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On a rapid method for the accurate recognition of sulphides, arsenides, antimonides, and double compounds of these bodies with metals

Published online by Cambridge University Press:  14 March 2018

Extract

The process to be described has been applied to the minerals mentioned below, but I have no doubt that all similarly constituted minerals will also be easily recognised by the method.

I am quite sure that all mineralogists have experienced much annoyance and difficulty in obtaining really satisfactory results with the ordihary blowpipe reactions in regard to some of the compounds of arsenic, antimony, and sulphur with metals, particularly in the separation of the metal or metals from the above-mentioned elements. In order to obtain the metal the assay requires a most careful and tedious roasting on charcoal in the oxidising flame of the blow-pipe, in order to volatilise away the sulphur, arsenic, or antimony. When this roasting is complete the residue (oxide) is mixed with either sodium carbonate, or that salt and cyanide of potas. slum, and fused for a considerable time on charcoal in the reducing flame in order to obtain a bead of the metal.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1891

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