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Crevice corrosion of duplex stainless steels in natural and chlorinated seawater

Published online by Cambridge University Press:  02 February 2012

N. Larché
Affiliation:
French Corrosion Institute, 29200 Brest, France. e-mail: [email protected]
D. Thierry
Affiliation:
French Corrosion Institute, 29200 Brest, France. e-mail: [email protected]
V. Debout
Affiliation:
DCNS, 50104 Cherbourg, France
J. Blanc
Affiliation:
Délégation Générale pour l’Armement (DGA), 94114 Arcueil, France
T. Cassagne
Affiliation:
Total E&P, 64018 Pau, France
J. Peultier
Affiliation:
ArcelorMittal, Global R&D, Industeel, 71201 Le Creusot, France
E. Johansson
Affiliation:
Outokumpu Stainless, 77422 Avesta, Sweden
C. Taravel-Condat
Affiliation:
Technip, Flexi France, 76580 Le Trait, France
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Abstract

Since contradictory data can be found in the literature, it is often difficult to assess the susceptibility of crevice corrosion of stainless steels in service conditions for a given marine application. The initiation and propagation of crevice corrosion in natural seawater were evaluated for five different duplex stainless steel grades together with some austenitic grades. A CREVCORR-type assembly was used to simulate crevice configurations involving the use of plastic crevice formers. The standard pressure applied on the crevice assembly was 3 N/mm2. Pressure of about 20 N/mm2 was also applied on some selected specimens in order to assess the effect of crevice geometry on crevice corrosion. The effect of environmental parameters (i.e. temperature, flowing conditions, residual chlorine, and dissolved oxygen content) and of surface roughness on the crevice corrosion initiation and propagation were investigated, allowing the assessment of limits of applications for some tested stainless steel grades. The less alloyed duplex stainless steels were evaluated in stagnant seawater at 5 °C and 20 °C. The duplex stainless steel UNS S32205, with PREN = 37, was also evaluated under the same conditions of exposure. The high alloyed stainless steels with PREN above 40 were evaluated in the expected most severe conditions of exposure, namely in 0.5 ppm-chlorinated seawater at 20 °C, in seawater at 30 °C (not chlorinated and with 0.5 ppm of residual chlorine) and in seawater at 50 °C (not chlorinated and with 0.5 ppm of residual chlorine). As expected the less alloyed duplex stainless steels showed limited crevice corrosion resistance in the tested media while UNS S32205 showed better resistance in the less severe tested condition of exposure. In demanding media it was shown that the limits of application of highly alloyed stainless steels are highly dependent on the crevice geometry (i.e. specimen roughness and applied pressure at gasket location).

Type
Research Article
Copyright
© EDP Sciences 2012

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References

Références

Herbsleb, G., Mater. Corros. 33 (1982) 334-340
P. Combrade, Crevice Corrosion of Metallic Materials, Corrosion Mechanisms in Theory and Practice, 2nd edition, 2002, p. 358
ASTM G48-03 (reapproved 2009), Standard Test Methods for Pitting and Crevice Corrosion Resistance of Stainless Steels and Related Alloys by Use of Ferric Chloride Solutions, American Society for Testing and Materials, 2009
C.V. Roscoe, K.J. Gradwell, The History and Development of Duplex Stainless Steels, Duplex Stainless Steel’86, 1986, p. 34
O. Strandmyr, O. Hagerup, Field Experience with Stainless Steel Materials in Seawater Systems, Corrosion’98, Houston, NACE, 1998, p. 707
T. Havn, Material Engineering and Fabrication Experiences, NACE CORROSION’95, 1995, p. 56
R. Johnsen, North Sea Experience with the Use of Stainless Steel in Seawater Applications, EFC Publication 10, The Institute of Materials, 1993
J.P. Audouard, D. Thierry, D. Féron, C. Compère, V. Scotto, B. Wallen, A.H. Stigenberg, T. Rogne, Crevice Corrosion Resistance of Stainless Steels in Natural Sea Water, Results of a Paneuropean Test Programme, Stainless Steels 96, 1996, Düsseldorf, Germany, 1996, pp. 83–88
Le Bozec, N., et al., Corros. Sci. 43 (2001) 765-786
Marconnet, C., et al., Electrochem. acta 54 (2008) 123-132
P. Chandrasekaran, S.C. Dexter, Mechanism of Potential Ennoblement on Passive Metals by Seawater Biofilms, Corrosion Nace, New Orleans, 1993, p. 493
Landoulsi, J., et al., Environment Science Technologies 42 (2008) 2233-2242
D. Thierry, W. Sand, Microbial Corrosion, Corrosion Mechanisms in Theory and Practice, 2nd edition, (éd.) P. Marcus, 2002
Amaya, H., Miyuki, H., Corros. Eng. 44 (1995) 123-133
G. Ventura, E. Traverso, A. Mollica, Corrosion 45 (1989)
A. Mollica, V. Scotto, Mechanism and Prevention of Biofilm Effect on Stainless Steel Corrosion, Sea Water Corrosion of Stainless Steels – Mechanisms and Experiences, EFC Publication 19, 1996
R. Francis, G. Byrne, Stainless Steel World KCI 2004, pp. 53, Vol. 16
B. Espelid, Development of a New Crevice Corrosion Qualification Test for Stainless Steels, Stainless Steel World, 2003
J.W. Oldfield, Effect of Crevice Geometry on the Corrosion Of AISI 304 and 316 in Marine Environments, NACE Corrosion 89, 1989, p. 290
U. Steinsmo, T. Rogne, J.M. Drugli, Aspects of Testing and Selecting Stainless Steels for Seawater Application, NACE Corrosion 1997, pp. 53–12
Azuma, S., et al., Corros. Sci. 46 (2004) 2265-2280
J.P. Audouard, M. Verneau, Highly Alloyed Stainless Steels for Sea Water Applications, NACE Corrosion, 1996, p. 508
U. Kivisakk, Crevice Corrosion Testing of Stainless Steel Tubes, NACE Corrosion, 2004, p. 04300
T. Rogne, U. Steinsmo, Practical Conseque- nces of the Biofilm in Natural Sea Water and of Chlorination on the Corrosion Behaviour of Stainless Steels, Sea Water Corrosion of Stainless Steels – Mechanisms and Experiences, EFC Publication 19, 1996
Dexter, S.C., La Fontaine, J.P., Corrosion 54 (1998) 851-861
R. Francis, Galvanic Corrosion: A Practical Guide for Engineers, 2001
A.M. Grolleau, H. Le Guyader, V. Debout, Prediction of the Service Life of Nickel Based Alloys N06625 and N06059 and Super Austenitic Stainless Steel S31266 in Seawater Using in-House Crevice Corrosion Tests, Nace Corrosion, 2009, p. 09192
P. Gallagher, A. Nieuwhof, R.J.M. Tausk, Experiences with Seawater Chlorination on Copper Alloys and Stainless Steels, EFC publication 10, The Institute of Materials, 1993, pp. 73-91
P.O. Gartland, J.M. Drugli, Crevice Corrosion of High-Alloyed Stainless Steel in Chlorinated Seawater, NACE Corrosion, 1991, p. 510
J.P. Audouard, J.-C. Gagnepain, A New Generation of High Alloyed Austenitic Stainless Steel for Seawater Systems: UR B66, EFC publication 10, The Institute of Materials, 1993, pp. 152–164