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Sericitization of plagioclase in the Rosses Granite Complex, Co. Donegal, Ireland

Published online by Cambridge University Press:  05 July 2018

Meideno Que
Affiliation:
Department of Geology, University College, Cork, Ireland
Alistair R. Allen
Affiliation:
Department of Geology, University College, Cork, Ireland

Abstract

Sericitization in three separate pulses of the Rosses Granite Ring Complex, Co. Donegal, Ireland, has been investigated texturally and chemically using electron microscopy, electron microprobe and fluid inclusion thermometry. The sericitization, which is restricted to the cores of plagioclase, is associated with pores which are abundant in the cores, but absent in the margins. Alkali feldspar, although porous, is unaltered. Associated with the sericitization is alteration of the adjacent primary plagioclase within the cores of grains to a more sodic composition.

It is postulated that the sericitization resulted from the action of externally derived secondary hydrothermal fluids, which gained access to the pores in the plagioclase via now sealed microfractures, formed either by contraction during cooling of the Rosses Complex, or more likely by hydraulic fracturing by the fluids themselves. Limited fluid/rock ratios restricted the degree of sericitization within the host plagioclase, whilst an absence of alteration in alkali feldspar may have been due to the inaccessibility of pores in the alkali feldspar to the hydrothermal fluids at the time of alteration. Fluid inclusion data suggest that the fluids were of low salinity, and that the sericitization took place at an early stage in the cooling history of the Rosses Complex at temperatures between 400 and 600°C. It is further contended that greisenization in the Rosses Complex predated the sericitization and that the greisenization may have been due solely to volatile-rich late-stage magmatic fluids.

