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Mineralogy of the Neoproterozoic epidote-bearing TTG suite, Mons Claudianus batholith (Egypt) and implications for synorogenic magmatism

Published online by Cambridge University Press:  02 January 2018

Abstract

The Neoproterozoic, epidote-bearing Mons Claudianus Batholith (MCB), Egypt, consists of tonalite-trondhjemite-granodiorite (TTG) lithologies, containing variable contents of quartz, feldspars, amphiboles, biotite, and magmatic epidote, with accessory titanite, zircon, allanite, apatite, opaque magnetite and ilmenite. Plagioclase varies from An49 to An19, and K-feldspars possess near end-member compositions (Or97 to Or91). Amphiboles are calcic (Ca = 1.88–1.92 atoms per formula unit (apfu)), Al-rich (average AlT = 1.84 apfu), having an average Fe/(Fe + Mg) ratio of 0.50, and are edenite, ferro-edenite and ferropargasite. The Al-in-Hb barometer produced an average crystallization pressure of 5.5 kbar, consistent with the presence of magmatic epidote; the association epidote – Al-rich-Hb suggests mesozonal crustal levels, and thus a possible average rate of regional uplift for the Nubian Shield would have been in the order of 0.03 mm/yr. Calculated temperatures (using the Hb-Plag geothermometer) range from 729 to 754°C (average 747°C). The calculated P / T values of epidote-bearing MCB rocks fall within the experimentally-determined P-T range of stability of magmatic epidote with fO2 buffered from NNO to HM. Biotites in the MCB are moderately Mg-rich (Fe/(Fe + Mg) = 0.42 to 0.50), and are type 'C'-biotite, typical of calcalkaline orogenic suites, which are distinct from types 'A' and 'P' biotites occurring in anorogenic alkaline, and peraluminous lithologies, respectively. The minor secondary chlorite phases, with their Fe/(Fe + Mg) ratios of 0.37–0.52, are pycnochlorite and ripidolites, and belong to group 'c' chlorites. Minerals of the MCB reflect a petrogenetic history involving a wet, subsolvus, typically orogenic magmatic system. Results of this study could have wide implications for mineralogical characterization, level of emplacement and evolution of magmatic systems of TTG suites occurring in other orogenic belts.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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References

Abdel-Rahman, A.M. (1990) Petrogenesis of early-orogenic diorites, tonalities and post-orogenic trondh-jemites in the Nubian Shield. Journal of Petrology, 31, 12851312.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (1994) Nature of biotites from alkaline, calc-alkaline, and peraluminous magmas. Journal of Petrology, 35, 525541.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (1995a) Tectonic-magmatic stages of shield evolution: the Pan-African belt in northeastern Egypt. Tectonophysics, 242, 223—240.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (1995b) Chlorites in a spectrum of igneous rocks: mineral chemistry and paragenesis. Mineralogical Magazine, 59, 129141.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (1996) Pan African volcanism: petrology and geochemistry of the Dokhan Volcanic Suite in the northern Nubian Shield. Geological Magazine, 133, 1731.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (2006) Petrogenesis of anorogenic peralkaline granitic complexes from eastern Egypt. Mineralogical Magazine, 70, 27—50.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (2010) Nature of feldspars in felsic plutonic complexes from northeastern Egypt: Implications for the evolution of orogenic and anorogenic magmas. Neues Jahrbuch Für Geologie und Paläontologie Abhandlungen, 257, 147168.CrossRefGoogle Scholar
