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Recognition and significance of multiple fluid inclusion generations in telogenetic calcites

Published online by Cambridge University Press:  05 July 2018

Philippe Muchez
Affiliation:
Fysico-chemische geologie, K.U.Leuven, Celestijnenlaan 200C, B-3001 Leuven, Belgium
Marek Slobodnik
Affiliation:
Fysico-chemische geologie, K.U.Leuven, Celestijnenlaan 200C, B-3001 Leuven, Belgium Department of Geology and Paleontology, Masaryk University, Kotlarska 2, 61137 Brno, Czech Republic

Abstract

Ferroan and non-ferroan calcites occur in fractures in the Lower Carboniferous of the Variscan foreland of southern Belgium. These fractures post-date the Variscan orogeny and the calcites have a telogenetic origin. The non-ferroan calcites formed by recrystallization of the ferroan calcites. Two types of monophase aqueous fluid inclusions are present in the ferroan calcite cement. Although both types of inclusions formed at a temperature not exceeding 50°C, one type contains a moderately saline fluid (3.6–16.3 eq. wt.% NaCl) and the other type fresh water (Tm ice = 0°C). The fluid inclusions in the non-ferroan calcite also contain fresh water.

Detailed petrography of the fluid inclusions indicate that the fresh water migrated through the crystals along opened cleavage planes and microfractures. Therefore, they have a secondary origin. The recrystallization of the ferroan calcites to non-ferroan calcites occurred in this fresh water. The saline fluid inclusions are not related to the above mentioned microstructures and although their origin remains unknown, they could represent the ambient fluid from which the ferroan calcites precipitated. The study of the relationship between the occurrence of fluid inclusions and the microstructures seems promising for the identification of fluid inclusions representing post mineral formation fluid and temperature conditions in calcite cements.

Type
Mineralogy
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1996

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References

Aulstead, K.L. and Spencer, R.J. (1985) Diagenesis of the Keg River Formation, northwestern Alberta: Fluid inclusion evidence. Bull. Canad. Petrol. Geol, 33, 167–83.Google Scholar
Bodnar, R.J. (1993) Revised equation and table for determining the freezing point depression of H20 - NaCl solutions. Geochim. Cosmochim. Acta, 57, 683–4.CrossRefGoogle Scholar
Burruss, R.C. (1987) Diagcnelic palaeotemperaturcs from aqueous inclusions: re-equilibration of inclusions in carbonate cements by burial heating. Mineral. Mag., 51, 477–81.CrossRefGoogle Scholar
Choquette, P.W. and Pray, L.C. (1970) Geological nomenclature and classification of porosity in sedimentary carbonates. Bull. Anxer. Assoc. Petrol. Geol., 54, 207–50.Google Scholar
Dickson, J.A.D. (1966) Carbonate identification and genesis as revealed by staining. J. Sediment. Petrol., 36 491505.Google Scholar
Dorobek, S.L. (1987) Petrography, geochemistry and origin of burial diagenetic facies, Siluro-Devonian Helderberg Group, (carbonate rocks), central Appalachians. Bull. Amer. Assoc. Petrol. Geol., 71, 492514.Google Scholar
Emery, D. and Dickson, J.A.D. (1989) A syndepositional meteoric phreatic lens in the Middle Jurassic Lincolnshire Limestone, England, U.K. Sediment. Geology, 65, 273–84.CrossRefGoogle Scholar
Goldstein, R.H. (1986) Reequilibration of fluid inclusions in low-temperaturc calcium-carbonate cement. Geology, 14, 792—5.Google Scholar
Goldstein, R.H. and Reynolds, T.J. (1994) Systematics of fluid inclusions in diagenetic minerals. SEPM Short Course, 31, 1199.Google Scholar
Goldstein, R.H., Franseen, E.V. and Mills, M.S. (1990) Diagenesis associated with subaerial exposure of Miocene strata, southeastern Spain: Implications for sea-level change and preservation of low-temperature fluid inclusions in calcite cement. Geochim. Cosmochim. Acta, 54, 699704.CrossRefGoogle Scholar
Helsen, S. and Köningshof, P. (1994) Conodont thermal alteration patterns in Palaeozoic rocks from Belgium, northern France and western Germany. Geol. Mag., 131, 369–86.CrossRefGoogle Scholar
Leeder, O., Thomas, R. and Klemm, W. (1987) Einschlüsse in Mineralen. Liepzig, Veb Deutscher Verlag für Grundstoffindustrie, 180pp.Google Scholar
Muchez, P., Viaene, W.A., Keppens, E., Marshall, J.D. and Vandenberghe, N. (1991) Vein cements and the geochemical evolution of subsurface fluids in the Viscan of the Campine Basin (Poederlee borehole, Belgium). J. Geol. Soc. London, 148, 1005–17.CrossRefGoogle Scholar
Muchez, P., Marshall, J.D., Touret, J.L.R. and Viaene, W.A. (1994) Origin and migration of palaeofluids in the Upper Visean of the Campine Basin, northern Belgium. Sedimentology, 41, 133–45.CrossRefGoogle Scholar
Muchez, P., Slobodnik, M., Viaene, W.A. and Keppens, E. (1995) Geochemical constraints on the origin and migration of palaeofluids at the northern margin of the Variscan foreland, southern Belgium. Sediment. Geol., 95, 191200.CrossRefGoogle Scholar
Nelson, W.A. and Read, J.F. (1990) Updip to downdip cementation and dolomitization patterns in a Mississippian aquifer, Appalachians. J. Sediment. Petrol., 60, 379–96.Google Scholar
Prezbindowski, D.R. and Larese, R.E. (1987) Experimental stretching of fluid inclusions in calcite. Geology, 15, pt 4, 333–6.2.0.CO;2>CrossRefGoogle Scholar
Sabouraud, C., Macquar, J.C. and Ravier, H. (1980) Les inclusions fluidcs, témoins ct faux témoins des conditions de dépot. Quelques exemples pris dans lcs minéralisations Pb, Zn, Ba, F, du Sud du Massif Central Français. Mineral. Deposita, 15, 211–30.CrossRefGoogle Scholar
Vandycke, S., Bergerat, F. and Dupuis, Ch. (1991) Meso-Cenozoic faulting and inferred palaeostrcsscs in the Mons Basin, Belgium. Tectonophysics, 192, 261–71.CrossRefGoogle Scholar
Wojcik, K.M., Goldstein, R.H. and Walton, A.W. (1994) History of diagenetic fluids in a distant foreland area, Middle and Upper Pennsylvanian, Cherokee basin, Kansas, USA: Fluid incluions evidence. Geochim. Cosmochim. Acta, 58, 1175–91.CrossRefGoogle Scholar