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Can chromite weathering be a source of Cr in soils?

Published online by Cambridge University Press:  05 July 2018

J. Garnier
Affiliation:
UMR 8148 IDES, UPS11-CNRS, Bât. 504, 91405 Orsay Cedex, France UNB, IG/GMP-ICC Centro, Campus Universitario Darcy Ribeiro, 70919-970, Brasilia-DF, Brazil
C. Quantin
Affiliation:
UMR 8148 IDES, UPS11-CNRS, Bât. 504, 91405 Orsay Cedex, France IRD UMR LISAH, Sup Agro, Bât.12, 34060 Montpellier Cedex 2, France
E. Guimarães
Affiliation:
UNB, IG/GMP-ICC Centro, Campus Universitario Darcy Ribeiro, 70919-970, Brasilia-DF, Brazil
T. Becquer
Affiliation:
IRD, UMR 137 BioSol, Univ. Paris VI and XII, Embrapa Cerrados, CP 7091, 71619-970, Brasilia-DF, Brazil

Abstract

At Niquelândia, Cr extracted from the soil (5,000–9,300 mg.kg-1) is likely the result of the Cr-bearing Fe-oxides compared to the Cr-spinels, showing that low Cr-containing minerals present in the dunite (enstatite, olivine and clay minerals) have been completely dissolved. The chromites, accumulated inside soil profiles, have undergone chemical weathering, leading to a Cr enrichment during soil genesis. Traces of dissolution inside the soil chromites suggest that they can be slowly weathered. In this case chromites could represent a diffuse source of available Cr(III) within the soil profiles.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2008

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References

Beeson, M.H. and Jackson, E. (1969) Chemical composition of altered chromites from the Stillwater Complex, Montana. American Mineralogist, 54, 1084–1100.Google Scholar
Burkhard, DJ.M. (1993) Accessory chromium spinels: Their coexistence and alteration in serpentinites. Geochemical et Cosmochimica Ada, 57, 1297–1306.Google Scholar
Colin, F., Noack, Y., Trescases, JJ. and Nahon, D. (1985) L'alteration lateritique debutante des pyrox-enites de Jacuba, Niquelandia, Bresil. Clay Minerals, 20, 93–113.CrossRefGoogle Scholar
Gamier, J., Quantin, C. Martins, E.S., and Becquer, T. (2006) Solid speciation and availability of chromium in ultramafic soils from Niquelandia, Brazil. Journal of Geochemical Exploration, 88, 206–209.Google Scholar
Golding, H.G. and Bayliss, P. (1968) Altered chrome ores from the Coolac serpentine belt, New South Wales, Australia. American Mineralogist, 53, 162–183.Google Scholar
Horninger, G. (1941) Beobaehtungen am Erzinhalt von Gesteinen und an chromerz aus Tampadel in Schiesien. Schweizerische Mineralogische und Petrographische Mitteilungen, 52, 316–346.Google Scholar
Mihálik, P. and Saager, R. (1968) Chromite grains showing altered borders from the basal reef, Witwatersrand system. American Mineralogist, 53, 1543–1550.Google Scholar
Oze, C. Fendorf, S., Bird, D.K. and Coleman, R.G. (2004) Chromium geochemistry in serpentinized ultramafic rocks and serpentine soils from the Franciscan complex of California. American Journal of Science, 67–101.CrossRefGoogle Scholar
Robles-Camacho, J. and Armienta, M.A. (2000) Natural chromium contamination of groundwater at Leon Valley, México. Journal of Geochemical Exploration, 68, 167–181.CrossRefGoogle Scholar
Sack, R.O. and Ghiorso, M.S. (1991) Chromian spinels as petrogenetic indicators: Thermodynamics and petrological applications. American Mineralogist, 76, 827–847.Google Scholar
Shanker, A.K., Cervantes, C. Loza Tavera, H. and Avudainayagam, S. (2005) Chromium toxicity in plants. Environment International, 31, 739–753.CrossRefGoogle ScholarPubMed
Ulmer, G. (1974) Alteration of chromite during serpentinization in the Pennsylvania-Maryland District. American Mineralogist, 59, 1236–1241.Google Scholar