Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-07T15:24:14.178Z Has data issue: false hasContentIssue false
  • English
  • Français

Momentum Distribution in Molecular Systems

Part II. Carbon and the C—H Bond

Published online by Cambridge University Press:  24 October 2008

C. A. Coulson  and
W. E. Duncanson
C. A. Coulson
Affiliation:
University CollegeDundee
W. E. Duncanson
Affiliation:
University CollegeLondonc/o University College of North Wales Bangor
Get access Rights & Permissions [Opens in a new window]

Extract

The momentum distribution has been calculated for an electron in one of the hybridized orbitals of a carbon atom, and is shown as a function of the degree of hybridization. The mean momentum shows a steady increase from pure s to pure p binding. Similar calculations have been made for the momentum distribution in the C—H bond, and it is shown that this also depends upon the degree of s-p mixing. The mean momentum for the bond is less than for an isolated hybridized carbon orbital, but behaves similarly to such an orbital when the degree of hybridization is varied. The differences are about within the limit of experimental determination.

Type
Research Article
Information
Mathematical Proceedings of the Cambridge Philosophical Society , Volume 37 , Issue 1 , January 1941 , pp. 67 - 73
Copyright
Copyright © Cambridge Philosophical Society 1941

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

(1)Pauling, . Nature of the chemical bond (Cornell Press, 1939), p. 81.Google Scholar
(2)Podolsky, and Pauling, . Phys Rev. 34 (1929), 109.Google Scholar
(3)Van Vleck, . J. Chem. Phys. 1 (1933), 177, 219; 2 (1934), 20.CrossRefGoogle Scholar
(4)Kirkpatrick, , Ross, and Ritland, . Phys. Rev. 50 (1936), 928.CrossRefGoogle Scholar
(5)Du Mond, . Rev. Mod. Phys. 5 (1933), 1.CrossRefGoogle Scholar
(6)Slater, . Phys. Rev. 36 (1930), 57.CrossRefGoogle Scholar
(7)Hicks, . Phys. Rev. 52 (1937), 436.CrossRefGoogle Scholar