Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-25T18:10:34.894Z Has data issue: false hasContentIssue false
  • English
  • Français

Adsorption and diffusion of strontium in simulated rock fractures quantified via ion beam analysis

Published online by Cambridge University Press:  05 July 2018

T. Ohe ,
B. Zou ,
K. Noshita ,
I. Gomez-Morilla ,
C. Jeynes ,
P. M. Morris  and
R. A. Wogelius
T. Ohe
Affiliation:
Energy, Engineering and Science Department, Tokai University, 1117 Kita Kaname, Hiratsuka-shi, Kanagawa 259-1292, Japan
B. Zou
Affiliation:
Williamson Research Centre for Molecular Environmental Science and School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, UK
K. Noshita
Affiliation:
Energy and Environmental Systems Laboratory, Hitachi Ltd, 7-2-1 Omika, Hitachi-shi, Ibaraki 319-1221, Japan
I. Gomez-Morilla
Affiliation:
University of Surrey Ion Beam Centre, Guildford GU2 7XH, UK
C. Jeynes
Affiliation:
University of Surrey Ion Beam Centre, Guildford GU2 7XH, UK
P. M. Morris
Affiliation:
Williamson Research Centre for Molecular Environmental Science and School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, UK
R. A. Wogelius*
Affiliation:
Williamson Research Centre for Molecular Environmental Science and School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Oxford Road, Manchester M13 9PL, UK
*
*E-mail: [email protected]
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

An experimental technique has been developed and applied to the problem of determining effective diffusion coefficients and partition coefficients of Sr in low permeability geological materials. This technique, the micro-reactor simulated channel method (MRSC), allows rapid determination of contaminant transport parameters with resulting values comparable to those determined by more traditional methods and also creates product surfaces that are amenable for direct chemical analysis. An attempt to further constrain mass flux was completed by detailed ion beam analysis of polished tuff surfaces (tuff is a polycrystalline polyminerallic aggregate dominated by silicate phases) that had been reacted with Sr solutions at concentrations of 10−5, 10−3 and 10−1 mol l−1. Ion beam analysis was carried out using beams of both protons (using particle induced X-ray emission and elastic backscattering spectrometry or EBS) and alpha-particles (using Rutherford backscattering spectrometry). The ion beam analyses showed that increased solution concentrations resulted in increased surface concentrations and that in the highest concentration experiment, Sr penetrated to at least 4 μm below the primary interface. The Sr surface concentrations determined by EBS were 0.06 (±0.05), 0.87 (±0.30) and 2.40 (±1.0) atomic weight % in the experiments with starting solution concentrations of 10−5, 10−3, and 10−1 mol l−1, respectively.

Keywords

beam analysis (IBA)particle induced X-ray emission (PIXE)elastic backscattering spectrometry (EBS)rutherford backscattering spectrometry (RBS)strontium
Type
Research Article
Information
Mineralogical Magazine , Volume 76 , Issue 8 , December 2012 , pp. 3203 - 3215
Creative Commons
Creative Common License - CCCreative Common License - BY
© [2012] The Mineralogical Society of Great Britain and Ireland. This is an open access article distributed under the terms of the Creative Commons Attribution (CC BY) licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

Footnotes

†

Current address: Technische Universität Dresden, Institut für Strömungsmechanik, Lehrstuhl für Magnetofluiddynamik, 01062 Dresden, Germany

