Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-25T18:54:35.975Z Has data issue: false hasContentIssue false
  • English
  • Français

Textural and spectroscopic studies on hydrothermal dumortierite from an Al-rich clay deposit, southeastern Korea

Published online by Cambridge University Press:  05 July 2018

C. O. Choo  and
Y. Kim
C. O. Choo*
Affiliation:
Department of Geology, Kyungpook National University, Daegu, 702-701, Korea
Y. Kim
Affiliation:
Department of Geology, Kyungpook National University, Daegu, 702-701, Korea
*
* E-mail: [email protected]
Get access Rights & Permissions [Opens in a new window]

Abstract

Dumortierite occurs as small nodules or thin layers along horizontal fractures in the altered volcanic rocks of the Milyang clay deposit, southeastern Korea. Textural evidence shows that dumortierite is associated with pyrophyllite, suggesting that the silica activity increased with decreasing B and Al activities during the hydrothermal alteration. Dumortierite chemistry shows a slight excess of Al, possibly due to common occurrence of Al-rich minerals in the clay deposit. The structural formula of dumortierite is recalculated as Al6.93(Fe0.03Mg0.07)B(Si2.99Al0.01)O18. An absorption peak at 1387 cm–1 in the IR spectrum indicates that B is present in three-fold coordinated sites. The 29Si MAS NMR spectrum has two peaks at –90.9 and –95.5 ppm, showing that Si in dumortierite is located in two different crystallographic sites and is linked to four octahedral Al atoms. The 27Al MAS NMR spectrum shows only one asymmetrical peak near 0 ppm, suggesting that there is no substitution of Al for Si. The 11B MAS NMR spectrum at 17.5 ppm shows a typical second order quadrupole pattern represented by the three-fold coordinated B. The 11B chemical shifts indicate that all of the B occupies such sites, indicating that the B sites are axially symmetric or nearly so in a very well defined site.

