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Equation of state of hydrous Fo90 ringwoodite to 45 GPa by synchrotron powder diffraction

Published online by Cambridge University Press:  05 July 2018

M. H. Manghnani ,
G. Amulele ,
J. R. Smyth ,
C. M. Holl ,
G. Chen ,
V. Prakapenka  and
D. J. Frost
M. H. Manghnani
Affiliation:
Hawaii Institute of Geophysics, University of Hawaii, Honolulu, HI 96822, USA
G. Amulele
Affiliation:
Hawaii Institute of Geophysics, University of Hawaii, Honolulu, HI 96822, USA
J. R. Smyth*
Affiliation:
Department of Geological Sciences, University of Colorado, Boulder, CO 80309, USA
C. M. Holl
Affiliation:
Department of Geological Sciences, University of Colorado, Boulder, CO 80309, USA
G. Chen
Affiliation:
Argonne National Laboratory, University of Chicago, Chicago IL 60637, USA
V. Prakapenka
Affiliation:
Argonne National Laboratory, University of Chicago, Chicago IL 60637, USA
D. J. Frost
Affiliation:
Bayerisches Geoinstitut, Universität Bayreuth, D95440 Bayreuth, Germany
*
*E-mail: [email protected]
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Abstract

The equation of state of Fo90 hydrous ringwoodite has been measured using X-ray powder diffraction to 45 GPa at the GSECARS beam line at the Advanced Photon Source synchrotron at Argonne National Laboratory. The sample was synthesized at 1400°C and 20 GPa in the 5000 ton multi anvil press at Bayerisches Geoinstitut in Bayreuth. The sample has the formula Mg1.70Fe0.192+ Fe0.023+H0.13- Si1.00O4 as determined by electron microprobe, Fourier transform infrared and Mössbauer spectroscopies, and contains ~0.79% H2O by weight. Compression of the sample had been been measured previously to 11 GPa by single crystal X-ray diffraction. A third-order Birch-Murnaghan equation of state fit to all of the data gives V0 = 530.49±0.07 Å3, K0 = 174.6±2.7 GPa and K' = 6.2±0.6. The effect of 1% H incorporation in the structure on the bulk modulus is large and roughly equivalent to an increase in the temperature of ∼600°C at low pressure. The large value of K' indicates significant stiffening of the sample with pressure so that the effect of hydration decreases with pressure.

Keywords

equation of stateringwooditesynchrotronBirch-Murnaghan equation
Type
Research Article
Information
Mineralogical Magazine , Volume 69 , Issue 3 , June 2005 , pp. 317 - 323
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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References