References

Akiba, K. and Hashimoto, H. (1990) Distribution coefficient of strontium on a variety of minerals and rocks. Journal of Nuclear Science and Technology, 27, 275–279.Google Scholar
Blaauw, M., Campbell, J.L., Fazinic, S., Jaksic, M., Orlic, I. and Van Espen, P. (2002) The 2000 IAEA intercomparison of PIXE spectrum. Nuclear Instruments and Methods in Physics Research, B189, 113–122.Google Scholar
Deer, W.A., Howie, R.A. and Zussman, J. (1992) An Introduction to the Rock-Forming Minerals, second edition. Pearson Education, Harlow, UK.Google Scholar
Grime, G.W. (1996) The ‘‘Q factor’’ method: quantitative microPIXE analysis using RBS normalisation. Nuclear Instruments and Methods in Physics Research, B109, 170–174.CrossRefGoogle Scholar
Grime, G.W., Watt, F., Wogelius, R.A. and Jamtveit, B. (1993) Processing micro PIXE lines can data - studies of arsenic zoning in skarn garnets. Nuclear Instruments and Methods in Physics Research, B77, 410–414.CrossRefGoogle Scholar
Gurbich, A.F. (2010) Evaluated differential crosssections for IBA. Nuclear Instruments and Methods in Physics Research, B268, 1703–1710.CrossRefGoogle Scholar
Iijima, A. (1980) Geology of natural zeolites and zeolitic rocks. Pure and Applied Chemistry, 52, 2115–2130.CrossRefGoogle Scholar
Jeynes, C., Barradas, N.P., Marriott, P.K., Boudreault, G., Jenkin, M., Wendler, E. and Webb, R.P. (2003) Elemental thin film depth profiles by ion beam analysis using simulated annealing - a new tool. Journal of Physics D: Applied Physics, 36, R97–R126.CrossRefGoogle Scholar
Jeynes, C., Bailey, M.J., Bright. N.J., Christopher, M.E., Grime, G.W., Jones, B.N., Palitsin, V.V. and Webb, R.P. (2012) Total IBA - where are we? Nuclear Instruments and Methods in Physics Research, B271, 107–118.Google Scholar
Li, Z., Alessi, D. and Allen, L. (2002) Influence of quaternary ammonium on sorption of selected metal cations onto clinoptilolite zeolite. Journal of Environmental Quality, 31, 1106–1114.CrossRefGoogle ScholarPubMed
Okuyama, K., Sasahira, A, Noshita, K. and Ohe, T.A. (2008) Method for determining both diffusion and sorption coefficients of rock medium within a few days by adopting a micro-reactor technique. Applied Geochemistry, 23, 2130–2136.CrossRefGoogle Scholar
Papelis, C. and Um, W. (2003) Evaluation of Cesium, Strontium, and Lead Sorption, Desorption, and Diffusion in Cores from Western Pahute Mesa, Nevada Test Site, Based on Macroscopic and Spectroscopic Investigation. Department of Energy Publication No. 45187, DOE/NV/13609-16. US Department of Energy, Nevada, USA.CrossRefGoogle Scholar
Patanker, S.V. (1980) Numerical Heat Transfer and Fluid Flow. Taylor & Francis, London.Google Scholar
Rancon, D. (1986) Influence of concentration distributions in solid medium on the assessment of radioelement distribution between the liquid and solid phases. Pp. 64–71.in: Application of Distribution Coefficients to Radiological Assessment Models (T.H. Sibley and C. Myttenaere, editors). Elsevier Applied Science, London.Google Scholar
Seitz, M.G., Wogelius, R.A. and Flower, M.F. (1987) Nuclear waste elements slip through hydrothermally altered basalt. Chemical Geology, 64, 109–119.Google Scholar
Simon, A., Jeynes, C., Webb, R.P., Finnis, R., Tabatabian, Z., Sellin, P.J., Breese, M.B.H., Fellows, D.H. Van den Broek, B. and Gwilliam, R.M. (2004) The new Surrey ion beam analysis facility. Nuclear Instruments and Methods in Physics Research, B219-B220, 405–409.CrossRefGoogle Scholar
Skagius, K. and Neretnieks, I. (1982) Diffusion in crystalline rock. Pp. 509–518.in: Scientific Basis for Nuclear Waste Management V (V.W. Lutze, editor). Elsevier, Amsterdam.Google Scholar
Skagius, K. and Neretnieks, I. (1988) Measurement of cesium and strontium diffusion in biotite gneiss. Water Resources Research, 24, 75–84.CrossRefGoogle Scholar
Sudicky, E.A. and Frind, E.O. (1982) Contaminant transport in fractured porous media: analytical solutions for a system of parallel fractures. Water Resources Research, 18, 1634–1642.CrossRefGoogle Scholar
Takasaka, A., Matsuda,Y. and Ito, H. (1989) Purification of Itaya zeolite on an industrial scale and its characteristics. Nihon Kagakukai-Shi, 3, 621–627. [in Japanese].Google Scholar
Tsukamoto, M. and Ohe, T. (1991) Intraparticle diffusion of cesium and strontium cations into rock materials. Chemical Geology, 90, 31–44.CrossRefGoogle Scholar
Van Brakel, J. and Heertjes, P.M. (1974) Analysis of diffusion in macroporous media in terms of porosity, a tortuosity and a constrictivity factor. International Journal of Heat and Mass Transfer, 17, 1093–1103.CrossRefGoogle Scholar
Wogelius, R.A., Fraser, D.G., Feltham, D. and Whiteman, M. (1992) Trace elements in dolomite: proton microprobe data and constraints on fluid compositions. Geochimica et Cosmochimica Acta, 56, 319–334.CrossRefGoogle Scholar
Wogelius, R.A., Fraser, D.G., Grime, G.W. and Wall, G.R.T. (1997) Trace element and isotopic zonation in vein calcite from the Mendip Hills, UK, with spatial-process correlation analysis. Geochimica et Cosmochimica Acta, 61, 2037–2051.CrossRefGoogle Scholar
Woolf, L.A. (1975) Tracer diffusion of tritiated heavy water (DTO) in heavy water (D2O) under pressure. Journal of the Chemical Society, Faraday Transactions, 1, 72, 1267–1273.Google Scholar
Yamaguchi, T., Sakamoto, Y. and Senoo, M. (1993) Consideration on effective diffusivity of strontium in granite. Journal of Nuclear Science and Technology, 30, 796–803.CrossRefGoogle Scholar