Hostname: page-component-cd9895bd7-gbm5v Total loading time: 0 Render date: 2024-12-23T23:03:30.228Z Has data issue: false hasContentIssue false
  • English
  • Français

Characterization of fluoro-edenite by μ-Raman and μ-FTIR spectroscopy

Published online by Cambridge University Press:  05 July 2018

C. Rinaudo ,
S. Cairo ,
D. Gastaldi ,
A. Gianfagna ,
S. Mazziotti Tagliani ,
G. Tosi  and
C. Conti
C. Rinaudo
Affiliation:
Department of Environmental and Life Science, University of Eastern Piedmont 'A. Avogadro'– V. Bellini 25/G, 15100 Alessandria, Italy
S. Cairo
Affiliation:
Department of Environmental and Life Science, University of Eastern Piedmont 'A. Avogadro'– V. Bellini 25/G, 15100 Alessandria, Italy
D. Gastaldi
Affiliation:
Department of Environmental and Life Science, University of Eastern Piedmont 'A. Avogadro'– V. Bellini 25/G, 15100 Alessandria, Italy
A. Gianfagna
Affiliation:
Department of Earth Science, University of Rome `La Sapienza', P. le Aldo Moro 5, 00185 Roma, Italy
S. Mazziotti Tagliani
Affiliation:
Department of Earth Science, University of Rome `La Sapienza', P. le Aldo Moro 5, 00185 Roma, Italy
G. Tosi
Affiliation:
Department of Earth and Material Sciences, Universitá Politecnica delle Marche, 60100 Ancona, Italy
C. Conti
Affiliation:
Department of Earth and Material Sciences, Universitá Politecnica delle Marche, 60100 Ancona, Italy
Get access Rights & Permissions [Opens in a new window]

Abstract

The prismatic variety of fluoro-edenite, a new amphibole found in lavas from Mt Etna in Biancavilla (Catania Province, Sicily, Italy), has been characterized by μ-Raman and μ-FTIR spectroscopy. The wavenumbers at which the bands are detected in the μ-Raman and μ-FTIR spectra are compared with tremolite, asbestos the chemical and crystallographic characteristics of which are very similar to those of fluoro-edenite.

