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Kenoplumbomicrolite, (Pb,□)2Ta2O6[□,(OH),O], a new mineral from Ploskaya, Kola Peninsula, Russia

Published online by Cambridge University Press:  28 February 2018

Daniel Atencio*
Affiliation:
Instituto de Geociências, Universidade de São Paulo, Rua do Lago, 562, 05508-080, São Paulo, SP, Brazil
Marcelo B. Andrade
Affiliation:
Department of Physics and Interdisciplinary Science, São Carlos Institute of Physics, University of São Paulo, Caixa Postal 369, 13560-970, São Carlos, SP, Brazil
Luca Bindi
Affiliation:
Dipartimento di Scienze della Terra, Università di Firenze, Via G. La Pira 4, I-50121 Florence, Italy
Paola Bonazzi
Affiliation:
Dipartimento di Scienze della Terra, Università di Firenze, Via G. La Pira 4, I-50121 Florence, Italy
Matteo Zoppi
Affiliation:
Dipartimento di Scienze della Terra, Università di Firenze, Via G. La Pira 4, I-50121 Florence, Italy
Chris J. Stanley
Affiliation:
Economic and Environmental Earth Sciences Division, Earth Sciences Department, Natural History Museum, Cromwell Road, London SW7 5BD, UK
Roy Kristiansen
Affiliation:
P.O. Box 32, N–1650 Sellebakk, Norway
*

Abstract

This study presents a complete characterization of kenoplumbomicrolite, (Pb,□)2Ta2O6[□,(OH),O], occurring in an amazonite pegmatite from Ploskaya Mountain, Western Keivy Massif, Kola Peninsula, Murmanskaja Oblast, Northern Region, Russia.

Kenoplumbomicrolite occurs in yellowish brown octahedral, cuboctahedral and massive crystals, up to 20 cm, has a white streak, a greasy lustre and is translucent. The Mohs hardness is ~6. Attempts to measure density (7.310–7.832 g/cm3) were affected by the ubiquitous presence of uraninite inclusions. Reflectance values were measured in air and immersed in oil. Kenoplumbocrolite is optically isotropic. The empirical formula is (Pb1.300.30Ca0.29Na0.08U0.03)Σ2.00(Ta0.82Nb0.62Si0.23Sn4+0.15Ti0.07Fe3+0.10Al0.01)Σ2.00O6[□0.52(OH)0.25O0.23]Σ1.00 (from the crystal used for the structural study) and (Pb1.330.66Mn0.01)Σ2.00(Ta0.87Nb0.72Sn4+0.18Fe3+0.11W0.08Ti0.04)Σ2.00O6[□0.80(OH)0.10O0.10]Σ1.00 (average including additional fragments). The mineral is cubic, space group Fd$\overline 3 $m. The unit-cell parameters refined from powder X-ray diffraction data are a = 10.575(2) Å and V = 1182.6(8) Å3, which are in accord with those obtained previously from a single crystal of a = 10.571(1) Å, V = 1181.3(2) Å3 and Z = 8. The mineral description and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA2015-007a).

Type
Article
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2018 

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Footnotes

Associate Editor: Anthony Kampf

References

Anthony, J.W., Bideaux, R.A., Bladh, K.W. and Nichols, M.C. (1990) Handbook of Mineralogy. Mineral Data Publishing, Tucson Arizona, USA.Google Scholar
Atencio, D., Andrade, M.B., Christy, A.G., Gieré, R. and Kartashov, P.M. (2010) The pyrochlore supergroup of minerals: nomenclature. Canadian Mineralogist, 48, 673698.Google Scholar
Atencio, D., Andrade, M.B., Bastos Neto, A.C. and Pereira, V.P. (2017) Ralstonite renamed hydrokenoralstonite, coulsellite renamed fluornatrocoulsellite, and their incorporation into the pyrochlore supergroup. Canadian Mineralogist, 55, 115120.Google Scholar
Beurlen, H., Soares, D.R., Thomas, R., Prado-Borges, L.E. and Castro, C. (2005) Mineral chemistry of tantalate species new in the Borborema Pegmatitic Province, Northeast Brazil. Anais da Academia Brasileira de Ciências, 77, 169182.Google Scholar
Bindi, L., Zoppi, M. and Bonazzi, P. (2006) Plumbomicrolite from the Ploskaya Mountain, Keivy Massif, Kola Peninsula, Russia: composition and crystal structure. Periodico di Mineralogia, 75, 5158.Google Scholar
Christy, A.G. and Atencio, D. (2013) Clarification of status of species in the pyrochlore supergroup. Mineralogical Magazine, 77, 1320.Google Scholar
Chukanov, N.V (2014) Infrared Spectra of Mineral Species: Extended library. Springer-Verlag GmbH, Dordrecht–Heidelberg–New York–London, 1716 pp.Google Scholar
Downs, R.T., Bartelmehs, K.L., Gibbs, G.V. and Boisen, M.B. (1993) Interactive software for calculating and displaying X-ray or neutron powder diffractometer patterns of crystalline materials. American Mineralogist, 78, 11041107.Google Scholar
Ercit, T.S. (1986) The Simpsonite Paragenesis: the Crystal Chemistry and Geochemistry of Extreme Ta Fractionation. PhD Thesis, University of Manitoba, Winnipeg, USA.Google Scholar
Raade, G. (2010) Plumbomicrolite from the Heftetjern granitic pegmatite, Tørdal, Telemark,south Norway. Norsk Bergverksmuseum, Skrifter, 43, 2128.Google Scholar
Safiannikoff, A. and van Wambeke, L. (1961): Sur un terme plombifère du groupe pyrochlore-microlite. Bulletin de la Société Francaise de Minéralogie et de Cristallographie, 84, 382384.Google Scholar
Stepanov, V.I., Bukanov, V.V. and Bykova, A.V. (1982) Plumbomicrolite from amazonite pegmatite of Mount Ploskaya, its first find in the USSR. Doklady Akademii Nauk SSSR, 263, 183185 [in Russian]. Doklady Earth Sciences Section, 263, 130–132.Google Scholar
Uher, P., Černý, P. and Chapman, R. (2008) Foordite-thoreaulite, Sn2+Nb2O6– Sn2+Ta2O6: compositional variations and alteration products. European Journal of Mineralogy, 20, 501516.Google Scholar
Voloshin, A.V., Bukanov, V.V. and Polezhaeva, L.I. (1981) Plumbomicrolite and plumbopyrochlore from amazonite pegmatites of the Kola Peninsula. Mineralogicheskij Zhurnal, 3, 2034 [in Russian].Google Scholar
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