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Chemical Composition of Fluorapatite and Associated Minerals from Skarn Near Gatineau, Quebec

Published online by Cambridge University Press:  05 July 2018

D. D. Hogarth
D. D. Hogarth*
Affiliation:
Department of Geology, University of Ottawa and Ottawa-Carleton Centre for Geoscience Studies, Ottawa, Canada, K1N 6N5
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Abstract

Sixteen fluorapatite specimens from regional skarns in granulite terrain were associated with Al-zoned diopside ± scapolite ± actinolite ± calcite(+ rare phlogopite). Apatite was low in Ce (ave. 0.19% Ce2O3) and enriched in LREE relative to HREE (La/Yb = 31 to 74 in 4 specimens). Some specimens showed small negative Eu anomalies and some crystals were zoned in REE. SrO averaged 0.36%. The mineral contained some carbonate (ave. 0.5% CO2 in 5 specimens), appreciable silica (ave. 0.5%), and variable sulphate (0.1 to 1.2% SO3). Excess charge due to S6+ was largely compensated by Si4+. Chlorine was minor and F accounted for 75–98% of the F, Cl and OH ions. Apatite from marble lacking amphiboles and pyroxenes has a similar chemical composition, but apatite from later carbonatite and fenite contains more Ce and Sr. Apatite from Gatineau fenite, Gatineau carbonatite and world-wide siliceous igneous rock generally contains less S. Apatite from Gatineau skarns normally contains more Cl and less S than that from phosphorite. Magnesian marble was silicated to skarn by reaction with siliceous gneiss. Phosphorus, REE, and Sr were removed from nearby rocks and transported in aqueous, carbonated solutions containing minor amounts of F, Cl and S at granulite-facies conditions. Apatite and calcite precipitation took place in skarns and marble during the Grenville (Proterozoic) orogeny.

Keywords

skarnfluorapatitediopsiderare earth elementsstrontiumchlorinegranulite metamorphism
Type
Mineralogy and Crystal Structures
Information
Mineralogical Magazine , Volume 52 , Issue 366 , June 1988 , pp. 347 - 358
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1988

