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Cooling rate and situation of the glass-forming border in the GeSe2-Sb2Te3-PbSb2Te4 system

Published online by Cambridge University Press:  13 March 2012

L. Aljihmani ,
V. Vassilev  and
T. Hristova-Vasileva
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Abstract

The glass-forming ability of chalcogenide glasses from the GeSe2-Sb2Te3-PbSb2Te4 system is investigated at different cooling rates. The samples are synthesized by direct synthesis in evacuated quartz ampoules from the initial compounds and quenched in air, water, water+ice+NaCl and liquid nitrogen with cooling rates of 3, 9, 34 and 400 K/s, respectively. The obtained bulks are characterized by visual and X-ray diffraction analyses. The critical cooling rate for obtaining chalcogenide glasses from the investigated system is 34 K/s. Above this rate the border between the glassy and crystalline phases shows a tendency towards narrowing of the glass-forming region.

Keywords

Cooling rateglass-forming regionX-ray diffraction
Type
Research Article
Information
Metallurgical Research & Technology , Volume 109 , Issue 1 , 2012 , pp. 21 - 26
Copyright
© EDP Sciences 2012

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References

Jalali, P., Li, M., Phys. Rev. B 71 (2005) 014206
Jalali, P., Li, M., Intermetallics 12 (2004) 1167-1176
Redington, W., Redington, M., Hampshire, S., Materials Science Forum 554 (2007) 25-30
Busch, R., J. Optoel. Adv. Mat. 52 7 (2000) 39-42
Lohwongwatana, B., Schroers, J., Johnson, W.L., Phys. Rev. Lett. 96 (2006) 075503
Xu, Min, Quan, Mindxiu, Hu, Zhuangqi, Cheng, Lizhi, He, Kaiyuan, J. Mater. Sci. Technol. 17 (2001) 260-262
Todoroki, S., Inoue, S., Matsumoto, T., Appl. Surface Sci. 189 (2002) 241-244
Darby Dyar, M., Naney, M.T., Swanson, S.E., Amer. Mineralogist 72 (1987) 792-800
Oganesyan, M.R., Oganesyan, R.M., Knyazyan, N.B., Theoretical Foundations of Chemical Engineering 44 (2010) 500-502
Kim, Ji-Hun, Sik Park, Joon, Soo Park, Eun, Tae Kim, Won, Kim, Do Hyang, Met. Mater. Internat. 11 1 (2005) 1-9
Aljihmani, L., Hristova-Vasileva, T., Vassilev, V., Fundamental Sci. Appli. 16 2 (2011) 159-161
Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Powder Diffraction File 16-80
Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Powder Diffraction File 26-9659
Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Powder Diffraction File 40-1008
Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Powder Diffraction File 15-861
Joint Committee on Powder Diffraction Standards, International Center for Diffraction Data, Powder Diffraction File 02-588