Keywords

dumortieriteclay depositborontrigonal groupMAS NMRKorea.
Type
Research Article
Information
Mineralogical Magazine , Volume 67 , Issue 4 , August 2003 , pp. 799 - 806
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Alexander, V.D., Griffen, D.T. and Martin, T.J. (1986 Crystal chemistr y of some Fe- and Ti-poor dumortierites. American Mineralogist, 71, 786—794.Google Scholar
Aurisicchio, C., Ottolini, L. and Pezzotta, F. (1999 Electron- and ion-microprobe analyses, and genetic inferences of tourmalines of the foite-schorl solid solition, Elba Island (Italy). European Journal of Mineralogy, 11, 217—225.CrossRefGoogle Scholar
Beukes, G.J., Slabbert, M.J., de Bruiyn, H., Botha, B.B.J., Schoch, A.E. and van der Westhuizen, W.A. (1987 Ti-dumortierite from the Keimoes area, Namaqua mobile belt, South Africa. Neues Jahrbuch für Mineralogie Abhandlungen, 157, 303—318.Google Scholar
Choo, C.O., Kim, J.J. and Kim, Y. (2001 Complex zoned tourmaline in the diaspore nodule from a hydrotherrmal kaolin deposit, Miryang deposit, south Korea. 11th Annual Goldschmidt Conference, May 2001, Virginia, USA. Abstract supplement, 147.Google Scholar
Chopin, C., Ferraris, G., Ivaldi, G., Schertl, H.-P., Schreyer, W., Compagnoni, R., Davidson, C. and Davis, A.M. (1995 Magnesiodumortierite, a new mineral from very-high-pressure rocks (western Alps). II. Crystal chemistry and petrological signi . cance. European Journal of Mineralogy, 7, 525—535.CrossRefGoogle Scholar
Foit, F.F., Jr., Fuchs, Y. and Myers, P.E. (1989 Chemistry of alkali-deficient schorls from two tourmaline-dumor tie rit e deposi ts. Americ an Mineralogist, 74, 1317—1324.Google Scholar
Henry, D.J. and Dutrow, B.L. (1996 Metamorphic tourmaline and its petrologic applications. Pp. 500—555 in: Boron Mineralogy, Petrology and Geochemistry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington, D.C.Google Scholar
Hong, S.H. and Choi, P.Y. (1988 Geological report of the Yuchon sheet (1:50,000) . Korea Institute of Energy and Resources, Seoul, Korea, 26 pp.Google Scholar
Huijsmans, J.J.P., Barton, M. and van Bergen, M.J. (1982 A pegmatite containing Fe-rich grandidierite, Ti-rich dumortierite and tourmaline from the Precambrian, high-grade metamorphic complex of Rogaland S.W. Norway. Neues Jahrbuch für Mineralogie Abhandlungen, 143, 249—261.Google Scholar
Jin, M.S., Kim, S.J. and Shin, S.C. (1991 Fission track and K-Ar ages of granites in southeastern Korea . Report KR-90-1B2, Korea Institute of Energy and Resources. Taejon, Korea, pp. 57—98.Google Scholar
Kentgens, A.A.P. (1997 A practical guide to solid-state NMR of half-integer quadrupolar nuclei with some applications to disordered systems. Geoderma, 80, 271—306.CrossRefGoogle Scholar
Kerr, P.F. and Jenney, P. (1935 The dumortieriteandalusit e mineralisation at Oreana, Nevada. Economic Geology, 30, 287—300.CrossRefGoogle Scholar
Kim, S.J., Kim, J.J. and Choo, C.O. (1992 Mineralogy and genesis of hydrothermal deposits in the southeastern part of Korean peninsula: (3) Miryang Napseok deposit. Journal of Mineralogical Society of Korea, 5, 93—101.Google Scholar
Kim, Y. and Kirkpatrick, R.J. (1998 High-temperature multi-nuclear NMR investigation of analcime. American Mineralogist, 83, 339—347.CrossRefGoogle Scholar
Kirkpatrick, R.J. (1988 MAS-NMR spectroscopy of minerals and glasses. Pp. 341—403 in: Spectroscopic Methods in Mineralo gy and Geology (Hawthorne, F.C., editor). Reviews in Mineralogy, 18, Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Koh, S.M. and Chang, H.W. (1997 Comparative anatomy of the hydrot hermal altera tion of Chonnam and Kyongsang hydrothermal clay alteration areas in Korea. Economic and Environmental Geology, 30, 81—87.Google Scholar
Koh, S.M., Tagaki, T., Kim, M.Y., Naito, K., Hong, S.S. and Sudo, S. (2000 Geological and geochemical characteristics of the hydrothermal clay alteration in south Korea. Resources Geology, 50, 229—242.CrossRefGoogle Scholar
Lee, K., Moo, H.-S., Song, Y. and Kim, I.J. (1993 Wall rock alteration and genetic environment of the Milyrang pyrophyllite deposit. Journal of Korea Institute of Mining Geology, 26, 289—309.Google Scholar
Lippmaa, E., Samson, A. and Mägi, M. (1986 Highresolution 27Al NMR of aluminosilicates. Journal of the American Chemical Society, 108, 1730—1735.CrossRefGoogle Scholar
Min, K.D., Kim, O.J., Lee, D.S. and Choo, S.H. (1982 Applicability of plate tectonics to the post Late Cretaceous igneous activities and mineralization in southern part of South Korea (I). Journal of the Korea Institute of Mining Geology, 15, 123—154.Google Scholar
Moore, P.B. and Araki, T. (1978 Dumortierite, Si3B[Al6.750.25O17.25(OH)0.75]: a detailed structure analysis. Neues Jahrb uch für Mine ralogi e Abhandlungen, 132, 231—241.Google Scholar
Oh, D.G. and Chon, H.T. (1993 Geochemical dispersion of elements in volcanic wallrocks of pyrophyllite deposits in Milyang area, Kyeongnam province. Journal of Korea Institute of Mining Geology, 26, 337—347.Google Scholar
Platonov, A.N., Langer, K., Chopin, C., Andrut, M. and Taran, M.N. (2000 Fe2+–Ti4+ charge-transfer in dumortierite. European Journal of Mineralogy, 12, 521—528.CrossRefGoogle Scholar
Putnis, A., Fyfe, C.A. and Gobbi, G.C. (1985 Al, Si ordering in cordierite using magic angle spinning NMR. I: Si-29 spectra of synthetic cordierites. Physics and Chemistry of Minerals, 12, 211—216.CrossRefGoogle Scholar
Sabzehei, M. (1971 Dumortierite from Iran: a . rst record. Mineralogical Magazine, 38, 526—527.CrossRefGoogle Scholar
Schreyer, W., Abraham, K. and Behr, H.J. (1975 Sapphirine and associated minerals from kornerupine rock of Waldheim, Saxony. Neues Jahrbuch für Mineralogie Abhandlungen, 126, 1—27.Google Scholar
Schreyer, W., Wodara, U., Marler, B., van Aken, P.A., Seifert, F. and Robert, J.-L. (2000 Synthetic tourmaline (olenite) with excess boron replacing silicon in the tetrahedral site: I. Synthesis conditions, chemical and spectroscopic evidence. European Journal of Mineralogy, 12, 529—541.CrossRefGoogle Scholar
Slack, J.F. (1996 Tourmaline associations with hydrothermal ore deposits. Pp. 559—643 in: Boron Mineralogy, Petrology and Geochemistry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Tagg, S.L., Cho, H., Dyar, M.D. and Grew, E.S. (1999 Tetrahedral boron in naturally occurring tourmaline. American Mineralogist, 84, 1451—1455.CrossRefGoogle Scholar
Takahata, H. and Uchiyama, K. (1985 Dumortieritebearing argillaceous gneisses from the Abukuma metamorphic terrain, northeast Japan. Journal of Faculty of Science, Hokkaido University, Service IV, 21, 465—481.Google Scholar
Taner, M.F. and Martin, R.F. (1993 Significance of dumortierite in an aluminosilicate-rich alteration zone, Louvicour t, Quebe c. The Canadian Mineralogist, 31, 137—146.Google Scholar
Turner, G.L., Smith, K.A., Kirkpatrick, R.J. and Oldfield, E. (1985 Boron-11 nuclear magnetic resonance spectroscop ic study of borate and borosilicate minerals and a borosilicate glass. Journal of Magnetic Resonance, 67, 544—550.Google Scholar
Visser, D. and Senior, A. (1991 Mg-rich dumortierite in cordierite-orthoamphibole-bearing rocks from the high- grade Bamble Sector, sout h Norway. Mineralogical Magazine, 55, 563—577.CrossRefGoogle Scholar
Werding, G. and Schreyer, W. (1990 Synthetic dumortierite: its PTX-dependent compositional variations in the system Al2O3-B2O3-SiO2-H2O. Contributions to Mineralogy and Petrology, 105, 11—24.CrossRefGoogle Scholar
Werding, G. and Schreyer, W. (1996 Experimental studies on borosilicates and selected borates. Pp. 117—163 in: Boron Mineralogy, Petrology and Geochemist ry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Xue, X. and Kanzaki, M. (1998 Correlations between 29Si, 17O and 1H NMR properties and local structures in silicates: an ab initio calculation. Physics and Chemistry of Minerals, 26, 14—30.CrossRefGoogle Scholar