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Travelling Waves of Fast Cryo-chemical Transformations in Solids(Non-Arrhenius Chemistry of the ColdUniverse)

Published online by Cambridge University Press:  13 December 2008

V. Barelko*
Affiliation:
Institute of Problems in Chemical Physics, 142432 Chernogolovka, Russia
N. Bessonov
Affiliation:
Institute of Mechanical Engineering Problems, 199178 Saint Petersburg, Russia
G. Kichigina
Affiliation:
Institute of Problems in Chemical Physics, 142432 Chernogolovka, Russia
D. Kiryukhin
Affiliation:
Institute of Problems in Chemical Physics, 142432 Chernogolovka, Russia
A. Pumir
Affiliation:
Department of Mathematics, University of Nice, 06560, Valbonne, France
V. Volpert
Affiliation:
Institute of Mathematics, UMR 5208 CNRS, University Lyon 1, 69622 Villeurbanne, France
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Abstract

Propagation of chemical waves at very low temperatures, observedexperimentally [V.V. Barelko et al., Advances in Chem. Phys. 74 (1988), 339-384.] at velocities of order  10 cm/s, is due toa very non- standard physical mechanism. The energy liberated bythe chemical reaction induces destruction of the material, therebyfacilitating the reaction, a process very different from standardcombustion. In this work we present recent experimental results and develop anew mathematical model which takes into account mechanical and chemicalprocesses. We carry out numerical simulations and suggest a simplified model inorder to obtain an explicit expression for the wave speed. This modelling allowsus to give a possible explanation of the existence of two modes of propagationobserved experimentally and of the dependence of the speed of propagation on theradiation dose.

Type
Research Article
Copyright
© EDP Sciences, 2008

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