Two classes of vector-valued BMOA spaces are defined, in the complex ball and on the complex sphere, respectively. In the case of the complex sphere, vector measures are involved, since the argument in the scalar setting is not appropriate. Several properties (the Lp-equivalent norm theorem, exponential decay, the Baernstein theorem, and so on) of BMOA in the complex ball are extended to the Banach space setting. The two classes of BMOA spaces are proved to be isomorphic; in particular, the corresponding John–Nirenberg exponential decay is shown. Finally, the vector-valued H1-BMOA duality theorem is proved.