Abdel-Rahman, A.M. (2014) Role of Pan-African magmatism in uniting plates of Gondwana: The example of Mons Claudianus batholith, Egypt. Geological Association of Canada — Mineralogical Association of Canada Program with Abstracts, 37, 2.Google Scholar
Abdel-Rahman, A.M. and Doig, R. (1987) The Rb-Sr geochronological evolution of the Ras Gharib segment of the northern Nubian shield. Journal of the Geological Society of London, 144, 577586.CrossRefGoogle Scholar
Abdel-Rahman, A.M. and El-Kibbi, M.M. (2001) Anorogenic magmatism: chemical evolution of the Mount El-Sibai A-type complex (Egypt), and implications for the origin of within-plate felsic magmas. Geological Magazine, 138, 6785.CrossRefGoogle Scholar
Abdel-Rahman, A.M. and Martin, R.F. (1987) Late Pan-African magmatism and crustal development in northeastern Egypt. Geological Journal, 22, 281301.CrossRefGoogle Scholar
Abdel-Rahman, A.M. and Martin, R.F. (1990) The Mount Gharib A-type granite, Nubian shield: petrogenesis and role of metasomatism at the source. Contributions to Mineralogy and Petrology, 104, 173183.CrossRefGoogle Scholar
Abdel-Rahman, Y., Ploat, A., Dilek, Y., Fryer, B., El-Sharkawy, M. and Sakran, S. (2009) Geochemistry and tectonic evolution of the Neoproterozoic Wadi Ghadir ophiolite, Eastern Desert, Egypt. Lithos, 113, 158178.CrossRefGoogle Scholar
Abu El-Enen, M.M., Zalata, A.A., El-Metwally, A.A. and Okrusch, M. (1999) Orthogneisses from the Taba metamorphic belt, SE Sinai, Egypt: witnesses for granitoid magmatism at an active continental margin. Neues Jahrbuch Für Mineralogie Abhandlungen, 175, 5381.CrossRefGoogle Scholar
Albee, A.L. (1962) Relations between the mineral association, chemical composition and physical properties of the chlorite series. American Mineralogist, 47, 851870.Google Scholar
Barker, F. (1979) Trondhjemite: definition, environment and hypothesis of origin. Pp. 1—12. in: Trondhjemites, Dacites and Related Rock.(F. Barker, editor). Elsevier, Amsterdam.CrossRefGoogle Scholar
Barker, F. and Arth, J.G. (1976) Generation of trondhjemitic-tonalitic liquids and Archean bimodal trondhjemite basalt suites. Geology, 4, 596600.2.0.CO;2>CrossRefGoogle Scholar
Barr, S.M., White, C.E. and Culshaw, N.G. (2001) Geology and tectonic setting of Paleoproterozoic granitoid suite in the Island Harbour Bay area, Makkovick Province, Labrador. Canadian Journal of Earth Sciences, 38, 441463.CrossRefGoogle Scholar
Bédard, J.H. (2003) Evidence for regional-scale, pluton-driven, high-grade metamorphism in the Archean Minto Block, northern Superior Province, Canada. Journal of Geology, 111, 183205.CrossRefGoogle Scholar
Bettison, L.A. and Schiffman, P. (1988) Compositional and structural variations of phy llo silicates from the point Sal ophiolite, California. American Mineralogist, 73, 62—76.Google Scholar
Blundy, J.D. and Holland, T.J.B. (1990) Calcic amphibole equilibria and a new amphibole-plagioclase geotherm-ometer. Contributions to Mineralogy and Petrology, 104, 208224.CrossRefGoogle Scholar
Brown, G.C. (1980) Calc-alkaline magma genesis: the Pan-African contribution to crustal growth? Institute of Applied Geology Bulletin, Jeddah, 3, 1929.CrossRefGoogle Scholar
Cahen, L., Snelling, N.J., Delhal, I and Vail, J.R. (1984) The Geochronology and Evolution of Africa.Clarendon, Oxford, UK, 371 pp.Google Scholar
Condie, K.C. (2005) TTGs and adakites: are they both slab melts? Lithos, 80, 33-4.CrossRefGoogle Scholar