Angel, R.J. (2000) Equations of state. Pp. 35–60 in: High-pressure, High-temperature Crystal Chemistry (Hazen, R.M. and Downs, R.T., editors). Reviews in Mineralogy and Geochemistry, 41. Mineralogical Society of America and the Geochemical Society, Washington, D.C.CrossRefGoogle Scholar
Angel, R.J., Allan, D.R., Miletich, R. and Finger, L.W. (1997) The use of quartz as an internal pressure standard in high pressure crystallography. Journal of Applied Crystallography, 30, 461—466.CrossRefGoogle Scholar
Angel, R.J., Frost, D.J., Ross, N.L. and Hemley, R. (2001) Stabilities and equations of state of dense hydrous magnesium silicates. Physics of the Earth and Planetary Interiors, 111, 181—196.CrossRefGoogle Scholar
Dixon, J.E. and Clague, D.A. (2001) Volatiles in basaltic glasses from Loihi Seamount, Hawaii: Evidence for a relatively dry plume component. Journal of Petrology, 42, 627–654.CrossRefGoogle Scholar
Fischer, T.P., Hilton, D.R., Zimmer, M.M., Shaw, A.M., Sharp, Z.D. and Walker, J.A. (2002) Subduction and recycling of nitrogen along the Central American margin. Science, 297, 1154–1157.CrossRefGoogle ScholarPubMed
Hammersley, A.P., Svensson, S.O., Hanfland, M., Fitch, A.N. and Hausermann, D. (1996) Two-dimensional detector software: from real detector to idealised image or two-theta scan. High Pressure Research, 14, 235–242.CrossRefGoogle Scholar
Hazen, R.M. and Yang, H. (1999) Effects of cation substitution and order disorder on P-V-T equations of state of cubic spinels. American Mineralogist, 84, 1956–1960.CrossRefGoogle Scholar
Inoue, T., Weidner, D.J., Northrup, P.A. and Parise, J.B. (1998) Elastic properties of hydrous ringwoodite (γ- phase in Mg2SiO4). Earth and Planetary Science Letters, 160, 107–113.CrossRefGoogle Scholar
Jacobsen, S.D., Smyth, J.R., Spetzler, H., Holl, C.M. and Frost, D.J. (2004) Sound velocities and elasticity of Fe-bearing hydrous ringwoodite. Physics of the Earth and Planetary Interiors, 143—144, 47—56.CrossRefGoogle Scholar
Karato, S.I. (1998) Plastic deformation of silicate spinel under transition-zone conditions of the Earth's mantle. Nature, 395, 266–269.CrossRefGoogle Scholar
Kavner, A. (2003) Elasticity and strength of hydrous ringwoodite at high pressure. Earth and Planetary Science Letters, 214, 645—654.CrossRefGoogle Scholar
Kleppe, A.K. Jephcoat, A.P., Smyth, J.R. and Frost, D.J. (2002) On protons, iron, and the high pressure behaviour of ringwoodite. Geophysical Research Letters, 29, 2021. DOI: 10.1029/2002GL015276.CrossRefGoogle Scholar
Kohlstedt, D.L., Keppler, H. and Rubie, D.C. (1996) The solubility of water in α, β and γ phases of (Mg,Fe)2SiO4 . Contributions to Mineralogy and Petrology, 123, 345–357.CrossRefGoogle Scholar
Kudoh, Y., Kuribayashi, T., Mizohata, H. and Ohtani, E. (2000) Structure and cation disorder of hydrous ringwoodite, γ-Mg1.89Si0.97H0.34O4 . Physics and Chemistry of Minerals, 27, 474–479.CrossRefGoogle Scholar
Larson, A.C. and Von Dreele, R.B. (2000) General Structure Analysis System (GSAS). Los Alamos Unclassified Report LAUR 86-748, Los Alamos National Laboratory, New Mexico, USA, 231 pp.Google Scholar
Locke, D.R., Holloway, J.R. and Hervig, R. (2002) Oxidation independent solution mechanism for hydrogen in olivine: Examples from simple and peridotite systems. Eos Transactions, AGU, 83(47), Abstract T21C-1116.Google Scholar
Meng, Y., Weidner, D.J., Gwanmesia, G.D., Liebermann, R.C., Vaughan, M.T., Wang, Y., Leinenweber, K., Pacalo, R.E., Yeganeh-Haeri, A. and Zhao, Y. (1993) In situ high P-T X-ray diffraction studies on three polymorphs (α_β_γ) of Mg2SiO4 . Journal of Geophysical Research, 98, 22199–22207.CrossRefGoogle Scholar
Mottl, M.J., Komor, S.C., Fryer, P. and Moyer, C.L. (2003) Deep-slab fluids fuel extremophilic Archaea on a Mariana forearc serpentinite mud volcano: ODP Leg 195. Geochemistry, Geophysics, Geosystems, 4(11), 9009, DOI: 10.1029/2003GC000588.CrossRefGoogle Scholar
Schmidt, M.W. and Poli, S. (1998) Experimentally based water budgets for dehydrating slabs and consequences for arc magma generation. Earth and Planetary Science Letters, 163, 361–179.CrossRefGoogle Scholar
Sinogeikin, S.V., Bass, J.D. and Katsura, T. (2001) Single-crystal elasticity of γ-(Mg0.91Fe0.09)2SiO4 to high pressures and to high temperatures. Geophysical Research Letters, 28, 4335–4338.CrossRefGoogle Scholar
Smyth, J.R. (1987) Beta-Mg2SiO4; a potential host for water in the mantle. American Mineralogist, 72, 1051–1055.Google Scholar
Smyth, J.R. (1994) A crystallographic model for hydrous wadsleyite: An ocean in the Earth's interior. American Mineralogist, 79, 1021–1025.Google Scholar
Smyth, J.R. and Ahrens, T.J. (1997) The crystal structure of calcite III. Geophysical Research Letters, 24, 1595–1598.CrossRefGoogle Scholar
Smyth, J.R., Jacobsen, S.D., Swope, R.J., Angel, R.J., Arlt, T., Domanik, K. and Holloway, J.R. (2000) Crystal structures and compressibilities of synthetic 2M1 and 3T phengite micas. European Journal of Mineralogy, 12, 955–963.CrossRefGoogle Scholar
Smyth, J.R., Holl, C.M., Frost, D.J., Jacobsen, S.D., Langenhorst, F. and McCammon, C.A. (2003) Structural systematics of hydrous ringwoodite and water in the Earth's interior. American Mineralogist, 88, 1402–1407.CrossRefGoogle Scholar
Smyth, J.R., Holl, C.M., Frost, D.J. and Jacobsen, S.D. (2004) High pressure crystal chemistry of hydrous ringwoodite and water in the Earth's interior. Physics of the Earth and Planetary Interiors 143—144, 271–278.CrossRefGoogle Scholar
Smyth, J.R., Holl, C.M., Langenhorst, F., Laustsen, H.M.S., Rossman, G.R., Kleppe, A., McCammon, C.A., Kawamoto, T. and van Aken, P.A. (2005) Crystal chemistry of wadsleyite U and water in the Earth's interior. Physics and Chemistry of Minerals, 32, 691–705. doi 10.1007/s00269-004-0431-x.CrossRefGoogle Scholar
White, W.M. (2002) Earth science: through the wringer. Nature, 420, 366–367.CrossRefGoogle ScholarPubMed
Yusa, H., Inoue, T. and Ohishi, Y. (2000) Isothermal compressibility of hydrous ringwoodite and its relation to mantle discontinuities. Geophysical Research Letters, 11, 413–416.CrossRefGoogle Scholar
Zerr, A., Reichmann, H.-J., Euler, H. and Boehler, R. (1993) Hydrostatic compression of γ-(Mg0.6Fe0.4)2SiO4 to 50.0 GPa. Physics and Chemistry of Minerals, 19, 507–509.CrossRefGoogle Scholar