Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-17T15:20:23.938Z Has data issue: false hasContentIssue false
  • English
  • Français

Two varieties of lithiophorite in some Australian deposits

Published online by Cambridge University Press:  05 July 2018

J. Ostwald
J. Ostwald*
Affiliation:
The Broken Hill Proprietary Company Limited, Central Research Laboratories, Shortland, NSW, Australia
Get access Rights & Permissions [Opens in a new window]

Abstract

Electron probe microanalyses carried out on thirty areas of lithiophorite (Al,Li)MnO2(OH)2 from five Australian localities indicate wide variations in its Ni, Co, Cu, and Zn content. The concentration of these elements varies inversely with the alumina content, though there is a marked change in their concentration at 18% alumina, suggesting the existence of two varieties of lithiophorite with differing concentration of transition elements. EPMA line scans also indicate definite changes in Co content in lithiophorite grains less than 0.2 mm in dimension. The variations in alumina and transition elements may be explained if lithiophorite is considered to be an irregular mixed-layer-lattice intergrowth of pure lithiophorite with members of the recently discovered asbolane-type minerals.

Type
Research Article
Information
Mineralogical Magazine , Volume 48 , Issue 348 , September 1984 , pp. 383 - 388
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1984

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Blockley, J. G. (1976) In Economic Geology of Australia and Papua-New Guinea, 1 (Knight, C. L., ed.), 1019-20. Aust. IMM.Google Scholar
Burns, R. G., and Burns, V. M. (1977) In Marine Manganese Deposits (Glasby, G. P., ed.), 185–248. Elsevier, New York.CrossRefGoogle Scholar
Buseck, P. R., and Cowley, J. M. (1983) Am. Mineral. 68, 18-40.Google Scholar
Chukhrov, F. V., and Gorshkov, A. I. (1981) Chem. Erde. 40, 207-16.Google Scholar
Chukhrov, F. V., Gorshkov, A. I., Vitoskaya, I. V., Drits, V. A., and Sivtsov, A. V. (1982) In Ore Genesis—The State of the Art (Amstutz, G. C., El Gorezy, A., Frenzel, G., Kluth, C., Moh, G., Wauschkuhn, A., and Zimmermann, R. C., eds.), 230-9. Springer-Verlag, Berlin.CrossRefGoogle Scholar
Fleischer, M., and Faust, G. T. (1963) Schweiz. Mineral. Petrogr. Mitt. 43, 197-216.Google Scholar
Frenzel, A. (1871) J. Prakt. Chem. 112, 353-5.Google Scholar
Frenzel, G. (1980) In Geology and Geochemistry of Manganese, 1 (Varentsov, I. M., and Grasselly, G., eds.), 125-58. Stuttgart.Google Scholar
Ginzburg, l. l. (1960) Akad. Nauk SSSR, Inst, geol., rudn. mestorozhd., petrog., mineral, i geokhim., Kora Vyvetri- vaniya. 3, 56–66.Google Scholar
Ginzburg, l. l. and Rukavishnikova, I. A. (1951) Izd. Akad. Nauk SSSR, Inst. geol. nauk, 92–132.Google Scholar
Giovanoli, R., Buhler, H., and Sokolowska, K. (1973). J. Microsc. 18, 271-84.Google Scholar
Giovanoli, R., Burki, P., Giuffredi, M., and Strumm, W. (1975) Chimia. 29, 517-20.Google Scholar
INAL Staff (1975) In Economic Geology of Australia and Papua-New Guinea, 1 (Knight, L. C., ed.), 1001-6. Aust. IMM.Google Scholar
Larson, L. T. (1970) Econ. Geol. 65, 952-62.CrossRefGoogle Scholar
McKenzie, R. M. (1970) Austral. J. Soil Res. 8, 97–106.CrossRefGoogle Scholar
Nikitin, K. K. (1960) Akad. Nauk SSSR, Inst, geol., rudn. mestorozhd., petrog., mineral, i geokhim., Kora Vyvetri- vaniya. 3, 39–55.Google Scholar
Ostwald, J. (1975) Mineral. Deposita. 10, 1-12.CrossRefGoogle Scholar
Ostwald, J. (1977) Austral. Mineral. 7, 2-3.Google Scholar
Ostwald, J. (1980) In Geology and Geochemistry of Manganese 2 (Varentsov, I. M., and Grasselly, G., eds.), 149-81. Stuttgart.Google Scholar
Palache, C., Berman, H., and Frondel, C. (1944) Dana's System of Mineralogy 1, 566-71. John Wiley, New York.Google Scholar
Pauling, L., and Kamb, B. (1982) Am. Mineral. 67, 817-21.Google Scholar
Simpson, E. S. (1948) Minerals of Western Australia. Government Printer, Perth.Google Scholar
Ubbelohde, A. R. (1966) J. Chim. Phys. 62, 33–40.CrossRefGoogle Scholar
Valarelli, J. V. (1975) Bull. Suisse. Mineral. Petrog. 55, 19–30.Google Scholar
Villiers, J. E., and Van Der Walt, C. F. J. (1945) Am. Mineral. 30, 629-34.Google Scholar
Wagner, G. H., Konig, R. H., Vogelpohl, S., and Jones, M. D. (1979) Chem. Geol. 27, 309-27.CrossRefGoogle Scholar
Wadsley, D. A. (1952) Acta. Crystallogr. 5, 676-80.CrossRefGoogle Scholar