Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-23T13:03:43.219Z Has data issue: false hasContentIssue false
  • English
  • Français

Extreme closed system fractionation of volatile-rich, ultrabasic peralkaline melt inclusions and the occurrence of djerfisherite in the Kugda alkaline complex, Siberia

Published online by Cambridge University Press:  05 July 2018

C. M. B. Henderson ,
L. N. Kogarko  and
D. A. Plant
C. M. B. Henderson
Affiliation:
Department of Earth Sciences, University of Manchester, M13 9PL, UK
L. N. Kogarko
Affiliation:
Vernadsky Institute of Geochemistry, Academy of Sciences, Moscow 117975, Russia
D. A. Plant
Affiliation:
Department of Earth Sciences, University of Manchester, M13 9PL, UK
Get access Rights & Permissions [Opens in a new window]

Abstract

Djerfisherite [K6(Cu,Fe,Ni)25S26Cl] has been found as a daughter mineral in melt inclusions in melilite from a Kugda melilitolite. The inclusion mineral assemblage includes pyrrhotite, pentlandite, forsterite, diopside, monticellite, phlogopite, wollastonite, nepheline, sodalite, combeite, calcite, Na-K-Ca carbonate, and hydrated calcium silicates. The djerfisherite is Ni-rich rather than Cu-rich consistent with an ultimate upper mantle magma source. The djerfisherite-bearing assemblage formed from primary carbonate/alkali-rich, melilititic melt inclusions which underwent extreme, closed-system, magmatic to postmagmatic fractionation over a temperature range of >1000° to <500 °C.