Cornelius, H.P. (1915) Geologische Beobachtungen in Gebiet des Forno- Gletschers (Engadin). Centralblatt Für Mineralogie, Geologie und Paläontologie 1913, 8, 246252.Google Scholar
Czamanske, G.K. and Wones, D.R. (1973) Oxidation during magmatic differentiation, Fennmarks, Oslo area, Norway: Part II, the mafic silicates. Journal of Petrology, 14, 349374.CrossRefGoogle Scholar
Czamanske, G.K., Ishihara, S. and Atkin, S.A. (1981) Chemistry of rock-forming minerals of the Cretaceous-Paleocene batholith in southwestern Japan and implications for magma genesis. Journal of Geophysical Research, 86, 1043110469.CrossRefGoogle Scholar
Dahlquist, I A. (2001) REE fractionation by accessory minerals in epidote-bearing metaluminous granitoids from the Sierras Pampeanas, Argentina. Mineralogical Magazine, 65, 463475.CrossRefGoogle Scholar
Davidson, J., Turner, S., Handley, H., Macpherson, C. and Dosseto, A. (2007) Amphibole “sponge” in arc crust? Geology, 35, 787790.CrossRefGoogle Scholar
Deer, W.A., Howie, R.A. and Zussman, I (1971) Rock-forming Minerals, vol. 3, Sheet Silicates.Longman, London, pp. 270.Google Scholar
Drummond, M.S., Defant, M.J. (1990) A model for trondhjemite—tonalite—dacite genesis and crustal growth via slab melting: Archean to modern comparisons. Journal of Geophysical Research, 95, 2150321521.CrossRefGoogle Scholar
Eggleton, R.A. and Banfield, J.F. (1985) The alteration of granitic biotite to chlorite. American Mineralogist, 70, 902910.Google Scholar
El-Bialy, M.Z. (2013) Geochemistry of the Neoproterozoic metasediments formation, Kid meta-morphic complex, Sinai, Egypt: Implications for source-area weathering, provenance, recycling and depositional tectonic setting. Lithos, 175, 6885.CrossRefGoogle Scholar
Eliwa, H.A., Kimura, J.I. and Itaya, T (2006) Late Neoproterozoic Dokhan Volcanics, North Eastern Desert, Egypt: geochemistry and petrogenesis. Precambrian Research, 151, 31—52.CrossRefGoogle Scholar
El-Ramly, M.F. (1972) A new geological map for the basement rocks in the Eastern and South-Western Desert of Egypt. Annals of the Geological Survey of Egypt,2,118.Google Scholar
El-Sayed, M.M., Obeid, M.A., Furnes, H. and Moghazi, A.M. (2004) Late Neoproterozoic volcanism in southern Eastern Desert, Egypt: petrological, structural and geochemical constraints on the tectonic-magmatic evolution of the Allaqi Dokhan Volcanic suite. Neues Jahrbuch Für Mineralogie Abhandlungen, 180, 261286.CrossRefGoogle Scholar
El-Shazly, S.M. and El-Sayed, M.M. (2000) Petrogenesis of the Pan-African El-Bula igneous suite, central Eastern Desert, Egypt. Journal of African Earth Sciences, 31, 317336.CrossRefGoogle Scholar
Engel, A.E.J., Dixon, T.H. and Stern, R.J. (1980) Late Precambrian evolution of Afro-Arabian crust from ocean arc to craton. Bulletin of the Geological Society of America, 91, 699706.2.0.CO;2>CrossRefGoogle Scholar
Evans, B.W.and Vance, J.A. (1987) Epidote phenocrysts in dacitic dikes, Boulder County, Colorado. Contributions to Mineralogy and Petrology, 96, 178185.CrossRefGoogle Scholar
Evarts, R. and Schiffman, P. (1983) Submarine hydro-thermal metamorphism of the Del Puerto ophiolite, California. American Journal of Science, 283, 289340.CrossRefGoogle Scholar
Farrow, C.E.G. and Barr, S.M. (1992) Petrology of high-Al-hornblende and magmatic epidote-bearing plutons in the southeastern Cape Breton Highlands, Nova Scotia. The Canadian Mineralogist, 30, 377—392.Google Scholar
Ferry, J.M. (1979) Reaction mechanisms, physical conditions, and mass transfer during hydrothermal alteration of mica and feldspar in granitic rocks from south-central Maine. American Journal of Science, 278, 10251056.CrossRefGoogle Scholar
