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A note on an assumption in the theory of cooperative phenomena

Published online by Cambridge University Press:  24 October 2008

G. S. Rushbrooke
G. S. Rushbrooke
Affiliation:
St John's College
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Extract

When the approximate methods of Bragg and Williams or Bethe are used in theoretical work on cooperative phenomena it is customary to suppose that only the configurational energy of the assembly depends on the molecular arrangement; the contribution which a molecule makes to the partition function, apart from its share in this configurational energy, is supposed to be independent of the positions of the other molecules.

Type
Research Article
Information
Mathematical Proceedings of the Cambridge Philosophical Society , Volume 34 , Issue 3 , July 1938 , pp. 424 - 428
Copyright
Copyright © Cambridge Philosophical Society 1938

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References

* Fowler, , Proc. Cambridge Phil. Soc. 32 (1936), 144.CrossRefGoogle Scholar