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X-ray studies of halloysite and metahalloysite

Part II. The transition of halloysite to metahalloysite in relation to relative humidity

Published online by Cambridge University Press:  14 March 2018

G. W. Brindley
Affiliation:
Physics Laboratories, University of Leeds
J. Goodyear
Affiliation:
Physics Laboratories, University of Leeds

Extract

The experiments described below on the dehydration of halloysite were largely carried out in the laboratoire Central des Services Chimiques de l'État, Paris, where we enjoyed not only the excellent facilities of the laboratory but also the advice of Monsieur J. Méring and Mile R. Glaser who had made similar studies of montmorillonite. The use of a Guinier-type focusing camera with strictly monochromatic radiation was especially useful. These experiments were undertaken because little was known about the dehydration process beyond the recognition that it occurs very readily in dry atmospheres and at low temperatures. The main experimental difficulty lies in differentiating between water adsorbed oil external surfaces of the clay particles (adsorbed water) and water internally absorbed between the kaolin layers (interlayer water).

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1948

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References

Alexander, (L. T.), Faust, (G. T.), Hendricks, (S. B.), Insley, (H.), and McMurdie, (H. F.), 1943. Relationships of the clay minerals halloysite and endellite. Amer. Min., vol. 28, pp. 118. [M.A. 8–342.]Google Scholar
Bragg, (W. L.) and West, (J.), 1928. A technique for the X-ray examination of crystal structures with many parameters. Zeits. Krist., vol. 69, pp. 118148. [M.A. 4–17.]Google Scholar
Brindley, (G. W.), 1945. The effect of grain or particle size on X-ray reflections from mixed powders and alloys. Phil. Mag., vol. 36, pp. 347369.CrossRefGoogle Scholar
Brindley, (G. W.) and Robinson, (K.), 1946. Randomness in the structures of kaolinitic clay minerals. Trans. Faraday Soc., vol. 42 B, pp. 198205.CrossRefGoogle Scholar
Brindley, (G. W.) and Spiers, (F. W.), 1934. A technique for the photographic determination of the intensities of X-ray reflections from powders. Proc. Physical Soc., vol. 46, pp. 841852.CrossRefGoogle Scholar
Brindley, (G. W.) and Spiers, (F. W.), 1938. The measurement in absolute units of the intensities of X-ray reflections from crystalline powders. Proc. Physical Soc., vol. 50, pp. 1729.CrossRefGoogle Scholar
Hendricks, (S. B.) and Jefferson, (M. E.), 1938. Structures of kaolin and talc-pyrophyllite hydrates and their bearing on water sorption of the clays. Amer. Min., vol. 23, pp. 863875. [M.A. 7422.]Google Scholar
Hendricks, (S. B.) and Teller, (E.), 1942. X-ray interference in partially ordered layer lattices. Journ. Chem. Physics, vol. 10, pp. 147167. [M.A. 9–221.]CrossRefGoogle Scholar
Hofmann, (U.), Endell, (K.), and Wilm, (D.), 1934. Röntgenographische und kolloidchemische Untersuchungen über Ton. Angew. Chem., vol. 47, pp. 539 547.CrossRefGoogle Scholar
MacEwan, (D. M. C.), 1947. The nomenclature of the halloysite minerals. Min. Mag., vol. 28, pp. 3644.Google Scholar
Méring, (J.), 1946. On the hydration of montmorillonite. Trans. Faraday Soc., vol. 42 B, pp. 205219.CrossRefGoogle Scholar
Ross, (C. S.), and Kerr, (P. F.), 1934. Halloysite and allophane. Prof. Paper, U.S. Geol. Survey, no. 185-G, pp. 135148. [M.A. 6–136.]Google Scholar