Keywords

Raman spectroscopyIR spectroscopyfluoro-edenitetremolite
Type
Research Article
Information
Mineralogical Magazine , Volume 70 , Issue 3 , June 2006 , pp. 291 - 298
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bard, D., Yarwood, J. and Tylee, B. (1997) Asbestos fibre identification by Raman microspectroscopy. Journal of Raman Spectroscopy, 28, 803–809.3.0.CO;2-7>CrossRefGoogle Scholar
Blaha, J.J. and Rosasco, G.J. (1978) Raman microprobe spectra of individual microcrystals and fibers of talc, tremolite, and related silicate minerals. Analytical Chemistry, 50, 892–896.CrossRefGoogle Scholar
Burragato, F., Comba, P., Baiocchi, V., Palladino, D.M., Simei, S., Gianfagna, A., Paoletti, L. and Pasetto, R. (2005) Geo-volcanological, mineralogical and en¬vironmental aspects of quarry materials related to pleural neoplasm in the area of Biancavilla, Mount Etna (Eastern Sicily, Italy). Environmental Geology, 47, 855–868.CrossRefGoogle Scholar
Cardile, V., Renis, M., Scifo, C, Lombardo, L., Gulino, R., Mancari, B. and Panico, A.M. (2004a) Behaviour of the new asbestos amphibole fluoro-edenite in different lung cell systems. The International Journal of Biochemistry & Cell Biology, 36, 849–860.CrossRefGoogle Scholar
Cardile, V., Proietti, L., Panico, A.M. and Lombardo, L. (2004b) Nitric oxide production in fluoro-edenite treated mouse monocyte-macrophage cultures. Oncology Reports, 12, 1209–1215.Google Scholar
Comba, P., Gianfagna, A. and Paoletti, L. (2003) Pleural mesothelioma cases in Biancavilla are related to a new fluoro-edenite fibrous amphibole. Archives of Environmental Health 58, 229–232.CrossRefGoogle ScholarPubMed
Farmer, V.C. (1974) The Infrared Spectra of Minerals. Monograph 4, Mineralogical Society, London.CrossRefGoogle Scholar
Gianfagna, A. and Oberti, R. (2001) Fluoro-edenite from Biancavilla (Catania, Sicily, Italy): crystal chemistry of a new amphibole end-member. American Mineralogist, 86, 1489–1493.CrossRefGoogle Scholar
Gianfagna, A., Paoletti, L. and Ventura, P. (1997) Segnalazione di fibre di amianto anfibolico nei prodotti lavici metasomatizzati di Monte Calvario (Biancavilla, Sicilia Orientale). Plinius, Suppl. EJM, 18, 117–119.Google Scholar
Gianfagna, A., Ballirano, P., Bellatreccia, F., Bruni, B., Paoletti, L. and Oberti, R. (2003) Characterization of amphibole fibres linked to mesothelioma in the area of Biancavilla, Eastern Sicily, Italy. Mineralogical Magazine, 67, 1221–1229.CrossRefGoogle Scholar
Kloprogge, J.T., Case, M.H. and Frost, R.L. (2001) Raman microscopic study of the Li amphibole holmquistite, from the Martin Marietta Quarry, Bessemer City, NC, USA. Mineralogical Magazine, 65, 775–785.CrossRefGoogle Scholar
Lazarev, A.N. (1972) Vibrational Spectra and Structure of Silicates. Consultants Bureau, New York and London, p. 1.Google Scholar
Leake, B.E., Woolley, A.R., Arps, C.E., Birch, W.D., Gilbert, M.C., Grice, J.D., Hawthorne, F.C., Kato, A., Kisch, H.J., Krivovichev, V.G., Linthout, K., Laird, J., Mandarino, J.A., Maresch, W.V., Nickel, E.H., Rock, N.M.S., Schumacher, J.C., Smith, D.C., Stephenson, N.C.N., Ungaretti, L., Whittaker, E.J.W. and Youzhi, G. (1997) Nomenclature of amphiboles: report of the subcommittee on amphiboles of the International Mineralogical Association, Commission on New Minerals and Mineral Names. Mineralogical Magazine, 61, 295–321.CrossRefGoogle Scholar
Lewis, I.R., Chaffin, N.C., Gunter, M.E. and Griffiths, P.R. (1996) Vibrational spectroscopic studies of asbestos and comparison of suitability for remote analysis. Spectrochimica Acta A, 52, 315–328.CrossRefGoogle Scholar
Paoletti, L., Batisti, D., Bruno, C., Di Paola, M., Gianfagna, A., Mastrantonio, M., Nesti, M. and Comba, P. (2000) Unusually high incidence of malignant pleural mesothelioma in a town of eastern Sicily: an epidemiological and environmental study. Archives of Environmental Health, 55, 392–398.CrossRefGoogle Scholar
Raudsepp, M., Turnock, A.C. and Hawthorne, F.C. (1991) Amphibole synthesis at low pressure: what grows and what doesn't. European Journal of Mineralogy, 3, 983–1004.CrossRefGoogle Scholar
Rinaudo, C., Gastaldi, D. and Belluso, E. (2003) La spettroscopia Raman: tecnica di identificazione rapida di fibre di asbesto. Siti Contaminati, 2, 116–120.Google Scholar
Rinaudo, C., Belluso, E. and Gastaldi, D. (2004) Assessment of the use of Raman spectroscopy for the determination of amphibole asbestos. Mineralogical Magazine, 68, 455–465.CrossRefGoogle Scholar
Soffritti, M., Minardi, F., Bua, L., Degli Esposti, D. and Belpoggi, F. (2004) First experimental evidence of peritoneal and pleural mesotheliomas induced by fluoro-edenite fibres present in Etnean volcanic material from Biancavilla (Sicily, Italy). European Journal of Oncology, 9, 169–175.Google Scholar