Franz, G and Smelik, E.A. (1995) Zoned zoisite from Weissenstein pegmatite that derived from high-pressure melting of eclogite at a 2.0 GPa, importance for decompressional melting in Eclogite. European Journal of Mineralogy, 7, 14211436.Google Scholar
Frisch, W and Abdel-Rahman, A.M. (1999) Petrogenesis of the Wadi Dib alkaline ring complex, Eastern Desert of Egypt. Mineralogy and Petrology, 65, 249275.CrossRefGoogle Scholar
Greenwood, W.R., Hadley, D.G., Anderson, R.E., Fleck, R.J. and Schmidt, D.L. (1976) Late Proterozoic cratonization in southwestern Saudi Arabia. Philosophical Transaction of the Royal Society of Londo.280A, 517527.Google Scholar
Hammarstrom, J.M. and Zen, E-An (1986) Aluminum in hornblende: an empirical igneous geobarometer. American Mineralogist, 71, 1297—1313.Google Scholar
Harris, N.B.W. (1985) Alkaline complexes from the Arabian Shield. Journal of African Earth Science, 3, 8388.CrossRefGoogle Scholar
Hawthorne, F.C. (1983) The crystal chemistry of amphi-boles. The Canadian Mineralogist, 21, 173—480.Google Scholar
Hey, M.H. (1954) A new review of the chlorites. Mineralogical Magazine, 30, 272—292.Google Scholar
Hollister, L.S., Grissom, G.C., Peters, E.K. Stowell, H.H. and Sisson, V.B. (1987) Confirmation of the empirical correlation of Al in hornblende with pressure of solidification of calc-alkaline plutons. American Mineralogist, 72, 231239.Google Scholar
Holtz, F., Johannes, W., Tamic, N. and Behrens, H. (2001) Maximum and minimum water contents of granitic melts generated in the crust: a re-evaluation and implications. Lithos, 56, 114.CrossRefGoogle Scholar
Hume, W.R. (1934) Geology of Egypt: V.2, Part 1.Survey of Egypt, Cairo, 134 pp.Google Scholar
Ishihara, S. (1977) The magnetite-series and ilmenite-series granitic rocks. Mining Geology, 27, 293—305.Google Scholar
Jarrar, G., Stern, R.J., Saffarinai, G. and Al-Zubi, H. (2003) Late- and post-orogenic Neoproterozoic intrusions of Jordan: implications for crustal growth in the northernmost segment of the East African Orogen. Precambrian Research, 123, 295319.CrossRefGoogle Scholar
Johnson, P.R. and Woldehaimanot, B. (2003) Development of the Arabian-Nubian shield: perspectives on accretion and deformation in the northern East African Orogen and the assembly of Gondwana. Geological Society of London Special Publication, 206, 289325.CrossRefGoogle Scholar
Landoll, J.D., Foland, K.A. and Henderson, C.M. (1994) Nd-isotopes demonstrate the role of contamination in the formation of coexisting quartz- and nepheline syenites at the Abu Khruq complex, Egypt. Contributions to Mineralogy and Petrology, 117, 305329.CrossRefGoogle Scholar
Leake, B.E. , Woolley, A.R., Arps, C.E.S., Birch, W.D., Gilbert, M.C., Grice, J.D., Hawthorne, F.C., Kato, A., Kisch, H.J., Krivovichev, V.G., Linthout, K., Laird, J., Mandarino, J.A., Maresch, W.V., Nickel, E.H., Rock, N.M.S., Schumacher, J.C., Smith, D.C., Stephenson, N.C.N., Ungaretti, L., Whittaker, E.J.W. and Guo, Youzhi (1997) Nomenclature of amphiboles: report of the Subcommittee on Amphiboles of the International Mineralogical Association, commission on New Minerals and Mineral Names. The Canadian Mineralogist, 35, 219246.Google Scholar
Liou, J.G. (1973) Synthesis and stability relations of epidote, Ca2Al2FeSi3O12(OH). Journal of Petrology, 14, 381413.CrossRefGoogle Scholar
Loizenbauer, J., Walbrecher, E., Fritz, H., Neumayr, P., Khudeir, A.A. and Kloetzli, U. (2001) Structural geology, single zircon ages and fluid inclusion studies of the Meatiq metamorphic core complex: implications for Neoproterozoic tectonics in the Eastern Desert of Egypt. Precambrian Research, 110, 357383.CrossRefGoogle Scholar
