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Self-consistent fields without exchange for Pr3+ and Tm3+

Published online by Cambridge University Press:  24 October 2008

E. Cicely Ridley
E. Cicely Ridley
Affiliation:
Atomic Energy Research Establishment, Harwell
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Abstract

Self-consistent fields without exchange have been calculated for the ground state of Pr3+ and Tm3+. The spin-orbit coupling constant ζ(4f) is found to have the values 785 and 2742 cm−1 in Pr3+ and Tm3+, respectively. The corresponding values of are 29·4 and 77·5 Å−3. Values of the Slater integrals F2(4f, 4f), F4(4f, 4f) and F6(4f, 4f) are also given for each structure.

Type
Research Article
Information
Mathematical Proceedings of the Cambridge Philosophical Society , Volume 56 , Issue 1 , January 1960 , pp. 41 - 54
Copyright
Copyright © Cambridge Philosophical Society 1960

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References

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