Type
Mineralogy
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1996

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References

Bodnar, R.J. (1993) Revised equation and table for determining the freezing point depression of H2O- NaCl solutions. Geochim. Cosmochim. Acta, 57, 683–4.CrossRefGoogle Scholar
Burnham, C.W. (1962) Facies and types of hydrothermal alteration. Econ. GeoL, 57, 768–84.CrossRefGoogle Scholar
Chou, I.M. (1987) Phase relations in the system NaCl–KC1–H20 III: Solubilities of halite in vapor-saturated liquids above 445°C and redetermination of phase equilibrum properties in the system NaCl–H2O to 1000°C and 1500 bars. Geochim Cosmochim. Acta, 51, 1965–75.CrossRefGoogle Scholar
Crawford, M.L. (1981) Phase equilibria in aqueous fluid inclusions. Mineral. Assoc. Canada Short Course Handbook, 6, 76100.Google Scholar
Creasey, S.C. (1966) Hydrothermal alterations. In Titley, S.R. and Hicks, C.L., (Eds.), Geology of the Porphyry Copper Deposits, Southwestern North America. University of Arizona Press, 5174.Google Scholar
Dengler, L. (1976) Microcracks in crystalline rocks. In Wenk, H.R. (Ed.) Electron Microscopy in Mineralogy. Springer, pp 550–6.CrossRefGoogle Scholar
Hall, A. (1966a) A petrogenetic study of the Rosses granite complex, Donegal. J. Petrol., 7, 202–20.CrossRefGoogle Scholar
Hall, A. (1966b) The feldspars of the Rosses granite complex, Donegal, Ireland. Mineral. Mag., 35, 975–82.Google Scholar
Hall, A. (1969) The micas of the Rosses granite complex, Donegal. Sci. Proc. Roy. Dublin Soc, 3A, 209-17.Google Scholar
Hall, A. (1993) The influence of secondary alteration on the ammonium content of granites, exemplified by the Rosses Complex of Donegal. Mineral Mag., 57, 591–8.CrossRefGoogle Scholar
Honma, H. and Itihara, Y. (1981) Distribution of ammonium in minerals of metamorphic and granitic rocks. Geochim. Cosmochim. Acta, 45, 983–8.CrossRefGoogle Scholar
Kwak, T.A.P. and Tan, T.H., (1981) The importance of CaCl2 in fluid composition trends - evidence from the King Island (Dolphin) skarn deposit. Econ. Geoly 76, 955-60.CrossRefGoogle Scholar
Kranz, R.L. (1984) Microcracks in rocks: a review. Tectonophysics, 100, 449–80.CrossRefGoogle Scholar
Lofgren, G. (1974) An experimental study of plagioclase crystal morphology: Isothermal crystallization. Amer. J. Sci., 274, 243–73.CrossRefGoogle Scholar
Lowell, J.D. and Guilbert, J.M. (1970) Lateral and vertical alteration - mineralization zoning in porphyry copper deposits. Econ. GeoL, 65, 373408.CrossRefGoogle Scholar
Mercy, E.L.P. (1960) The geochemistry of the Rosses granites ring complex, Co Donegal, Ireland. Trans. Roy, Soc. Edinb., 64, 128–39.Google Scholar
Meyer, C. and Hemley, J.J. (1967) Wall rock alterations. In Barnes, H.L. (Ed.), Geochemistry of Hydrothermal Ore Deposits New York, Holt Rinehart and Winston, 166255.Google Scholar
Montgomery, C.W. and Brace, W.F. (1975) Micropores in plagioclase. Contrib. Mineral. Petrol., 52, 1728.CrossRefGoogle Scholar
Morey, G.W. (1957) The solubility of solid in gases. Econ. GeoL, 52, 225–51.CrossRefGoogle Scholar
Orville, P.M. (1963) Alkali ion exchange between vapour and feldspar phases. Amer. J. Sci., 261, 201–37.CrossRefGoogle Scholar
Orville, P.M. (1972) Plagioclase cation exchange equilibria with aqueous chloride solution; results at 700°C and 2000 bars in the presence of quartz. Amer. J. ScL, 272, 234–72.CrossRefGoogle Scholar
Parsons, I. (1978) Feldspars and fluids in cooling plutons. Mineral Mag., 42, 117.CrossRefGoogle Scholar
Petrovic, R., Berner, R.A. and Goldhaber, M.B. (1975) Rate control in dissolution of alkali feldspars, 1. Study of residual feldspar grains by X-ray photoelectron spectroscopy. Geochim. Cosmochim. Acta, 40, 537–8.CrossRefGoogle Scholar
Pitcher, W.L. (1953) The Rosses Granitic Ring Complex, Co Donegal, Eire. Proc. Geol. Assoc. London, 64, 153–79.CrossRefGoogle Scholar
Pitcher, W.L. and Berger, A.R. (1972) The Geology of Donegal, A Study of Granitic Emplacement and Unroofing Wiley-lnterscience.Google Scholar
Roedder, E. and Coombs, D.S. (1967) Immiscibility in granitic melts, indicated by fluid inclusions in ejected granitic blocks from Ascension Island. J. Petrol., 8, 437–5..CrossRefGoogle Scholar
Rose, A.N. (1970) Zonal relations of wall rock alteration and sulfide distribution of porphyry copper deposits. Econ. Geol. 65, 205–20.Google Scholar
Shepherd, T. (1981) Temperature-programmable heating-freezing stage for microthermometric analysis of fluid inclusions. Econ. GeoL, 76, 1244–7.CrossRefGoogle Scholar
Shirey, S.B., Simmons, G. and Padovani, E.R. (1980) Angular oriented microtubes in metamorphic plagi-oclase. Geology, 8, 240–4.2.0.CO;2>CrossRefGoogle Scholar
Smith, J.V. and Brown, W.L. (1988) Feldspar Minerals Vol 1, Springer Verlag, 828 pp.CrossRefGoogle Scholar
Sprunt, E.S. and Brace, W.F. (1974) Direct observation of microcavities in crystalline rocks. Int. J. Rock Mech. Min. Sci., 11, 139–50.CrossRefGoogle Scholar
Tuttle, O.F. and Bowen, N.L. (1958) Origin of granite in the light of experimental studies in the system NaAlSi3Os_KAlSi3Og-SiO2-H2O. Mem. Geol. Soc. Amer., 74.Google Scholar
Wells, A.F. (1984) Structural Inorganic Chemistry. 5th edition. Clarendon Press, Oxford.Google Scholar
Worden, R.H., Walker, F.D.L., Parsons, I. and Brown, W.L. (1990) Development of microporosity, diffusion channels and deuteric coarsening in perthitic alkali feldspars. Contrib. Mineral. Petrol., 104, 507–15.CrossRefGoogle Scholar