Maurice, A.E., Basta, F.F. and Khiamy, A.A. (2012) Neoproterozoic nascent island arc volcanism from the Nubian shield of Egypt: Magma genesis and generation of continental crust in intra-oceanic arcs. Lithos, 132, 120.CrossRefGoogle Scholar
Naney, M.T.(1983) Phase equilibria of rock-forming ferromagnesian silicates in granitic systems. American Journal of Science, 283, 9931033.CrossRefGoogle Scholar
O'Connor, J.T.(1965) A classification for quartz-rich igneous rocks based on feldspar ratios. US. Geological Survey Professional Paper,525-B, 7984.Google Scholar
Owen, J.V.(1992) Geochemistry of orbicular diorite from the Grenville-Front zone, eastern Labrador. Mineralogical Magazine, 56, 451458.CrossRefGoogle Scholar
Piwinski, A.J. (1965) Experimental study of rocks from a zonedpluton.Unpublished MSc Thesis, Pennsylvania State University, USA, 118 pp.Google Scholar
Popov, V.S., Nikiforova, N.F. and Bogatov, V.I. (2001) Multiple gabbro-granite intrusive series of the Syrostan pluton, southern Urals; geochemistry and petrology. Geochemistry International, 39, 732747.Google Scholar
Schiffman, P. and Smith, B. (1988) Petrology and O-isotope geochemistry of a fossil sea water hydrothermal system within the Solea graben, northern Troodos ophiolite, Cyprus. Journal of Geophysical Research, 93, 4612—4624.CrossRefGoogle Scholar
Schmidt, M.W. (1992) Amphibole composition in tonalities as a function of pressure: an experimental calibration of the Al-in-hornblende-barometer. Contributions to Mineralogy and Petrology, 110, 304310.CrossRefGoogle Scholar
Schmidt, M.W. and Poli, S. (2004) Magmatic Epidote. Pp. 399-130 in: Epidote.(A. Liebscher and G. Franz G., editors). Reviews in Mineralogy & Geochemistry, 56. Mineralogical Society of America and the Geochemical Society, Washington DC.CrossRefGoogle Scholar
Schmidt, M.W. and Thompson, A.B. (1996) Epidote in calc-alkaline magmas: An experimental study of stability, phase relationships, and role of epidote in magmatic evolution. American Mineralogist, 81, 462-174.CrossRefGoogle Scholar
Schuermann, H.M. (1966) The Pre-Cambrian along the Gulf of the Suez and the Northern Part of the Red Sea.E.J. Brill, Leiden, Amsterdam, 76 pp.Google Scholar
Smith, J.V. (1974a) Feldspar Minerals. I. Crystal structure and physical properties.Springer-Verlag, Berlin, 627 pp.Google Scholar
Smith, J.V.(1974b) Feldspar Minerals. IIChemical Vielzeuf, D. andand textural properties. Springer-Verlag, Berlin, 690 pp.Google Scholar
Vail, J.R. (1985a) Pan-African (Late Precambrian) tectonic terrains and the reconstruction ofthe Arabian-Nubian shield. Geology, 13, 839—842.2.0.CO;2>CrossRefGoogle Scholar
Vail, J.R. (1985b) Alkaline ring complexes in Sudan. Journal of African Earth Sciences, 3,51—59.Google Scholar
Veblen, D.R. and Ferry, J.M. (1983) ATEM study of the biotite-chlorite reaction and comparison with petro-logic observations. American Mineralogist, 68, 11601168.Google Scholar
Vielzeuf, D. andSchmidt, M.W. (2001) Melting relation. in hydrous systems revisited: applications to metape. lites, metagreywackes and metabasalts. Contributions to Mineralogy and Petrology, 141,251267.CrossRefGoogle Scholar
Zalata, A.A. (1972) Geology of the basement rocks in the orthern part of El Shayib and Safaga sheets, Eastern Desert of Egypt. PhDThesis,Assiut University Egypt, 240 pp.Google Scholar
Zen, E-an and Hammarstorm, J.M. (1984) Magmatic epidote and its petrologic significance. Geology, 12. 515518.2.0.CO;2>CrossRefGoogle Scholar