Materials Data Series DS 46, Philadelphia, Pennsylvania, USA.Google Scholar
Kamenev, Ye.N. (1972) Geological structure of Enderby Land. Pp. 579—583 in: Antarctic Geology and Geophysics(R.J. Adie, editor). Universitetsforlaget, Oslo.Google Scholar
Lima-de-Faria, J. (1962) Heat treatment of chevkinite and perrierite. Mineralogical Magazine, 33, 42—47.Google Scholar
Macdonald, R. and Belkin, H.E. (2002) Compositional variation in minerals of the chevkinite group. Mineralogical Magazine, 66, 1075—1098.CrossRefGoogle Scholar
Miyawaki, R., Matsubara, S. and Miyajima, H. (2002) The crystal structure of rengeite, Sr4ZrTi4(Si2O7)2O8. Journal of Mineralogical and Petrological Sciences, 97, 7—12.CrossRefGoogle Scholar
Parodi, G.C., Della Ventura, G., Montana, A. and Raudsepp, M. (1994) Zr-rich non metamict perrier- ite-(Ce) from holocrystalline ejecta in the Sabatini volcanic complex (Latium, Italy). Mineralogical Magazine, 58, 607—613.CrossRefGoogle Scholar
Sarkar, S., Dasgupta, S. and Fukuoka, M. (2003) Petrological evolution of a suite of spinel granulites from Vizianagram, Eastern Ghats Belt, India, and genesis of sapphirine-bearing assemblages. Journal of Metamorphic Geology, 21, 899—913.CrossRefGoogle Scholar
Segalstad, T.V. and Larsen, A.O. (1978) Chevkinite and perrierite from the Oslo region, Norway American Mineralogist, 63, 499—505.Google Scholar
Sengupta, P., Sen, J., Dasgupta, S., Raith, M.,Bhui, U.K. and Ehl, J. (1999) Ultra-high temperature metamorphism of metapelitic granulites from Kondapalle, Eastern Ghats Belt: Implications for the Indo-Antarctic correlation. Journal ofPetrology, 40, 1065—1087.Google Scholar
Shen, G., Yang, G. and Xu, J. (2005) Maoniupingite- (Ce): a new rare-earth mineral from the Maoniuping rare-earth deposit in Mianning, Sichuan. Sedimentary Geology and Tethyan Geology (Chenji yu Tetisi Dizhi), 25, 210—216 [in Chinese with English abstract].Google Scholar
Sheraton, J.W. (1982) Origin of charnockitic rocks of MacRobertson Land. Pp. 489—497 in: Antarctic Geoscience(C. Craddock, editor). University of Wisconsin Press, Madison, USA.Google Scholar
Sheraton, J.W., Tingey, R.J., Black, L.P, Offe, L.A. and Ellis, D.J. (1987) Geology of an unusual Precambrian high-grade metamorphic terrane — Enderby Land and western Kemp Land, Antarctica. Department of Resources and Energy, Bureau of Mineral Resources, Geology and Geophysics Bulletin, 223, 1—51.Google Scholar
Shimazaki, H., Yang, Z., Miyawaki, R. and Shigeoka, M. (2008) Scandium-bearing minerals in the Bayan Obo Nb-REE-Fe deposit, Inner Mongolia, China. Resource Geology, 58, 80—86.CrossRefGoogle Scholar
Sokolova, E., Hawthorne, F.C., Della Ventura, G. and Kartashov, P.M. (2004) Chevkinite-(Ce): crystal structure and the effect of moderate radiation- induced damage on site-occupancy refinement. The Canadian Mineralogist, 42, 1013—1025.CrossRefGoogle Scholar
Song, R., Ding, K. and Li, Z. (1999) Site occupancies of iron in saimaite and chevkinite. Chinese Science Bulletin, 44, 2274—2276.Google Scholar
Sun, S-S. and McDonough, W.F. (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Pp. 313—345 in: Magmatism in the Ocean Basins(A.D. Saunders and M.J. Norry, editors). Special Publications, 42, The Geological Society, London.Google Scholar
van Bergen, M.J. (1984) Perrierite in siliceous lavas from Mt Amiata, central Italy. Mineralogical Magazine, 48, 553—556.Google Scholar
Wendt, M. and Christ, B. (1985) The relative intensity of MZ-lines. Crystal Research and Technology, 20, 1443—1449.CrossRefGoogle Scholar
Xu, J., Yang, G., Li, G., Wu, Z. and Shen, G. (2008) Dingdaohengite-(Ce) from the Bayan Obo REE-Nb- Fe Mine, China: Both a true polymorph of perrierite- (Ce) and a titanic analog at the C1 site of chevkinite subgroup. American Mineralogist, 93, 740—744.CrossRefGoogle Scholar
Yakovenchuk, V.N., Ivanyuk, G.Yu., Pakhomovsky, Ya.A. and Menshikov, Yu.P. (2005) Khibiny. (F. Wall, editor). Laplandia Minerals, Apatity, in association with the Mineralogical Society of Great Ireland and Ireland, 448 pp.Google Scholar
Young, D.N. and Black, L.P. (1991) U-Pb zircon dating of Proterozoic igneous charnockites from the Mawson Coast, East Antarctica. Antarctic Science, 3, 205—216.CrossRefGoogle Scholar
Young, D.N., Zhao, J.-X., Ellis, D.J. and McCulloch, M.T. (1997) Geochemical and Sr-Nd isotopic mapping of source provinces for the Mawson charnockites, East Antarctica: implications for Proterozoic tectonics and Gondwana reconstruction. Precambrian Research, 86, 1—19.CrossRefGoogle Scholar
Supplementary material: File

Belkin et al. supplementary material

Supplementary Table of Analyses

Download Belkin et al. supplementary material(File)
File 181.8 KB