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Experimental validation of a tube based constitutive equationfor linear polymer melts with inter-chain tube pressure effect
Published online by Cambridge University Press: 02 April 2013
Abstract
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A polydisperse case of an entangled linear polymer melts constitutive equation wasstudied. This constitutive equation, proposed by S. Dhole et al. [J. Non-Newtonian FluidMech. 161 (2009) 10–18], based on the reptation theory and the tube model, was tested on apolystyrene in shear (capillary rheometry) and planar extension in a complex flow(fieldwise measurements in a contraction flow) for different level of strain rates. A goodquantitative prediction of all the set of experiments was obtained, using no adjustablenonlinear parameters.
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