Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-19T04:30:59.310Z Has data issue: false hasContentIssue false

Development and simulation of a hydrogen storage unit using metal hydrides

Published online by Cambridge University Press:  17 August 2007

Maxime Botzung
Affiliation:
CEA Grenoble, DRT/LITEN/ DTH, 17 rue des Martyrs, 38054 Grenoble, France
Serge Chaudourne
Affiliation:
CEA Grenoble, DRT/LITEN/ DTH, 17 rue des Martyrs, 38054 Grenoble, France
Christian Perret
Affiliation:
CEA Grenoble, DRT/LITEN/ DTH, 17 rue des Martyrs, 38054 Grenoble, France
Michel Latroche
Affiliation:
CNRS, CMTR-ICMPE-UMR7182, 2–8 rue Henri Dunant, 94320 Thiais Cedex, France
Annick Percheron-Guegan
Affiliation:
CNRS, CMTR-ICMPE-UMR7182, 2–8 rue Henri Dunant, 94320 Thiais Cedex, France
Marty Philippe
Affiliation:
CEA, Équipe LEGI-GRETh, 17 rue des Martyrs, 38054 Grenoble Cedex, France
Get access

Abstract

This paper presents a hydrogen storage system using metal hydrides for a Combined Heat and Power CHP) system. Hydride storage technology has been chosen due to project specifications: high volumetric capacity, low pressures (<3.5 bar) and low temperatures (<75 °C: fuel cell temperature). During absorption, heat from hydride generation is dissipated by fluid circulation. An integrated plate-fin type heat exchanger has been designed to obtain good compacity and to reach high absorption/desorption rates. At first, the storage system has been tested in accordance with project specifications (absorption/desorption 3.5/1.5 bar). Then, the hydrogen charge/discharge times have been decreased to reach system limits. System design has been used to simulate thermal and mass comportment of the storage tank. The model is based on the software Fluent. We take in consideration heat and mass transfers in the porous media and a convective flow for cooling/heating the system during absorptions/desorptions. The hydride thermal and mass comportment has been integrated in the software. The heat and mass transfers experimentally obtained have been compared to results calculated by the model.

Type
Research Article
Copyright
© AFM, EDP Sciences, 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Iosub, V., Latroche, M., Joubert, J.-M., Percheron-Guégan, A., Optimisation of MmNi$_{5-x}$Snx (Mm=La, Ce, Nd and Pr, $0.27<x<0.5$) compositions as hydrogen storage materials, Int J. Hydrogen Energy 31 (2006) 101108 CrossRef
M. Pons, Heat transfers in the LaNi5 powder coupled with hydrogenation reaction, Ph.D., 1991
Nasrallah, S.B., Jemni, A., Study of a two-dimensional heat and mass transfer during absorption/desorption in a metal-hydrogen reactor, Int J. Hydrogen Energy 20 (1995) 4352