Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-30T17:19:21.489Z Has data issue: false hasContentIssue false
  • English
  • Français

Molybdenum in Some Ocean and Estuarine Waters

Published online by Cambridge University Press:  11 May 2009

P. C. Head  and
J. D. Burton
P. C. Head
Affiliation:
Department of Oceanography, The University, Southampton
J. D. Burton
Affiliation:
Department of Oceanography, The University, Southampton
Get access Rights & Permissions [Opens in a new window]

Extract

Knowledge of the distribution of molybdenum in sea water is needed for an understanding of the behaviour of the element in the geochemical cycle of weathering and sedimentation and for the assessment, in relation to environmental levels, of its possible utilization by marine organisms. The principal measurements of molybdenum in sea water are summarized in Table 1; the results of earlier investigations (Ernst & Hoermann, 1936; Bardet, Tchakirian & Lagrange, 1938; Noddack & Noddack, 1940) are excluded from this summary as later work suggests that they were inaccurate. The summary indicates that molybdenum is a comparatively uniformly distributed trace element in sea water with a concentration usually in the range of 9–13 µg/l. Except for waters directly affected by continental drainage or other localized influences, the only values appreciably below this range appear to be those reported by the early workers cited above, by Zhavoronkina (1960) for a single sample from the Atlantic, and by Brooks (1965) for waters off New Zealand.

Type
Research Article
Information
Journal of the Marine Biological Association of the United Kingdom , Volume 50 , Issue 2 , May 1970 , pp. 439 - 448
Copyright
Copyright © Marine Biological Association of the United Kingdom 1970

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Bachmann, R. W. & Goldman, C. R., 1964. The determination of microgram quantities of molybdenum in natural waters. Limnol. Oceanogr., Vol. 9, pp. 143–6.CrossRefGoogle Scholar
Bardet, J., Tchakirian, A. & Lagrange, R., 1938. Recherche spectrographique des éléments existant à l'état de traces dans l'eau de mer. C. r. hebd. Séanc. Acad. Sci., Paris, T. 206, pp. 450–2.Google Scholar
Black, W. A. P. & Mitchell, R. L., 1952. Trace elements in the common brown algae and in sea water. J. mar. biol. Ass. U.K., Vol. 30, pp. 575–84.CrossRefGoogle Scholar
Brooks, R. R., 1965. Trace elements in New Zealand coastal waters. Geochim. cosmochim. Acta, Vol. 29, pp. 1369–70.CrossRefGoogle Scholar
Burton, J. D., 1969. Molybdenum in the Vellar Estuary, Southern India. J. Cons. perm. int. Explor. Mer, Vol. 33, 103–4.CrossRefGoogle Scholar
Chan, K. M. & Riley, J. P., 1966. The determination of molybdenum in natural waters, silicates and biological materials. Analytica chim. Acta, Vol. 36, pp. 220–9.CrossRefGoogle ScholarPubMed
Ernst, T. & Hoermann, H., 1936. Bestimmung von Vanadium, Nickel und Molybdän im Meerwasser. Nachr. Ges. Wiss. Göttingen mathematisch-physikalische Klasse, Fach. IV N.F., Bd. I, pp. 205–8.Google Scholar
Ishibashi, M., 1953. Studies on minute elements in sea water. Rec. oceanogr. Wks Japan, N.S., Vol. I, pp. 88–92.Google Scholar
Ishibashi, M., Shigematsu, T. & Nakagawa, Y., 1954. Determination of tungsten and molybdenum in sea water. Bull. Inst. chem. Res. Kyoto Univ., Vol. 32, pp. 199–202.Google Scholar
Kharkar, D. P., Turekian, K. K. & Bertine, K. K., 1968. Stream supply of dissolved silver, molybdenum, antimony, selenium, chromium, cobalt, rubidium and cesium to the oceans. Geochim. cosmochim. Acta, Vol. 32, pp. 285–98.CrossRefGoogle Scholar
Livingstone, D. A., 1963. Chemical composition of rivers and lakes. Prof. Pap. U.S. geol. Surv., No. 440-G, p. G 50.Google Scholar
Noddack, I. & Noddack, W., 1940. Die Häufigkeiten der Schwermetalle in Meerestieren. Ark. Zool., Vol. 32 A, pp. 1–35.Google Scholar
Riley, J. P. & Taylor, D., 1968. The use of chelating ion exchange in the determination of molybdenum and vanadium in sea water. Analytica chim. Acta, Vol. 41, pp. 175–8.CrossRefGoogle Scholar
Savage, P. D. V., 1965. Preliminary observations on the phytoplankton of Southampton Water. Br. phycol. Bull., Vol. 2, pp. 515–16.Google Scholar
Sugawara, K., 1965. Some microelements in the world ocean. In Problemy Geokhimii. Nauka, Moscow, pp. 635–47. National Lending Library for Science and Technology, Translation RTS 4737, pp. 13.Google Scholar
Sugawara, K. & Okabe, S., 1960. Geochemistry of molybdenum in natural waters (1). J. Earth Sci., Vol. 8, pp. 93–107.Google Scholar
Sugawara, K. & Okabe, S., 1966. Molybdenum and vanadium determination of “Umitaka-Maru” samples from her 1962–1963 and 1963–1964 cruises of the International Indian Ocean Expedition. J. Tokyo Univ. Fish., Vol. 8, No. 2, pp. 165–71.Google Scholar
Sugawara, K., Terada, K., Kanamori, S., Kanamori, M. & Okabe, S., 1962. On different distribution of calcium, strontium, iodine, arsenic and molybdenum in the northwestern Pacific, Indian and Antarctic Oceans. J. Earth Sci., Vol. 10, pp. 34–50.Google Scholar
Weiss, H. V. & Lai, M. G., 1961. The cocrystallisation of ultramicro quantities of molybdenum with a-benzoinoxime. Determination of molybdenum in sea water. Talanta, Vol. 8, pp. 72–6.CrossRefGoogle Scholar
Young, E. G., Smith, D. G. & Langille, W. M., 1959. The chemical composition of sea water in the vicinity of the Atlantic provinces of Canada. J. Fish. Res. Bd Can., Vol. 16, pp. 7–12.CrossRefGoogle Scholar
Zhavoronkina, T. K., 1960. Spectrographic method for determining several trace elements in sea water. Trudy morsk. gidrofiz. Inst., Vol. 19, pp. 38–41, translated in Soviet Oceanogr., 1963 Series, No. 3, pp. 27–9.Google Scholar