In 1926 schultenite from Tsumeb, Otavi, South-West Africa, was described as a new mineral by L. J. Spencer and related to the compound PbHAsO4. The specimen on which the original description was based is still unique in the British Museum collection and was used for the present study. There appears to be no record in the literature that the mineral has been discovered in any other locality

For the X-ray examination rather small fragments (less than 0·1 × 0·05 mm.) were broken from pieces of crystals since all the available crystals were too large and the material has a high absorption to X-rays. Single crystal rotation, oscillation, and Weissenberg photographs in 6-cm. diameter cameras with Cu-Kα radiation as well as Laue photographs (crystal-plate distance 4 cm.) with tungsten radiation were used to derive the unit-cell dimensions and space-group.