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The crystal chemistry of cowlesite

Published online by Cambridge University Press:  05 July 2018

Giovanna Vezzalini
Affiliation:
Istituto di Mineralogia e Petrologia, Università di Modena Via S. Eufemia 19, 41100 Modena, Italy
Gilberto Artioli
Affiliation:
Istituto di Mineralogia e Petrologia, Università di Modena Via S. Eufemia 19, 41100 Modena, Italy
Simona Quartieri
Affiliation:
Istituto di Mineralogia e Petrologia, Università di Modena Via S. Eufemia 19, 41100 Modena, Italy
Harry Foy
Affiliation:
19 Wynard Park, Belfast BT5 6NS, Northern Ireland

Abstract

Cowlesite specimens from nine new occurrences in Northern Ireland and from eight localities previously reported in the literature, were crystal-chemically characterised. The chemical data for a total of 25 samples indicate a composition close to the stoichiometric formula for cowlesite and a very limited compositional range. X-ray powder diffraction spectra were performed on 8 samples. The crystallographic unit cell permit a proper indexing of the X-ray powder diffraction patterns as orthorhombic, unit cell constants close to a 23.3, b 30.6, c 25.0 Å and doubled with respect to those originally reported in literature. The powder pattern and the TG curve arc reported for an unidentified mineral species associated with cowlesite in one of the samples from Northern Ireland.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1992

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References

Albee, A. L. and Ray, L. (1970) Anal. Chem., 42, 1408–14.CrossRefGoogle Scholar
Alberti, A. (1991) Proc. Int. Symposium on Chemistry of microporous crystals, Kodansha Ltd, Tokyo, 107-22.CrossRefGoogle Scholar
Artioli, G., Gottardi, G., Rinaldi, R., Satow, Y., Horiuchi, H., Ye, J., Sawada, H., Tanaka, M., and Tokonami, M. (1988) Photon Factory Activity Report, KEK, proposal No. 87-086.Google Scholar
Betz, V. (1981) Mineral. Record., 12, 526.Google Scholar
Birch, W. D. (1988) Austral. MineraL, 3(1), 911.Google Scholar
Birch, W. D. (1989) Zeolites of Victoria, Mineral. Soc. Victoria, Special Publ. no. 2.Google Scholar
Fujimoto, M., Matsubara, S., and Nishido, H. (1990) Chigaku Kenkyu, 39(4), 219-24 (in Japanese).Google Scholar
Gottardi, G. and Galli, E. (1985) Natural zeolites, Springer-Verlag Editors, Berlin Heidelberg.CrossRefGoogle Scholar
Matsubara, S., Tiba, T., and Kato, A. (1978) Bull. Natn. Sci. Mus., ser. C (Geol), 4(2), 33-6.Google Scholar
Merlino, S. (1984) Proc. 6th Int. Conf. on Zeolites (Bisio, A. and Olson|D. H., eds.), Butterworth, Guildford, 747-59.Google Scholar
Nawaz, R. (1984) Mineral. Mag., 48, 565–6.CrossRefGoogle Scholar
SPSS-X Statistical Algorithms (1983) SPSS Inc. Chicago.Google Scholar
Wise, W. S. and Tschernich, R. W. (1975) Amer. Mineral., 60, 951–6.Google Scholar
Ziebold, T. O. and Ogilvie, R. E. (1964) Anal. Chem., 36, 322–7.CrossRefGoogle Scholar