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References

Altschuler, Z.S. (1980) Soc. Econ. Paleontol. Mineral. 29, 193-0Google Scholar
Beuge, P., Rösler, H.J., Logs, G., Niese, S., and Saupe, M. (1978) Z. ang. Geol. 24, 334-9.Google Scholar
Birch, G.F. (1977) Trans. Roy. Soc. S. Afr. 42, 223-40.CrossRefGoogle Scholar
Bliskovskii, V.Z. (1979) In Veshchestvennyi Sostav Fosforitov (Yu. N. Zanin, ed.). Nauka, Sib. Div., Novosibirsk, 16-36. [in Russian].Google Scholar
Borneman-Starynkevich, I.D., and Belov, N.V. (1953) Dokl. Akad. Nauk. SSSR, 90, 89-92. [in Russian].Google Scholar
Bulakh, A.G. (1984) Mineral. Zhur. 6(4), 879-2 [in Russian].Google Scholar
Burnham, C.W., Holloway, J.R., and Davis, N.F. (1969) Spec. Pap. Geol. Soc. Am. 132.Google Scholar
Colinet, E., Griepink, B., Serrini, G., and Muntau, H. (1983) Com. European Communities, EUR 8537 EN.Google Scholar
Cruft, E.F. (1966) Geochim. Cosmochim. Acta, 30, 375-98.CrossRefGoogle Scholar
Ingamells, C.O., and Muysson, J. (1965) Ibid. 29, 581-97Google Scholar
Currie, J.B. (1951) Econ. Geol. 46, 765-78.CrossRefGoogle Scholar
Dadson, A.S. (1933) Univ. Tot. Studies, Geol. Ser. 35, 51-9.Google Scholar
Deer, W.A., Howie, R.A., and Zussman, J. (1963) Rock-forming Minerals, 4. Framework Silicates. Longmans, Green and Co., London,Google Scholar
de Keyser, F., and Cook, P.J. (1972) Austral. Bur. Min. Res. Geol. Geophys., Bull. 138.Google Scholar
de Schmid, H.S. (1912) Canada, Mines Br., Pub. 118.Google Scholar
El-Kammar, A.M., Robins, B., and Nysaether, E. (1983) Chem. Erde, 42, 131-43.Google Scholar
Ellsworth, H.V. (1932) Geol. Surv. Canada, Econ. Geol. Ser. 11.Google Scholar
Evans, B.W. (1965) Am. J. Sci. 263, 647-67CrossRefGoogle Scholar
Fershtater, G.B., Chashchukhina, V.A., and Vilisov, V.A. (1986) Geokhimiya, 771-9. [in Russian].Google Scholar
Gulbrandsen, R.A. (1966) Geochim. Cosmochim. Acta, 30, 769-78CrossRefGoogle Scholar
Gulbrandsen, R.A. Kramer, J.R., Beatty, L.B., and Mays, R.E. (1966) Am. Mineral. 51, 819-24.Google Scholar
Hoffmann, C. (1879) Geol. Surv. Canada, Rept. Progress 1877-78. Pt. H.Google Scholar
Hogarth, D.D. (1981) Qubbec, Min. Energie Ress., DPV- 816.Google Scholar
Hogarth, D.D. (1983) Can. Inst. Mining Met. Bull. 76, 103-5Google Scholar
Hogarth, D.D. and Rushforth, P. (1986) Geol. Assoc. Canada- Mineral. Assoc. CanadaCan. Geophys. Union, Joint Annual Meeting (Ottawa), Field trip 9B.Google Scholar
Hogarth, D.D. Hartree, R., Loop, J., and Solberg, T.N. (1985) Am. Mineral. 70, 1135-42.Google Scholar
Hounslow, A.W., and Chao, G.Y. (i970) Can. Mineral 10, 252-9.Google Scholar
Ingall, F.L. (1831) Trans. Lit. Hist. Soc. Quebec, 2, 7-23.Google Scholar
Jamil, A.K., A1-Dahan, A.A., and Al-Bassam, K. S. (1979) Iraqi J. Sci. 20, 519-40.Google Scholar
Jensen, M. (1984) M.Sc. thesis, Dept. Geology, South Dakota School of Mines and Technology.Google Scholar
Kerrick, D.M. (1972) Am. J. Sci. 272, 946-58CrossRefGoogle Scholar
Khrostova, V.A. (1962) Inst. Mineral. Geokhim. Kristallokhim. Redkikh Elem., Trudy 8, 147-55[in Russian].Google Scholar
Korzhinskiy, D.S. (1947) Inst. Geol. Nauk, Akad. Nauk SSSR, Trudy 29, petrograf, ser. 10 [in Russian].Google Scholar
Korzhinskiy, M.A. (1981) Geochem. Internat. 18(3), 44-60.Google Scholar
Kretz, R. (1960) Geochim. Cosmochim. Acta, 20, 161-91CrossRefGoogle Scholar
Kretz, R. (1977) Qudbec, Min. Rich. Nat., DP-514.Google Scholar
Kretz, R. (1982) Geochim. Cosmochim. Acta, 46, 411-21CrossRefGoogle Scholar
Lafontaine, M.A. G. (1980) M.Sc. thesis, Dept. Geology, Univ. Ottawa.Google Scholar
Landes, K.K. (1938) Am. Mineral. 23, 359-90.Google Scholar
Levitskii, V.I., and Petrova, Z.I. (1982) In Geokhimiya Redkozemel'nykh Elementov v Endogennykh Protsessakh (Samoylov, V. S., ed.). Nauka, Sib. Div., Novosibirsk, 129-52. [in Russian].Google Scholar
Liu, Y. (1981) Bull. Mineral. 104, 530-5Google Scholar
Lucas, J., and Prévôt, L. (1981) Bull. Soc. Gkol. France, 23, 515-24.CrossRefGoogle Scholar
McConnell, D. (1973) Apatite: Its Crystal Chemistry, Mineralogy, Utilization, and Geologic and Biologic Occurrences. Springer-Verlag, New York.CrossRefGoogle Scholar
McLellan, G.H., and Lehr, J.R. (1969) Am. Mineral. 54, 1374-9.Google Scholar
Mikhailov, D.A., and Mineev, D.A. (1970) In Regional'- nyi Metamorfizm i Metamorfogennoe Rudoobrazovanie (Velikoslavinskii, D. A., ed.). Nauka, Leningrad, 222-33. [in Russian].Google Scholar
Moine, B., Rakotondratsima, C., and Cuney, M. (1985) Bull. MinOral. 108, 325-40.CrossRefGoogle Scholar
Morton, R.D. and Catanzaro, E.J. (1964) Norsk Geol. Tidsskr. 44, 307-13Google Scholar
Moskvitina, L.V. and Smirnov, F.L. (1977) In Mineraly Endogennykh Obazovaniy Yakutii (Flerov, B. L., ed.). Akad. Nauk, Sib. Div., Yakutsk Fil., Inst. Geol., 98-106. [in Russian].Google Scholar
Muecke, G.K., Pride, C., and Sarkar, P. (1979) In Origin and Distribution of the Elements. Physics and Chemistry of the Earth, 2 (Ahrens, L. H., ed.). Pergamon Press, New York, 449-64.Google Scholar
Petrov, P.A. and Zhuravel, R.F. (1971) Trudy Sib. Nauch.-Issled. Inst. Geol. Geofiz. Miner. Syr'ya, 108, 119-27. [in Russian].Google Scholar
Rösler, H.J., Beuge, P., and Adamski, B. (1977) Z. ang. Geol. 23, 53-6.Google Scholar
Russell, R.T. and Trueman, N.A. (1971) Econ. Geol. 66, 1186-214.CrossRefGoogle Scholar
Serrini, G. and Haemers, L. (1980) Comm. European Communities, EUR 6807 EN.Google Scholar
Shaw, D.M. (1957) Proc. Geol. Assoc. Canada, 9, 69-81.Google Scholar
Shaw, D.M. (1960) J. Petrol. 1, 261-85.Google Scholar
Moxham, R.L., Filby, R.H., and Lapkowsky, W.W. (1963) Can. Mineral. 7, 578-616Google Scholar
Spence, H.S. (1920) Canada, Mines Br., Pub. 396.Google Scholar
Taborsky, F.K. (1972) Neues Jahrb. Mineral. Mh. 79-91.Google Scholar
Trzcienski, W.E., Perrault, G., and Hébert, P. (1974) Can. Mineral. 12, 289-91.Google Scholar
Villeneuve, D. (1977) B.Sc. thesis. Dept. Geology, Univ. Ottawa.Google Scholar
Walker, T.L. and Parsons, A.L. (1926) Univ. Tor. Studies, Geol. Set. 22, 205Google Scholar
Wynne-Edwards, H. R. (1967) Geol. Surv. Canada, Mem. 346.Google Scholar
Yardley, B.W. D. (1985) Mineral. Mag. 49, 779CrossRefGoogle Scholar