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Crystal chemistry of natural layered double hydroxides. I. Quintinite-2H-3c from the Kovdor alkaline massif, Kola peninsula, Russia

Published online by Cambridge University Press:  05 July 2018

S. V. Krivovichev ,
V. N. Yakovenchuk ,
E. S. Zhitova ,
A. A. Zolotarev ,
Y. A. Pakhomovsky  and
G. Yu. Ivanyuk
S. V. Krivovichev
Affiliation:
Department of Crystallography, Faculty of Geology, St. Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia Nanomaterials Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia
V. N. Yakovenchuk
Affiliation:
Nanomaterials Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia Geological Institute, Kola Science Center, Russian Academy of Sciences, Apatity, Russia
E. S. Zhitova
Affiliation:
Department of Crystallography, Faculty of Geology, St. Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia
A. A. Zolotarev
Affiliation:
Department of Crystallography, Faculty of Geology, St. Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia
Y. A. Pakhomovsky
Affiliation:
Nanomaterials Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia Geological Institute, Kola Science Center, Russian Academy of Sciences, Apatity, Russia
G. Yu. Ivanyuk
Affiliation:
Nanomaterials Research Center, Kola Science Center, Russian Academy of Sciences, Apatity, Russia Geological Institute, Kola Science Center, Russian Academy of Sciences, Apatity, Russia
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Abstract

The crystal structure of quintinite-2H-3c, [Mg4Al2(OH)12](CO3)(H2O)3, from the Kovdor alkaline massif, Kola peninsula, Russia, was solved by direct methods and refined to an agreement index (R1) of 0.055 for 484 unique reflections with |Fo| ≥ 4σF. The mineral is rhombohedral, R32, a = 5.2745(7), c = 45.36(1) Å. The diffraction pattern of the crystal has strong and sharp Bragg reflections having h–k = 3n and l = 3n and lines of weak superstructure reflections extended parallel to c* and centred at h–k ≠ 3n. The structure contains six layers within the unit cell with the layer stacking sequence of …AC=CA=AC=CA=AC=CA… The Mg and Al atoms are ordered in metal hydroxide layers to form a honeycomb superstructure. The full superstructure is formed by the combination of two-layer stacking sequence and Mg-Al ordering. This is the first time that a long-range superstructure in carbonate-bearing layered double hydroxide (LDH) has been observed. Taking into account Mg-Al ordering, the unique layer sequence can be written as …=Ab1C=Cb1A=Ab2C=Cb2A=Ab3C=Cb3A=… The use of an additional suffix is proposed in order to distinguish between LDH polytypes having the same general stacking sequence but with different c parameters compared with the ‘standard’ polytype. According to this notation, the quintinite studied here can be described as quintinite-2H-3c or quintinite-2H-3c[6R], indicating the real symmetry.

Keywords

layered double hydroxidesquintinitecrystal structurecation orderingpolytypism
Type
Research Article
Information
Mineralogical Magazine , Volume 74 , Issue 5 , October 2010 , pp. 821 - 832
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2010

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