The flag curvature of a Finsler metric is called a Riemannian quantity because it is an extension of sectional curvature in Riemannian geometry. In Finsler geometry, there are several non-Riemannian quantities such as the (mean) Cartan torsion, the (mean) Landsberg curvature and the S-curvature, which all vanish for Riemannian metrics. It is important to understand the geometric meanings of these quantities. In the paper, Finsler metrics of scalar curvature (that is, the flag curvature is a scalar function on the slit tangent bundle) are studied and the flag curvature is partially determined when certain non-Riemannian quantities are isotropic. Using the obtained formula for the flag curvature, locally projectively flat Randers metrics with isotropic S-curvature are classified.