Keywords

fractionationperalkaline inclusionsdjerfisheriteKugdaSiberia
Type
Letter
Information
Mineralogical Magazine , Volume 63 , Issue 3 , June 1999 , pp. 433 - 438
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Balabonin, N.L., Voloshin, A.V., Pakhomovsky, J.A. and Poljakov, K.I. (1980) The composition of djerfisherite in alkali complexes of the Kola Peninsula. Mineral. J., 2, 90–9. (in Russian).Google Scholar
Barkov, A.Y., Laajoki, K.V.O., Gehor, S.A., Yakovlev, Y.N. and Taikina-Aho, O. (1997) Chlorine-poor analogues of djerfisherite-thalfenisite from Noril'sk, Siberia and Salmagorsky, Kola Peninsula, Russia. Canad. Mineral., 35, 1421–30.Google Scholar
Bulanova, G.P., Shestkova, O.E., and Leskova, N.V. (1980) Djerfisherite from sulphide segregations in diamond. Dokl. Akad. Nauk SSSR, 255, 430–3. (in Russian).Google Scholar
Clarke, D.B., Pe, G.G., Mackay, R.M., Gill, K.R., O'Hara, M.J. and Gard, J.A. (1977) A new potassium-iron-sulphide from a nodule in kimberlite. Earth Planet. Sci. Lett., 35, 421–8.CrossRefGoogle Scholar
Clarke, D.B., Mitchell, R.H., Chapman, C.A.T. and MacKay, R.M. (1994) Occurrence and origin of djerfisherite from the Elwin Bay kimberlite, Somerset Island, Northwest territories. Canad. Mineral., 32, 815–23.Google Scholar
Czamanske, G.K., Lanphere, M.A., Erd, R.C. and Blake, M.C. Jr. (1978) Age measurements of potassium-bearing sulphide minerals by the 40Ar/39Ar technique. Earth Planet. Sci. Lett., 40, 107–10.CrossRefGoogle Scholar
Czamanske, G.K., Erd, R.C., Sokolova, M.J., Dobrovol'skaya, M.G. and Dmitrieva, M.T. (1979) New data on rasvumite and djerfisherite. Amer. Mineral., 64, 776–8.Google Scholar
Czamanske, G.K., Leonard, B.F. and Clark, J.R. (1980) Erdite, a new hydrated sodium iron sulfide mineral. Amer. Mineral., 65, 509–15.Google Scholar
Dawson, J.B. (1998) Peralkaline nephelinite-natrocarbonatite relationships at Oldoinyo Lengai, Tanzania. J. Petrol., 39, 2077–94.CrossRefGoogle Scholar
Dawson, J.B., Smith, J.V. and Steele, I.M. (1992) 1996 ash eruption of the carbonatite volcano Oldoinyo Lengai: mineralogy of lapilli and mixing of silicate and carbonate magmas. Mineral. Mag., 56, 1–16.CrossRefGoogle Scholar
Dobrovol'skaya, M.G., Tsepin, A.I., Ilupin, I.P. and Ponomarenko, A.I. (1975) Djerfisherites from Yakutia kimberlites. In Mineraly I Paragenezisy Mineralov Endogennykh Mestorozhdeniy (Tamarinov, P.M., ed.). Izd. Nauka, Leningrad, (in Russian).Google Scholar
Dobrovol'skaya, M.G., Rogova, V.P., Tsepin, A.I. and Malov, V.S. (1980) About the sulphide mineralization in charoitic rocks (Murunsky massif). Mineral. J. (Kiev), 2, 3–13.(in Russian).Google Scholar
El Goresy, A., Grogler, N. and Ottemann, J. (1971) Djerfisherite composition in Bishopville, Pena Blanca Springs, St Marks amd Toluca meteorites. Chem. Erde, 30, 77–82.Google Scholar
Eremeev, N.V., Dobrol'skaya, M.G. and Muravitskaya, G.N. (1982) The new occurrence of djerfisherite in alkaline series of the Inaglinsky complex (Aldansky shield). Dokl. Acad. Nauk SSSR, 263, 1210–12.(in Russian).Google Scholar
Genkin, A.D., Troneva, N.V. and Zhuravlev, N.N. (1970) The first occurrence in ores of the sulfide of potassium, iron, copper, djerfisherite. Geochem. Int., 693–701.Google Scholar
Hanois, L. and Mineau, R. (1991) Geochemistry of the Ile Cadieus monticellite alnoite, Quebec, Canada. Canad. J. Earth Sci., 28, 1050–57.CrossRefGoogle Scholar
Hogarth, D.D. (1997) Mineralogy of leucite-bearing dykes from Napolean Bay, Baffin Island: multistage Proterozoic lamproites. Canad. Mineral., 35, 53–78.Google Scholar
Ifantopulo, T.N., Yushko-Zakharanova, O.E. and Dubakina, L.C. (1978). Djerfisherite from Lovozersky massif. Dokl. Akad. Nauk SSSR, 243, 199–200.(in Russian).Google Scholar
Jago, B.C. and Gittins, J. (1999) Mn- and F-bearing rasvumite in natrocarbonatite at Oldoinyo Lengai Volcano, Tanzania. Mineral. Mag., 63, 53–5.CrossRefGoogle Scholar
Jamtveit, B., Dahlgren, S. and Austrheim, H. (1997) High-grade contact metamorphism of calcareous rocks from the Oslo Rift, Southern Norway. Amer. Mineral., 82, 1241–54.CrossRefGoogle Scholar
Kogarko, L.N., Kononova, V.A., Orlova, M.P. and Woolley, A.R. (1991) Alkaline rocks and carbonatites of the world. Part 2: Former USSR. Chapman & Hall, London, 226 pp.Google Scholar
Kogarko, L.N., Plant, D.A., Henderson, C.M.B. and Kjarsgaard, B.A. (1995) Na-rich carbonate inclusions in perovskite and calzirtite from the Guli intrusive Ca-carbonatite, polar Siberia. Contrib. Mineral. Petrol., 109, 124–9.CrossRefGoogle Scholar
Konev, A.A., Afonin, L.A., Perfil'yeva, L.A. and Ushchapovskaya, Z.F. (1972). Djerfisherite from Tazheran skarns. In Vopr. Mineral. Gorn. Porod. Rud. Vost. Sib. (Shmakin, B.M., ed.), pp. 15–22. Akad. Nauk SSSR, Sib. Otd., Inst. Geokhim., Irkutsk, USSR, (in Russian).Google Scholar
Korobeinikov, A.N., Mitrofanov, F.P., Gehor, S., Laajoki, K., Pavlov, V.P. and Mamontov, V.P. (1998) Geology and copper sulphide mineralization of the Salmagorski ring igneous complex, Kola Peninsula, NW Russia. J. Petrol., 39, 2033–41.CrossRefGoogle Scholar
Mitchell, R.H. (1997) Carbonate-carbonate immiscibility, neighbourite and potassium iron sulphide in Oldoinyo Lengai natrocarbonatite. Mineral. Mag., 61, 779–89.CrossRefGoogle Scholar
Nielsen, T.F.D., Solovova, I.P. and Veksler, I.V. (1997) Parental melts of melilitolite and origin of alkaline carbonatite: evidence from crystallised melt inclusions, Gardiner complex. Contrib. Mineral. Petrol., 126, 331–44.CrossRefGoogle Scholar
Petibon, C.M., Kjarsgaard, B.A., Jenner, G.A. and Jackson, S.E. (1998) Phase relationships of a silicate-bearing natrocarbonatite from Oldoinyo Lengai at 20 and 100MPa. J. Petrol., 39, 2137–51.CrossRefGoogle Scholar
Ramdohr, P. (1963) The opaque minerals in stony meteorites. J. Geophys. Res., 68, 2011–36.CrossRefGoogle Scholar
Shapkin, A.I., Garanin, A.V. and Khodakovskii, I.L. (1986) DIANIK GEOKHI. Russian Acad. Sci. Computer Complex for Chemical Thermodyamics Project. In Direct and Inverse Thermodynamic Tasks, pp. 80–88. Nauka, Novosibirsk, (in Russian).Google Scholar
Sokolova, M.N., Dobrovo'skaya, M.G., Organova, N.I., Kazakova, M.E. and Vasil'yeva, G.L. (1971) On the occurrence and distribution of djerfisherite in pegmatites from the Khibina massif. Geol. Rudnykh Mestorozhd., 13, 62–71.(in Russian).Google Scholar
Zharikov, V.A., Shmulovich, K.I., and Bulatov, V.K. (1977) Experimental studies in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and conditions of high-temperature metamorphism. Tectonophys., 43, 145–62.CrossRefGoogle Scholar