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The first environmental science experiments on the new microfocus spectroscopy beamline at Diamond

Published online by Cambridge University Press:  05 July 2018

J. F. W. Mosselmans ,
P. D. Quinn ,
J. Roque Rosell ,
K. D. Atkinson ,
A. J. Dent ,
S. I. Cavill ,
M. E. Hodson ,
C. A. Kirk  and
P. F. Schofield
J. F. W. Mosselmans*
Affiliation:
Diamond Light Source Ltd, Chilton, Didcot, OX11 0DE, UK
P. D. Quinn
Affiliation:
Diamond Light Source Ltd, Chilton, Didcot, OX11 0DE, UK
J. Roque Rosell
Affiliation:
Diamond Light Source Ltd, Chilton, Didcot, OX11 0DE, UK
K. D. Atkinson
Affiliation:
Diamond Light Source Ltd, Chilton, Didcot, OX11 0DE, UK
A. J. Dent
Affiliation:
Diamond Light Source Ltd, Chilton, Didcot, OX11 0DE, UK
S. I. Cavill
Affiliation:
Diamond Light Source Ltd, Chilton, Didcot, OX11 0DE, UK
M. E. Hodson
Affiliation:
Department of Soil Science, University of Reading, WhiteKnights, Reading, RG6 6DW, UK
C. A. Kirk
Affiliation:
Department of Chemistry, University of Loughborough, Leicestershire, LE11 3TU, UK
P. F. Schofield
Affiliation:
Department of Mineralogy, Natural History Museum, Cromwell Road, SW7 5BD, London, UK
*
*E-mail: [email protected]
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Abstract

Synchrotron based μ-XRF, μ-XAS and μ-XRD have made a major impact in the field of environmental science in the last ten years. One of the first seven ‘day one’ beamlines on the Diamond Light Source is a microfocus spectroscopy beamline, beamline I18. Here the current status of the beamline and the opportunities it presents in the field of environmental science are described, with results from two of the first experiments also included. The first is based on the use of bonemeal to remediate soil. We used Zn K-edge and Pb L3-edge spectroscopy to characterize the speciation of these two elements on a soil after bonemeal treatment. The results are compared with bulk measurements taken on the whole soil and standard materials. The second experiment described here is a study of the speciation and association of Ni in a laterite from Moa Bay, Cuba. Here the differences in the Ni speciation associated with Mn oxides are examined and compared with Fe oxides phases.

Keywords

microfocus spectroscopy beamlinelateritebonemeal treatmentMoa BayCuba
Type
Research Article
Information
Mineralogical Magazine , Volume 72 , Issue 1 , February 2008 , pp. 197 - 200
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2008

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References

Brand, N.W., Butt, C.R.M. and Elias, M. (1998) Exploration model: the Cawse shear-controlled Ni-oxide and associated Mn-Co-Ni deposit, Western Australia AGSO. Journal of Australian Geology and Geophysics, 17, 81–88.Google Scholar
Dalvi, A.D., Bacon, W.C. and Osborne, R.C. (2004) Past and future of nickel laterite projects. Symposium on International Laterite Nickel 2004, Charlotte, N.C., USA. 23–24 pp.Google Scholar
Gleeson, S.A., Butt, C.R.M. and Elias, M. (2003) Nickel laterites, a review. SEG Newsletter, 54, 11–18.Google Scholar
Hodson, M.E., Valsami-Jones, E. and Cotter-Howells, J.D. (2000a) Metal phosphates and remediation of contaminated land. Pp. 291–311 in: Environmental Mineralogy. Microbial interactions, anthropogenic influences, contaminated land and waste management. Mineralogical Society Series No 9, London.Google Scholar
Hodson, M.E., Valsami-Jones, E. and Cotter-Howells, J.D. (2000b) Bone meal additions as a remediation treatment for metal contaminated soil. Environmental Science and Technology, 36, 3501–3507.Google Scholar
Hodson, M.E., Valsami-Jones E., Cotter-Howells, J.D., Dubbin, W.E., Kemp, A.J. and Warren, A. (2001) Effect of bone meal (calcium phosphate) amendments on metal release from contaminated soils — a leaching column study. Environmental Pollution, 111, 233–243.Google Scholar
Howells, M.R., Cambie, D., Duarte, R.M., Irick, S., MacDowell, A.A., Padmore, H.A., Renner, T.R., Rah, S. and Sandier, R. (2000) Theory and practice of elliptically bent X-ray mirrors. Optical Engineering, 39, 2748–2762.CrossRefGoogle Scholar
Jerden, J.L. and Sinha, A.K. (2003) Phosphate based immobilization of uranium in an oxidizing bedrock aquifer. Applied Geochemistry, 18, 823–843.CrossRefGoogle Scholar
Ma, Q.Y., Traina, S.J. and Logan, T.J. (1993) In situ lead immobilization by apatite. Environmental Science and Technology, 27, 1803–1810.CrossRefGoogle Scholar
Martinez, C.E., Bazilevskaya, K.A. and Lanzirotti, A. (2006) Zinc coordination to multiple ligand atoms in organic-rich surface soils. Environmental Science and Technology, 40, 5688–5695.CrossRefGoogle ScholarPubMed
Oliveira, S.M.B., Parititi, C.S. and Enzweiler, J. (2001) Ochreous laterite: a nickel ore from Punta Gordor, Cuba. Journal of South American Earth Sciences, 14, 307–317.CrossRefGoogle Scholar
Proenza, J.A., Gervilla, F., Melgarejo, J.C. and Bodinier, J.L. (1999) Al- and Cr-rich chromitites from the Mayari-Baracoa ophiolitic belt (eastern Cuba): consequences of interactions between volatile-rich melts and peridotites in suprasubduction mantle. Economic Geology, 94, 547–566.CrossRefGoogle Scholar
Ryser, A.L., Strawn, D.G., Marcus, M.A., Fakra, S., Johnson-Maynard, J.L. and Moller, G. (2006) Microscopically focused synchrotron X-ray investigation of selenium speeiation in soils developing on reclaimed mine lands. Environmental Science and Technology, 40, 462–467.CrossRefGoogle ScholarPubMed
Seaman, J.C, Arey, J.S. and Bertsch, P.M. (2001) Immobilization of nickel and other metals in contaminated sediments by hydroxyapatite addition. Journal of Environmental Quality, 30, 460–469.CrossRefGoogle ScholarPubMed
Sneddon, I.R., Orueetxebarria, M., Hodson, M.E., Schofield, P.F. and Valsami-Jones, E. (2006) Use of bone meal amendments to immobilise Pb, Zn and Cd in soil: a leaching column study. Environmental Pollution, 144, 816–825.CrossRefGoogle ScholarPubMed
Vantelon, D., Lanzirotti, A., Scheinost, A.C. and Kretzschmar, R. (2005) Spatial distribution and speeiation of lead around corroding bullets in a shooting range soil studied by micro-X-ray fluorescence and absorption spectroscopy. Environmental Science and Technology, 39, 4808–4815.CrossRefGoogle Scholar
Wiedemann, H. (2003) Synchrotron Radiation. Springer, Berlin.CrossRefGoogle Scholar